Commentary on "Using resonance synchronous spectroscopy to characterize the reactivity and electrophilicity of biologically relevant sulfane sulfur". Evidence that the methodology is inadequate because it only measures unspecific light scattering. [PDF]
Cuevasanta E+6 more
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Synechococcus sp. PCC7002 Uses Peroxiredoxin to Cope with Reactive Sulfur Species Stress
Cyanobacteria are a widely distributed group of microorganisms in the ocean, and they often need to cope with the stress of reactive sulfur species, such as sulfide and sulfane sulfur.
Daixi Liu+10 more
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Using resonance synchronous spectroscopy to characterize the reactivity and electrophilicity of biologically relevant sulfane sulfur. [PDF]
Sulfane sulfur is common inside cells, playing both regulatory and antioxidant roles. However, there are unresolved issues about its chemistry and biochemistry.
Li H+10 more
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Sulfane Sulfur Compounds as Source of Reappearance of Reductive Off-Odors in Wine
Reactive compounds with one or more sulfane sulfur atoms can be an important source of reductive off-odors in wine. These substances contain labile sulfur, which can participate in microbiological (enzymatic) and chemical transformations (including in ...
Nikolaus Müller+2 more
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The conversion of H2S to sulfane sulfur [PDF]
In a recently published Review article (H2S signalling through protein sulfhydration and beyond. Nature Rev. Mol. Cell Biol. 13, 499–507 (2012))1, Paul and Snyder use the term 'sulfhydration' to define a protein modification involving hydrogen sulfide (H2S) in which “the sulfhydryl group of a reactive Cys is modified to an -SSH group”.
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Persulfide, polysulfide and thiosulfate are examples of sulfane sulfur containing chemicals that play multiple functions in biological systems. Rhodaneses are widely present in all three kingdoms of life, which catalyze sulfur transfer among these ...
Qingda Wang+4 more
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Sulfane sulfur – new findings on an old topic
Sulfane sulfur is a divalent sulfur atom bonded to another sulfur which is very reactive and labile. Compounds containing this reactive sulfur include persulfides, polysulfides, thiosulfate, thiosulfinates, polythionates, and elemental sulfur. Sulfane sulfur appears in a number of biologically important compounds, including thiocysteine, thiocystine ...
Malgorzata Iciek+2 more
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Chemical tools for the study of hydrogen sulfide (H2S) and sulfane sulfur and their applications to biological studies. [PDF]
Takano Y, Shimamoto K, Hanaoka K.
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The glial Gomori-positive material is sulfane sulpfur.
The Gomori-positive glia are periventricular astrocytes with abundant cytoplasmic granular material, predominantly occupying a periventricular site in the brain.
Marta Góralska+3 more
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3-Mercaptopyruvate sulfurtransferase: an enzyme at the crossroads of sulfane sulfur trafficking
Abstract 3-Mercaptopyruvate sulfurtransferase (MPST) catalyzes the desulfuration of 3-mercaptopyruvate to generate an enzyme-bound hydropersulfide. Subsequently, MPST transfers the persulfide’s outer sulfur atom to proteins or small molecule acceptors. MPST activity is known to be involved in hydrogen sulfide generation, tRNA thiolation,
Brandán Pedre, Tobias P. Dick
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