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Steric Effects on Electroosmotic Nano-Thrusters under High Zeta Potentials [PDF]

open access: goldMathematics, 2021
Here, space electroosmotic thrusters in a rigid nanochannel with high wall zeta potentials are investigated numerically, for the first time, considering the effect of finite size of the ionic species. The effect, which is called a steric effect, is often
Jiaxuan Zheng, Siyi An, Yongjun Jian
doaj   +2 more sources

Steric Effects of N-Alkyl Group on the Base-Induced Nitrogen to Carbon Rearrangement of Orthogonally Protected N-Alkyl Arylsulphonamides [PDF]

open access: yesMolecules
The rearrangement of a total of 56 members of 22 series of orthogonally protected N-alkyl arylsulphonamides of general structure 4-XC6H4SO2NR1CO2R2 [X = H, CH3, F, Cl, Br, CH3O, CN, CF3 or C(CH3)3; R1 = CH3, CH2CH3, CH2CH2CH3, CH(CH3)2 or CH2CH(CH3)2; R2
Amie Saidykhan   +4 more
doaj   +2 more sources

Steric Effects of Alcohols on the [Mn4O4] Cubane-Type Structures [PDF]

open access: goldCrystals
[M4O4] (M = 3d transition metal) represents an interesting class of compounds featuring cubane-type molecular structures, and particularly, [Mn4O4] cubanes or their derivatives attract much attention by virtue of their potential applications as single ...
Yan He, Zheng Zhou, Haixiang Han
doaj   +2 more sources

Electrostatic and steric effects underlie acetylation-induced changes in ubiquitin structure and function [PDF]

open access: yesNature Communications, 2022
Ubiquitin is not only a posttranslational modifier but itself is subject to modifications, such as acetylation. Characterization of distinct acetylated ubiquitin variants reveals that each acetylation site has a particular impact on ubiquitin structure ...
Simon Maria Kienle   +9 more
doaj   +2 more sources

Steric effects on the sydnones reactivity. New sydnones and pyrazoles

open access: diamondARKIVOC, 2002
Florea Dumitrascu   +4 more
doaj   +3 more sources

Insights on tert-butyl alkylation effects on fluorobenzene

open access: yesScientific African, 2021
Directing effects of substituents on the benzene ring, ortho and para directors by electron donating groups and meta directors using electron withdrawing groups have been studied and reported widely. In particular and for many years, the directing effect
Lewis Mtashobya
doaj   +1 more source

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