Utilization of steric hindrance of alkyl lithium-based initiator to synthesize high 1,4 unit-containing hydroxyl- terminated polybutadiene [PDF]
Royal Society Open Science, 2018 A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized.
Xin Min, Xiaodong Fan, Jie Liu
doaj +1 more source
Using steric hindrance to manipulate and stabilize metal halide perovskites for optoelectronics. [PDF]
Chem Sci, 2021 The chemical instability of metal halide perovskite materials can be ascribed to their unique properties of softness, in which the chemical bonding between metal halide octahedral frameworks and cations is the weak ionic and hydrogen bonding as in most ...
Miao Y, Chen Y, Chen H, Wang X, Zhao Y.
europepmc +2 more sources
Structure-guided steric hindrance engineering of Bacillus badius phenylalanine dehydrogenase for efficient L-homophenylalanine synthesis. [PDF]
Biotechnol Biofuels, 2021 Background Direct reductive amination of prochiral 2-oxo-4-phenylbutyric acid (2-OPBA) catalyzed by phenylalanine dehydrogenase (PheDH) is highly attractive in the synthesis of the pharmaceutical chiral building block l -homophenylalanine ( l -HPA) given
Wu T, Mu X, Xue Y, Xu Y, Nie Y.
europepmc +2 more sources
STRIDER: Steric hindrance estimator [PDF]
, 2020 AbstractIn silicomodeling plays a vital role in thede novodesigning and docking of biomacromolecules as well as in exploring their conformational dynamics. Additionally, it has a major role in acquiring the structural insights from the parameters derived from the experimental techniques such as cryo-electron microscopy.
Prasad Patro, L Ponoop +1 more
openaire +1 more source
Phenyl Ring: A Steric Hindrance or a Source of Different Hydrogen Bonding Patterns in Self-Organizing Systems? [PDF]
J Phys Chem Lett, 2021 A series of five alcohols (3-methyl-2-butanol, 1-cyclopropylethanol, 1-cyclopentylethanol, 1-cyclohexylethanol, and 1-phenylethanol) was used to study the impact of the size of steric hindrance and its aromaticity on self-assembling phenomena in the ...
Nowok A +7 more
europepmc +2 more sources
Steric hindrance effects on the retention of pressure-induced emission toward scintillators
Cell Reports Physical Science, 2023 Dianlong Zhao +6 more
openalex +2 more sources
Observation of 1,3-Diketones Formation in the Reaction of Bulky Acyl Chlorides with Methyllithium
Molecules, 2012 The formation of 1,3-diketones was observed in the reactions of bulky acyl chlorides with methyllithium. The reaction products depend on the steric hindrance around the carbonyl group of the acyl chloride and the electronic effect of the group(s) linked ...
Liwen Yang, Nianfa Yang, Jian Zhang
doaj +1 more source
A Systematic Comparison of the Intrinsic Properties of Wheat and Oat Bran Fractions and Their Effects on Dough and Bread Properties: Elucidation of Chemical Mechanisms, Water Binding, and Steric Hindrance. [PDF]
Foods, 2021 This study aimed at elucidating the contribution of chemical interactions, water binding, and steric hindrance on the effect of wheat and oat brans and of their fractions, i.e., soluble and insoluble, on dough and bread properties.
Renzetti S, Theunissen M, Horrevorts K.
europepmc +2 more sources
A Model for Granular Texture with Steric Exclusion [PDF]
, 2002 We propose a new method to characterize the geometrical texture of a granular packing at the particle scale including the steric hindrance effect. This method is based on the assumption of a maximum disorder (entropy) compatible both with strain-induced ...
F. Calvetti +8 more
core +2 more sources
Scope and limitations of aliphatic Friedel-Crafts alkylations. Lewis acid catalyzed addition reactions of alkyl chlorides to carbon-carbon double bonds [PDF]
, 1983 Lewis acid catalyzed addition reactions of alkyl halides 1 with unsaturated hydrocarbons 2 have been studied. 1:l addition products 3 are formed if the addends 1 dissociate faster than the corresponding products 3; otherwise, polymerization of 2 takes ...
Mayr, Herbert, Striepe, Wilhelm
core +1 more source