Results 11 to 20 of about 60,682 (387)
Chloroaluminate ionic liquid bound on magnetic nanoparticles (Fe3O4@O2Si[PrMIM]Cl·AlCl3) was prepared and used as a heterogenous Lewis acidic catalyst for the Friedel–Crafts sulfonylation of aromatic compounds with sulfonyl chlorides or p-toluenesulfonic
Ngoc-Lan Thi Nguyen+5 more
doaj +1 more source
Synthetic exploration of sulfinyl radicals using sulfinyl sulfones
Sulfinyl radicals – one of the fundamental classes of S-centered radicals – have eluded synthetic application in organic chemistry for over 60 years, despite their potential to assemble valuable sulfoxide compounds.
Zikun Wang+7 more
semanticscholar +1 more source
Oxidation of sulfide to sulfone is a fundamental process to produce many important pharmaceutical compounds. Formerly, efficient methods have been reported for the synthesis of sulfones from sulfides.
Wei Lam Wan+5 more
doaj +1 more source
A chemoselective procedure for MCPBA oxidation of 26-thiodiosgenin to corresponding sulfoxides and sulfone was elaborated. An unusual equilibration of sulfoxides in solution was observed.
Aneta M. Tomkiel+5 more
doaj +1 more source
Dissimilation of C3-sulfonates [PDF]
Cysteate and sulfolactate are widespread natural products in the environment, while propanesulfonate, 3-aminopropanesulfonate and propane-1,3-disulfonate are xenobiotics. While some understanding of the bacterial assimilation of cysteate sulfur has been achieved, details of the dissimilation of cysteate and sulfolactate by microbes together with ...
Cook, Alasdair M.+2 more
openaire +8 more sources
A highly efficient and eco-friendly method has been developed for the synthesis of allyl sulfones using Morita–Baylis–Hillman (MBH) adducts and thiosulfonates under mild conditions.
Angothu Shankar+2 more
doaj +1 more source
The redox transformations and nucleophilic replacements as possible metabolic reactions of the drug “Triazaverin”. The chemical modeling of the metabolic processes [PDF]
As a model of metabolic transformations of antiviral drug “Triazaverin” and its analogues‑2-alkylthio‑6-nitro‑1,2,4-triazolo[5,1-c][1,2,4]triazine‑7-ones 1a-d examined the oxidation of alkylthio groups to the corresponding sulfoxides 2a-d and sulfones 3a-
Medvedeva, N. P.+3 more
core +3 more sources
Palladium-catalyzed sulfonylative coupling of benzyl(allyl) carbonates with arylsulfonyl hydrazides
An efficient palladium-catalyzed sulfonylative coupling for the synthesis of benzyl(allyl) sulfones from sulfonyl hydrazides and carbonates was developed.
Bozhen Gong+8 more
doaj +1 more source
Microbial Degradation of the Sulfonate of Dodecyl Benzene Sulfonate [PDF]
It has been observed that the sulfonate portion of alkyl benzene sulfonate (ABS) will undergo microbial attack in certain pure and mixed cultures if an energy source, such as glucose, is available. The evidence for this is provided by the stoichiometric relationship between the reduction of ABS concentration and the appearance of inorganic sulfur ...
Melvin A. Benarde+3 more
openaire +3 more sources
Hetero-Diels–Alder reactions of hetaryl and aryl thioketones with acetylenic dienophiles [PDF]
Selected hetaryl and aryl thioketones react with acetylenecarboxylates under thermal conditions in the presence of LiClO4 or, alternatively, under high-pressure conditions (5 kbar) at room temperature yielding thiopyran derivatives.
Grzelak, Paulina+4 more
core +4 more sources