Results 111 to 120 of about 280,815 (357)

Preparation of benzolactams by Pd(II)-catalyzed carbonylation of N-unprotected arylethylamines [PDF]

, 2014
An unprecedented NH2-directed Pd(II)-catalytic carbonylation of quaternary aromatic α -amino esters to yield 6-membered 10 benzolactams has been developed. The reaction shows a strong bias to 6-membered lactams over 5-membered ones.
Albert Mach, Joan, Ariza Piquer, Xavier, García Gómez, Jordi, Granell Sanvicente, Jaime Ramón, López Barallobre, Blanca, Rodríguez Ramírez, Aleix, Santos, David   +6 more
core   +1 more source

Flexibility and Dynamicity Enhances and Controls Supramolecular Self‐Assembly of Zinc(II) Metallogels

Advanced Functional Materials, EarlyView.
Zinc(II) coordination complexes with tunable aryloxy‐imine ligands exhibit controllable supramolecular self‐assembly into hierarchical fibrous structures. Coordination‐driven stacking, not π–π interactions, enables gelation, dynamic assembly/disassembly, and enhanced nanomechanical properties.
Merlin R. Stühler, Hesam Makki, Dorothee Silbernagl, Mathias Dimde, Kai Ludwig, Bengt E. Tegner, Christopher Greve, Konstantin Rausch, Eva M. Herzig, Anna Köhler, Alex J. Plajer   +10 more
wiley   +1 more source

Possible bi-stable structures of pyrenebutanoic acid-linked protein molecules adsorbed on graphene: theoretical study

Beilstein Journal of Organic Chemistry
We theoretically analyze possible multiple conformations of protein molecules immobilized by 1-pyrenebutanoic acid succinimidyl ester (PASE) linkers on graphene. The activation barrier between two bi-stable conformations exhibited by PASE is confirmed to
Yasuhiro Oishi, Motoharu Kitatani, Koichi Kusakabe   +2 more
doaj   +1 more source

Photocatalytic Versus Stoichiometric Hydrogen Generation Using Mesoporous Silicon Catalysts: The Complex Role of Sacrificial Reagents

Advanced Functional Materials, EarlyView.
This study highlights the importance of accounting for stoichiometric hydrogen produced when utilizing Si photocatalysts. The stoichiometric contribution is sacrificial reagent dependent and decreases with increasing sterics around the catalyst surface.
Sarrah H. Putwa, Sarah A. Martell, Berthold Reis, Simona Schwarz, Mita Dasog   +4 more
wiley   +1 more source

Emergence of Light‐Transforming Layered Hybrid Halide Perovskites

Advanced Functional Materials, EarlyView.
The emerging class of light‐transforming layered halide perovskite materials is reviewed, outlining challenges for their development and perspectives toward application in the future. Abstract Layered hybrid halide perovskites (LHPs) have attracted considerable attention in optoelectronics.
Ghewa AlSabeh, Jovana V. Milić
wiley   +1 more source

Anisotropic shock sensitivity for β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine energetic material under compressive-shear loading from ReaxFF-ℓg reactive dynamics simulations [PDF]

, 2012
We report here the predictions on anisotropy of shock sensitivity and of chemical process initiation in single crystal β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) using compressive shear reactive dynamics (CS-RD) model with ReaxFF-ℓg ...
Goddard, William A., III, Huang, Fenglie, Liu, Yi, Zhou, Tingting, Zybin, Sergey V.   +4 more
core  

Anisotropic Shock Sensitivity of Cyclotrimethylene Trinitramine (RDX) from Compress-and-Shear Reactive Dynamics [PDF]

, 2012
We applied the compress-and-shear reactive dynamics (CS-RD) simulation model to study the anisotropic shock sensitivity of cyclotrimethylene trinitramine (RDX) crystals.
An, Qi, Goddard, William A., III, Kim, Hyungjun, Zybin, Sergey V.   +3 more
core   +2 more sources

2D Phosphorene‐Decorated Ni‐Rich Layered Cathodes for High‐Power and High‐Energy Li‐Ion Batteries

Advanced Functional Materials, EarlyView.
A conformal coating of 2D phosphorene nanosheets is decorated on Li[Ni0.8Co0.1Mn0.1]O2 cathodes to enhance fast charge–discharge performance and structural stability under high mass loading and low carbon content. As a result, it exhibits improved power capability, cycle stability, and suppressed structural degradation, offering a promising strategy ...
Jihoe Lee, Kijeong Nam, Bonyoung Ku, Myungeun Choi, Min‐kyung Cho, Su Yeon Jung, Jinhong Min, Jinho Ahn, Yongseok Lee, Sang‐Yeop Lee, Dohyun Lee, Yun Seong Cho, Da‐Sol Kwon, Jung‐Keun Yoo, Joohoon Kang, Jongsoon Kim   +15 more
wiley   +1 more source

Catalyst-Dependent Chemoselectivity in the Dirhodium-Catalyzed Cyclization Reactions Between Enodiazoacetamide and Nitrosoarene: A Theoretical Study

Frontiers in Chemistry, 2019
N-O heterocycle compounds play an important role in various fields. Doyle et al. (Cheng et al., 2017) have recently reported an efficient catalyst-controlled selective cyclization reactions of tert-butyldimethylsilyl (TBS)-protected enoldiazoacetamides ...
Yan Zhang, Yongsheng Yang, Ruyu Zhu, Xingyu Wang, Ying Xue   +4 more
doaj   +1 more source

Photoswitching Conduction in Framework Materials

Advanced Functional Materials, EarlyView.
This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez, Stefan Hecht, Wolfgang Wenzel, Lars Heinke, Mariana Kozlowska   +4 more
wiley   +1 more source