Steric Effects in the Deposition Mode and Drug-Delivering Efficiency of Nanocapsule-Based Multilayer Films. [PDF]
Using surface-initiated atom transfer radical polymerization (ATRP), block polymers with a series of quaternization degrees were coated on the surface of silica nanocapsules (SNCs) by the “grafting-from” technique.
Xu L+12 more
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Interplay of Electronic and Steric Effects to Yield Low-Temperature CO Oxidation at Metal Single Sites in Defect-Engineered HKUST-1. [PDF]
In contrast to catalytically active metal single atoms deposited on oxide nanoparticles, the crystalline nature of metal‐organic frameworks (MOFs) allows for a thorough characterization of reaction mechanisms. Using defect‐free HKUST‐1 MOF thin films, we
Wang W+8 more
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Steric effects in cyclization reactions [PDF]
Calculations of geometric probability factors indicate that steric effects are important in determining whether the cyclization of β-substituted diallylmethylammonium ions results in five- or six-memberedrings. Evidence is obtained of the direction of intramolecular attack.
David H. Solomon+3 more
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Poisson-Fermi Formulation of Nonlocal Electrostatics in Electrolyte Solutions [PDF]
We present a nonlocal electrostatic formulation of nonuniform ions and water molecules with interstitial voids that uses a Fermi-like distribution to account for steric and correlation efects in electrolyte solutions.
Liu Jinn-Liang+2 more
doaj +2 more sources
Electrostatic and steric effects underlie acetylation-induced changes in ubiquitin structure and function [PDF]
Ubiquitin is not only a posttranslational modifier but itself is subject to modifications, such as acetylation. Characterization of distinct acetylated ubiquitin variants reveals that each acetylation site has a particular impact on ubiquitin structure ...
Simon Maria Kienle+9 more
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A Highly Efficient Regioselective Addition of Acetylides to Enediones Based on Steric Effects [PDF]
A simple and efficient strategy for the synthesis of 1-ethynylcyclohex-2-enol derivatives was developed utilizing regioselective addition of acetylides to enediones based on steric effects.
Zhaohai Qin+6 more
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Rotational and steric effects in water dissociative chemisorption on Ni(111). [PDF]
Weak rotational but significant steric effects are predicted in water dissociative chemisorption on Ni(111).
Jiang B.
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Review and Modification of Entropy Modeling for Steric Effects in the Poisson-Boltzmann Equation [PDF]
The classical Poisson-Boltzmann model can only work when ion concentrations are very dilute, which often does not match the experimental conditions.
Tzyy-Leng Horng
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Mercury(II) Complexes of Anionic N-Heterocyclic Carbene Ligands: Steric Effects of the Backbone Substituent [PDF]
Mercury(II) complexes (Me-maloNHCDipp)HgCl (1b), (t-Bu-maloNHCDipp)HgCl (2b) and (t-Bu-maloNHCDipp)HgMe (2c) supported by anionic N-heterocyclic carbenes have been obtained in good yields from the reaction of the potassium salt of N-heterocyclic carbene ...
Chandrakanta Dash+2 more
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Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects. [PDF]
Bicyclic nitroxyl derivatives, such as 2-azaadamantane N-oxyl (AZADO) and 9-azabicyclo[3.3.1]nonane N-oxyl (ABNO), have emerged as highly effective alternatives to TEMPO-based catalysts for selective oxidation reactions (TEMPO = 2,2,6,6-tetramethyl-1 ...
Rafiee M, Miles KC, Stahl SS.
europepmc +2 more sources