Results 101 to 110 of about 57,645 (308)

Harnessing nanomaterials to precisely regulate the immunosuppressive tumor microenvironment for enhanced immunotherapy

open access: yesBMEMat, EarlyView.
The immunosuppressive tumor microenvironment, characterized by hypoxia, redox imbalance, elevated interstitial fluid pressure, and acidity, was comprehensively elucidated. This review discussed the etiology and consequences of the characteristics of the immunosuppressive tumor microenvironment, and analyzed the recent advancements in nanomaterials for ...
Wen Zhang   +7 more
wiley   +1 more source

Synthesis of α‐Pentafluorosulfanylated‐β2,3‐Amino Esters

open access: yesChemistryEurope, EarlyView.
De novo α‐SF5‐β2,3‐amino esters are now accessible through a straightforward aza‐Michael reaction using a series of newly developed (E)‐α‐SF5‐α,β‐unsaturated esters. Two new, highly functionalized, contiguous tertiary stereocenters are formed with diastereodivergence governed by the choice of solvent and/or base.
Thi Mo Nguyen   +5 more
wiley   +1 more source

Protective effects of new aryl sulfone derivatives against radiation-induced hematopoietic injury [PDF]

open access: gold, 2020
Jian Cao   +8 more
openalex   +1 more source

Photoinduced Boron‐Catalyzed Direct α‐Aminoxylation of Carboxylic Acids

open access: yesChemistryEurope, EarlyView.
A boron‐catalyzed α‐aminoxylation of carboxylic acids enables rapid access to sterically congested α‐(aminoxy)carboxylic acids. Photoexcited diboron enediolates transfer energy to O‐sulfonylhydroxylamines, triggering SO bond cleavage to generate N‐oxyl radicals.
Tsubasa Oyama   +5 more
wiley   +1 more source

Research Progress of Polyoxometalate‐Integrated Frameworks: Syntheses, Properties, and Applications

open access: yesChemistryEurope, EarlyView.
This review systematically summarizes the integration of polyoxometalates with covalent organic frameworks, metal‐organic frameworks, hydrogen‐bonded organic frameworks, and emerging porous hosts. It highlights synergistic effects, synthesis strategies, and applications in catalysis, energy storage, sensing, and biomedicine, while addressing current ...
De‐Yin Wang   +6 more
wiley   +1 more source

Synthesis of Oligo‐Sulfonimidates by Exponential Growth via Sulfur‐Phenolate Exchange Reactions

open access: yesChemistryEurope, EarlyView.
A highly flexible iterative exponential growth strategy is used in combination with the sulfur‐phenolate exchange reaction to develop sequence‐defined oligosulfonimidates (16 mer). Combining this with sulfur‐fluorine exchange‐based iterative step growth, a bespoke 20 mer (Mw = 8.5 kDa) can be synthesized.
Yu Han   +5 more
wiley   +1 more source

Aspartic vinyl sulfones: Inhibitors of a caspase-3-dependent pathway

open access: green, 2011
Paulo M.C. Glória   +8 more
openalex   +1 more source

Advances in Parahydrogen‐Induced Polarization for Nuclear Magnetic Resonance of Peptides, Proteins, and Biopolymers

open access: yesChemistryEurope, EarlyView.
Hyperpolarization by parahydrogen‐induced polarization enhances the sensitivity of nuclear magnetic resonance spectroscopy of amino acids, peptides, mini‐proteins, and biopolymers using nonnatural amino acids with unsaturated side chains up to three orders of magnitude.
Gerd Buntkowsky
wiley   +1 more source

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