Aryl and Alkyl Radiotrifluoromethylation via Metallaphotoredox‐Mediated Radical Cross‐Coupling
The metallaphotoredox‐mediated radiotrifluoromethylation of arenes and alkanes is described. The operationally simple protocols make use of substrates bearing thianthrenium salts (TT) or N‐hydroxyphthalimide (NHPI) esters and CF218FI. The reaction proceeds through a Ru‐mediated radical formation followed by a Cu‐mediated radical cross‐coupling step and
Lukas Veth +2 more
wiley +2 more sources
Sulfur fluoride exchange with carbon pronucleophiles. [PDF]
Novicki JR +6 more
europepmc +1 more source
Regiodivergent C3 and C4 Amination of Quinolines via Radical and Ionic Pathways
A regiodivergent strategy converts a single N‐aminoquinolinium precursor into either C3‐ or C4‐aminated quinolines. Nucleophile‐induced dearomatization diverges into light‐driven N‐centered radical capture (C3) or base‐promoted SNAr (C4), enabling rapid assembly of aminoquinoline libraries and late‐stage diversification.
Ye‐Eun Kim +3 more
wiley +2 more sources
Arylazo Sulfones as 1,3-Dipole Acceptors in the (Photo)-Micellar van Leusen Triazole Synthesis. [PDF]
Volpe C +11 more
europepmc +1 more source
Two dicarbadodecaborane(12)‐based dual cyclooxygenase‐2/5‐lipoxygenase (COX‐2/5‐LO) inhibitors were 123I‐labeled. Refinement of labeling and formulation conditions and extensive in vitro characterization are presented. Cell uptake studies in COX‐2‐ and 5‐LO‐overexpressing cell lines showed COX‐2‐independent and partly 5‐LO‐dependent uptake.
Jonas Schädlich +11 more
wiley +1 more source
Balanced Ionic Conductivity and Permselectivity of Cation Exchange Membranes Prepared from Sulfonated Poly(ether sulfone). [PDF]
Srour HK +6 more
europepmc +1 more source
Structure-reactivity based control of radical-mediated degradation in thiol-Michael hydrogels.
Kirkpatrick BE +7 more
europepmc +1 more source
The Intersecting Physical Mechanisms That Regulate Cell Viability in 3D Synthetic Hydrogels. [PDF]
Richbourg NR +4 more
europepmc +1 more source
Node-Solution Microenvironment Governs the Selectivity of Thioanisole Oxidation within Catalytic Zr-Based Metal-Organic Framework. [PDF]
Ghuffar HA, Masood Z, Wang B, Noh H.
europepmc +1 more source

