Results 201 to 210 of about 32,232 (288)

Contrasting Solution and Gas‐Phase: Understanding Structure and Reactivity of Gold‐Diazenyl Intermediates

open access: yesHelvetica Chimica Acta, EarlyView.
Xx xx. Abstract Gold(I)‐catalyzed cross‐coupling reactions with aryldiazonium salts are instrumental in forming C─C and C─N bonds. However, mechanistic details remain unclear, particularly the role of diazenyl intermediates. We employ stoichiometric reactions, NMR spectroscopy, electrospray ionization mass spectrometry, and infrared photodissociation ...
Florian Ruepp   +4 more
wiley   +1 more source

Structural design and property regulation of organic polymers for photocatalytic synthesis of H2O2

open access: yesInfoScience, EarlyView.
Photocatalytic synthesis of H2O2 offers a sustainable approach. Photocatalytic efficiency depends critically on interfacial electron transfer kinetics and spatial charge separation. Herein, we systematically analyze key factors governing photogenerated carrier dynamics and propose engineered strategies to optimize performance, thereby providing design ...
Mingyang Xu   +8 more
wiley   +1 more source

Elementary Steps in Olefin Metathesis: Nickelacyclobutanes via Cycloaddition to Nickel Carbenes. [PDF]

open access: yesJ Am Chem Soc
Cormier SK   +5 more
europepmc   +1 more source

Contrasting functional responses of benthic and hyporheic stream biofilms to light availability and macronutrient stoichiometry

open access: yesLimnology and Oceanography, EarlyView.
Abstract Nutrient dynamics in headwater streams are governed by benthic and hyporheic biofilms, with carbon (C) : nitrogen (N) : phosphorus (P) ratios driving the heterotrophic microbial biofilm development through nutrient limitation. Furthermore, heterotrophic responses to changes in C : N : P ratios are probably modulated by autotrophic responses to
Anika Große   +8 more
wiley   +1 more source

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