Results 11 to 20 of about 17,437 (312)

Transfer of electrophilic NH using convenient sources of ammonia: direct synthesis of N–H sulfoximines from sulfoxides [PDF]

open access: yes, 2016
The transfer of nitrogen atoms is extremely valuable in the preparation of medicinal compounds. Here, a new system for NH transfer is developed to prepare sulfoximines, which are emerging as valuable motifs for drug discovery.
Bentley   +43 more
core   +1 more source

Enantiomeric oxidation of organic sulfides by the filamentous fungi Botrytis cinerea, Eutypa lata and Trichoderma viride [PDF]

open access: yes, 2007
The biotransformations of a series of substituted sulfides were carried out with the filamentous fungi Botrytis cinerea, Eutypa lata and Trichoderma viride.
Annunziata   +28 more
core   +2 more sources

Degradation of lansoprazole and omeprazole in the aquatic environment [PDF]

open access: yes, 2006
Lansoprazole and omeprazole degrade in water leading to sulfides, benzimidazolones and a red complex material. Degradation is accelerated in acid medium and by solar simulator irradiation.
BRIGANTE M.   +5 more
core   +1 more source

Electrochemical oxidations of thioethers: Modulation of oxidation potential using a hydrogen bonding network

open access: yesElectrochemistry Communications, 2019
A highly efficient chemo-selective electrochemical oxidation of thioethers to sulfoxides and sulfones was developed. The hydrogen bonding network generated from hexafluoro-2-propanol (HFIP) and acetic acid (AcOH) plays an important role in the modulation
Shiwen Liu   +6 more
doaj   +1 more source

Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts [PDF]

open access: yes, 2012
Organometallic complexes of halogen metallic salts have been used as catalysts in different organic reactions, mainly the oxidation of organic compounds. Their use has not only allowed the reduction of the amounts of catalyst (since they can be reused)
Rossi, Laura Isabel   +1 more
core   +1 more source

Highly Efficient Selective Oxygenation of Sulfides to Sulfoxides by Oxalic Acid Dihydrate in the Presence of H2O2

open access: yesE-Journal of Chemistry, 2012
A highly efficient method for the oxidation of sulfides to sulfoxides using oxalic acid dihydrate in the presence of hydrogen peroxide has been developed.
Masoud Mokhtary   +2 more
doaj   +1 more source

EFFECT OF PROPELLER MIXER TURNS NUMBER ON THE SULFIDES OXIDATION RATE IN THE OIL PHASE IN A MIXING REACTOR

open access: yesИзвестия высших учебных заведений: Проблемы энергетики, 2019
The effect of the rotation number of the propeller mixer on the concentration of sulfoxide sulfur in the oil fraction of Arlan oil during the oxidation of this fraction sulfides with hydrogen peroxide along with an acid catalyst, a mixture of formic and ...
R. E. Lipantyev, V. P. Tutubalina
doaj   +1 more source

Membrane-free selective oxidation of thioethers with water over a nickel phosphide nanocube electrode

open access: yesCell Reports Physical Science, 2021
Summary: Developing a membrane-free oxidation reaction, especially using water as the oxygen source, to generate high-value chemicals with high selectivity for replacing low-value O2 over a cost-effective catalyst is significant.
Shuyan Han   +6 more
doaj   +1 more source

Can acyclic conformational control be achieved via a sulfur-fluorine gauche effect? [PDF]

open access: yes, 2015
The gauche conformation of the 1,2-difluoroethane motif is known to involve stabilising hyperconjugative interactions between donor (bonding, σC-H) and acceptor (antibonding, σ*C-F) orbitals.
Daniliuc, C   +4 more
core   +1 more source

Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives [PDF]

open access: yes, 2003
DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work ...
Barkley, James V.   +3 more
core   +1 more source

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