Results 1 to 10 of about 11,587,644 (360)

Steric Effects in the Deposition Mode and Drug-Delivering Efficiency of Nanocapsule-Based Multilayer Films. [PDF]

open access: yesACS Omega, 2022
Using surface-initiated atom transfer radical polymerization (ATRP), block polymers with a series of quaternization degrees were coated on the surface of silica nanocapsules (SNCs) by the “grafting-from” technique.
Xu L   +12 more
europepmc   +2 more sources

Interplay of Electronic and Steric Effects to Yield Low-Temperature CO Oxidation at Metal Single Sites in Defect-Engineered HKUST-1. [PDF]

open access: yesAngew Chem Int Ed Engl, 2020
In contrast to catalytically active metal single atoms deposited on oxide nanoparticles, the crystalline nature of metal‐organic frameworks (MOFs) allows for a thorough characterization of reaction mechanisms. Using defect‐free HKUST‐1 MOF thin films, we
Wang W   +8 more
europepmc   +2 more sources

Steric effects in cyclization reactions [PDF]

open access: bronzeAustralian Journal of Chemistry, 1976
Calculations of geometric probability factors indicate that steric effects are important in determining whether the cyclization of β-substituted diallylmethylammonium ions results in five- or six-memberedrings. Evidence is obtained of the direction of intramolecular attack.
David H. Solomon   +3 more
openaire   +5 more sources

Poisson-Fermi Formulation of Nonlocal Electrostatics in Electrolyte Solutions [PDF]

open access: yesComputational and Mathematical Biophysics, 2017
We present a nonlocal electrostatic formulation of nonuniform ions and water molecules with interstitial voids that uses a Fermi-like distribution to account for steric and correlation efects in electrolyte solutions.
Liu Jinn-Liang   +2 more
doaj   +2 more sources

Electrostatic and steric effects underlie acetylation-induced changes in ubiquitin structure and function [PDF]

open access: yesNature Communications, 2022
Ubiquitin is not only a posttranslational modifier but itself is subject to modifications, such as acetylation. Characterization of distinct acetylated ubiquitin variants reveals that each acetylation site has a particular impact on ubiquitin structure ...
Simon Maria Kienle   +9 more
doaj   +2 more sources

A Highly Efficient Regioselective Addition of Acetylides to Enediones Based on Steric Effects [PDF]

open access: yesMolecules, 2013
A simple and efficient strategy for the synthesis of 1-ethynylcyclohex-2-enol derivatives was developed utilizing regioselective addition of acetylides to enediones based on steric effects.
Zhaohai Qin   +6 more
doaj   +2 more sources

Rotational and steric effects in water dissociative chemisorption on Ni(111). [PDF]

open access: yesChem Sci, 2017
Weak rotational but significant steric effects are predicted in water dissociative chemisorption on Ni(111).
Jiang B.
europepmc   +2 more sources

Review and Modification of Entropy Modeling for Steric Effects in the Poisson-Boltzmann Equation [PDF]

open access: yesEntropy, 2020
The classical Poisson-Boltzmann model can only work when ion concentrations are very dilute, which often does not match the experimental conditions.
Tzyy-Leng Horng
doaj   +2 more sources

Mercury(II) Complexes of Anionic N-Heterocyclic Carbene Ligands: Steric Effects of the Backbone Substituent [PDF]

open access: yesMolecules, 2020
Mercury(II) complexes (Me-maloNHCDipp)HgCl (1b), (t-Bu-maloNHCDipp)HgCl (2b) and (t-Bu-maloNHCDipp)HgMe (2c) supported by anionic N-heterocyclic carbenes have been obtained in good yields from the reaction of the potassium salt of N-heterocyclic carbene ...
Chandrakanta Dash   +2 more
doaj   +2 more sources

Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects. [PDF]

open access: yesJ Am Chem Soc, 2015
Bicyclic nitroxyl derivatives, such as 2-azaadamantane N-oxyl (AZADO) and 9-azabicyclo[3.3.1]nonane N-oxyl (ABNO), have emerged as highly effective alternatives to TEMPO-based catalysts for selective oxidation reactions (TEMPO = 2,2,6,6-tetramethyl-1 ...
Rafiee M, Miles KC, Stahl SS.
europepmc   +2 more sources

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