Results 181 to 190 of about 45,088 (258)
This review surveys the emerging role of copper(I) catalysis in sustainable synthesis, highlighting its exceptional capacity for monoelectronic processes. By examining the strategies based on electron, halogen, and hydrogen transfer processes (SET, XAT, and HAT, respectively), we outline key reactivity trends, design principles, and the synthetic ...
Antonio Torres‐Calis +1 more
wiley +1 more source
Omeprazole activation of CD4+ and CD8+ T-cells through off-target covalent modification of cellular proteins. [PDF]
Grice S +16 more
europepmc +1 more source
Selective E/Z isomerization of diaryl methoximes is achieved by the careful selection of a photosensitizer despite the small triplet‐energy differences between structurally and electronically similar E and Z isomers. The isomer‐enriched diaryl methoximes undergo site‐selective C(sp2)–H functionalization to furnish densely functionalized products ...
Yuki Hirata +4 more
wiley +1 more source
Strategically significant synthesis of conjugated porous organic polymers via retro diazotization chemistry. [PDF]
Ozer MS, Eroglu Z, Koyuncu S, Metin O.
europepmc +1 more source
An iridium‐catalyzed linear‐selective sp3 C─H alkylation of N‐methylamides with alkenes is described. This method tolerates various N‐methylacetamide derivatives and has a broad alkene scope. Mechanistic studies were also conducted. Internal alkenes can also be used through in situ consecutive alkene isomerization.
Haluhi Takahashi, Takanori Shibata
wiley +1 more source
4-Anilinoquinazoline carbamate derivatization as a platform for prodrug design and localized drug delivery. [PDF]
Carpio MB +9 more
europepmc +1 more source
Synthesis of (E)‐β‐SF5‐Styrenes via a Heck Reaction of in situ Generated Vinylsulfur Pentafluoride†
A Heck cross‐coupling reaction between aryl(hetero)iodides and in situ generated vinylsulfur pentafluoride is reported. This reaction provides β‐SF5‐styrenes in one‐step as a single (E)‐stereoisomer and tolerates a broad range of functional groups. Comprehensive Summary The synthesis of (E)‐(1‐alken‐1‐yl)pentafluoro‐λ6‐sulfanes, a valuable class of ...
Nicolas DeGrâce +1 more
wiley +1 more source
Nickel-catalyzed divergent sulfonations of propargylic carbonate. [PDF]
Gu W, He Z, Wang H, Peng L, Guo C.
europepmc +1 more source
Recent Progress on Enzyme Immobilization: Materials, Strategies, and Applications
Enzyme immobilization technology has undergone substantial evolution driven by advances in materials science. This review systematically examines the recent advances in enzyme immobilization since 2024, with a focused analysis of five major categories of enzyme carriers including covalent organic framework, metal‐organic frameworks, polymers, carbon ...
Shuran Wang +7 more
wiley +1 more source
Evaluation of Passive Air Sampling for Monitoring Current-Use Pesticide Pollution near Large-Scale Banana Plantations in Costa Rica. [PDF]
Solano Díaz K +5 more
europepmc +1 more source

