Towards a stable ion-solvating polymer electrolyte for advanced alkaline water electrolysis [PDF]
Steric hindrance is employed as a design strategy of polybenzimidazoles for ion-solvating polymer electrolyte membrane alkaline water electrolysis.
Aili, David +5 more
core +1 more source
1,9-Bis(2-pyridyl)-1,2,8,9-tetrathia-5-oxanonane
Disulfide crosslinking of proteins is typically performed by treating proteins bearing cysteine residues with small-molecule disulfide reagents. The process results in the formation of a mixed disulfide intermediate, which then reacts with the cysteine ...
Jeet Kalia, Ronald T. Raines
doaj +1 more source
The effect of polyether on the separation of pentlandite and serpentine
The effect of polyether on the separation of pentlandite from serpentine has been studied. In addition to flotation and sedimentation tests, electrophoresis and adsorption tests have been conducted.
Xiaowen Zhou, Bo Feng
doaj +1 more source
Reduced‐dimensional (2D or quasi‐2D) perovskites have recently attracted considerable interest due to their superior long‐term stability. The nature of the intercalating cations plays a key role in determining the physicochemical properties and stability
Jiyun Zhang +18 more
semanticscholar +1 more source
UNA PROPUESTA PARA ENSEÑAR EL EFECTO DE LA FORMA DE LAS MOLÉCULAS EN LA REACTIVIDAD QUÍMICA
We address the concept of steric effect in the pursuit of establishing quantitative correlations between reactivity of molecules and their molecular shape.
José G. Cermeños-Estrada +2 more
doaj +1 more source
Exploring the Mechanism of the Palladium-Catalyzed 3-Butene-2-ol Amination Reaction: A DFT Study
Palladium-catalyzed asymmetric allylic substitution, due to its valuable reactive profile, has become a quite useful tool in organic synthesis fields.
Lingshan Lyu +4 more
doaj +1 more source
London Dispersion Interactions Rather than Steric Hindrance Determine the Enantioselectivity of the Corey-Bakshi-Shibata Reduction. [PDF]
The well‐known Corey–Bakshi–Shibata (CBS) reduction is a powerful method for the asymmetric synthesis of alcohols from prochiral ketones, often featuring high yields and excellent selectivities.
Eschmann C, Song L, Schreiner PR.
europepmc +2 more sources
Synthesis and structure elucidation of novel pyrazolyl-2-pyrazolines obtained by the reaction of 3-(3-aryl-3-oxopropenyl)chromen-4-ones with phenylhydrazine [PDF]
Novel 3-aryl-5-{4-[5-(2-hydroxyphenyl)-1-phenylpyrazolyl]}-2-pyrazolines 2a-g have been prepared by the treatment of 3-(3-aryl-3-oxopropenyl)chromen-4-ones 1a-g with phenylhydrazine in refluxing acetic acid. NMR studies on deuteriochloroform solutions of
Jeko, József +3 more
core +1 more source
Resummed thermodynamic perturbation theory for bond cooperativity in associating fluids with small bond angles: Effects of steric hindrance and ring formation [PDF]
In this paper we develop a thermodynamic perturbation theory for two site associating fluids which exhibit bond cooperativity. We include both steric hindrance and ring formation such that the equation of state is bond angle dependent.
Amin Haghmoradi +3 more
core +2 more sources
Antibodies targeting enzyme inhibition as potential tools for research and drug development
Antibodies have transformed biomedical research and are now being used for different experimental applications. Generally, the interaction of enzymes with their specific antibodies can lead to a reduction in their enzymatic activity.
Pérez de la Lastra José Manuel +5 more
doaj +1 more source

