Visible-Light Assisted Covalent Surface Functionalization of Reduced Graphene Oxide Nanosheets with Arylazo Sulfones [PDF]
We present an environmentally benign methodology for the covalent functionalization (arylation) of reduced graphene oxide (rGO) nanosheets with arylazo sulfones. A variety of tagged aryl units were conveniently accommodated at the rGO surface via visible light irradiation of suspensions of carbon nanostructured materials in aqueous media. Mild reaction
arxiv +1 more source
The cesium carbonate-mediated reaction of 2-bromoallyl sulfones and ortho-hydroxychalcones furnished 3-arylsulfonyl-4H-chromene derivatives in 58–67% yield (18 examples).
Srinivas Thadkapally+2 more
doaj +1 more source
Cleaning ability of mixed solutions of sulfonated fatty acid methyl esters [PDF]
Here, we present results from a systematic study on cleaning of oily deposits from solid surfaces (porcelain and stainless steel) by solutions of fatty acid sulfonated methyl esters (SME), sodium salts. The zwitterionic dodecyldimethylamine oxide (DDAO) has been used as a cosurfactant.
arxiv +1 more source
Direct Synthesis of Allylic Sulfones via Hydrosulfonylation of 1,3-Dienes with Sulfinic Acids. [PDF]
Catalyst- and additive-free reactions for synthesizing valuable organic compounds have garnered significant attention in the context of sustainable development.
Guo K+5 more
europepmc +2 more sources
Electrochemical Degradation of Per- and Polyfluoroalkyl Substances (PFAS) using Low-cost Graphene Sponge Electrodes [PDF]
Boron-doped, graphene sponge anode was synthesized and applied for the electrochemical oxidation of C4-C8 per and polyfluoroalkyl substances (PFASs). Removal efficiencies, obtained in low conductivity electrolyte (1 mS cm-1) and one-pass flow-through mode, were in the range 16.7-67% at 230 A m-2 of anodic current density, and with the energy ...
arxiv +1 more source
Background Heteronucleophiles as well as carbanionic reagents can be used to react with α-amido sulfones, thus giving the opportunity to prepare a large array of amino derivatives.
Wang Zhenchao+6 more
doaj +1 more source
Pearlnecklacelike chain conformation of hydrophobic polyelectrolyte: a SANS study of partially sulfonated polystyrene in water [PDF]
The form factor of partially sulfonated polystyrene PSSNa (degree of sulfonation f =1, 0.72, 0.64 and 0.36), at polymer concentration 0.17M and 0.34M, without or with added salt (0 M, 0.34M, & 0.68M), is measured by Small Angle Neutron Scattering using the Zero Average Contrast method. The total scattering function is also measured, allowing extracting
arxiv +1 more source
Benzhydryl phenyl sulfone [PDF]
In the title compound, C(19)H(16)O(2)S, the sulfur-bound phenyl group is approximately parallel to one of the two phenyl rings of the benzhydryl group, making a dihedral angle of 12.53 (10)°, and forms a dihedral angle of 41.25 (9)° with the other phenyl ring. In the crystal, weak C-H⋯O inter-actions form a two-dimensional network propagating along the
Mahiuddin Baidya+2 more
openaire +4 more sources
Sulfur analysis of Bolu-Mengen lignite before and after microbiological treatment using reductive pyrolysis and gas chromatography/mass spectrometry [PDF]
Atmospheric pressure-temperature programmed reduction coupled with on-line mass spectrometry (AP-TPR/MS) is used for the first time on microbiologically treated coal samples as a technique to monitor the degree of desulfurization of the various sulfur ...
Bozdemir T.+27 more
core +1 more source
Photocatalytic formation of carbon–sulfur bonds
This review summarizes recent developments in photocatalyzed carbon–sulfur bond formation. General concepts, synthetic strategies and the substrate scope of reactions yielding thiols, disulfides, sulfoxides, sulfones and other organosulfur compounds are ...
Alexander Wimmer, Burkhard König
doaj +1 more source