A nucleophilic vinylic substitution (SNV) reaction of 1‐chlorovinyl p‐tolyl sulfoxides with alkynyllithiums provides a direct route to conjugated enynes. The transformation proceeds with stereochemical retention. Experimental studies and DFT calculations support a concerted SNVπ mechanism. Nucleophilic vinylic substitution (SNV) reactions of 2,2‐diaryl‐
Tsutomu Kimura +5 more
wiley +1 more source
Interfacial Stabilization of Li<sub>1.3</sub>Al<sub>0.3</sub>Ti<sub>1.7</sub>(PO<sub>4</sub>)<sub>3</sub> Solid Electrolytes Enabled by a Sulfone-Based Crystalline Organic Interlayer. [PDF]
Han S, Zhu L, Yu M, Tang W, Chen J.
europepmc +1 more source
Flexible photocatalytic materials: From substrate engineering to multi‐field synergistic enhancement
This review examines flexible photocatalytic systems, covering substrate evolution from polymers to biomass, fabrication methods like electrospinning, and key mechanical and optoelectrochemical metrics under deformation. Enhancement strategies are critically discussed, followed by applications in energy conversion, environmental remediation, and ...
Weiqi Wang +3 more
wiley +1 more source
Hydrogen peroxide-assisted oxidative desulfurization: mechanisms and catalytic perspectives. [PDF]
Ali-Zade A +4 more
europepmc +1 more source
ABSTRACT Organisms in human living spaces are surrounded by a variety of engineered substances. These chemical compounds have unexpected effects on the environment and human health. In particular, workers in industries face the risk of a health hazard caused by high‐dose or long‐term exposure to chemicals in the workplace.
Masahiro Tomioka
wiley +1 more source
4-Fluorophenyl Tagging as a Diagnostic Tool for Monitoring Sulfur Oxidation States via 19F NMR. [PDF]
Williams ML, Patel TI, Moschitto MJ.
europepmc +1 more source
Abstract BACKGROUND The new European Union Wastewater Directive 2024/3019 requires upgrading sewage treatment plants to achieve 80% removal of micropollutants. This study aimed to compare different Powdered Activated Carbon dosing strategies within a hybrid Moving Bed‐Membrane Bioreactor (PAC‐MB‐MBR) system, to evaluate its performance and to study the
Athanasia Iliopoulou +8 more
wiley +1 more source
An Evaluation of the Inhibitory Effect of Apatinib on Ilaprazole Metabolism: in vitro, in vivo and in silico Study. [PDF]
Li R +6 more
europepmc +1 more source
Repurposing antimicrobial agents for neuroprotection: Mechanisms, clinical potential, and challenges
Antimicrobial agents exert neuroprotective effects through modulation of interconnected pathways. Tetracyclines, macrolides, antimalarial agents, sulfones, and antiparasitic agents suppress neuroinflammation, oxidative stress, and apoptosis while preserving mitochondrial function and neurotransmission.
Mohammad Amin Manavi +5 more
wiley +1 more source
Ergosterol-Dependent Membrane Stress and Calcineurin-HSP90 Signaling Govern Fluorinated Sulfone-Induced Cell Death in Candida albicans. [PDF]
Staniszewska A +5 more
europepmc +1 more source

