Results 11 to 20 of about 5,141 (265)

Dibenzyl sulfoxide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2010
There are two independent mol-ecules in the asymmetric unit of the title compound, C(14)H(14)OS, which have asymmetric S-C bonds [1.791 (5) and 1.804 (5) Å in one mol-ecule and 1.798 (5) and 1.804 (5) Å in the other]. The long axes of the mol-ecules are directed along the crystallographic b axis.
Hai-Yang Liu   +3 more
openaire   +3 more sources

Sulfoxides in medicine

open access: yesCurrent Opinion in Chemical Biology, 2023
In the review, current status of sulfoxides on the pharmaceutical market is discussed. In the first part of the article, natural sulfoxides will be described with a special focus on sulforaphane and amanitin, a mushroom toxin which has been developed as payload in antibody drug conjugates in the possible cancer treatment.
Elżbieta Wojaczyńska   +1 more
openaire   +2 more sources

Electrochemical oxidations of thioethers: Modulation of oxidation potential using a hydrogen bonding network

open access: yesElectrochemistry Communications, 2019
A highly efficient chemo-selective electrochemical oxidation of thioethers to sulfoxides and sulfones was developed. The hydrogen bonding network generated from hexafluoro-2-propanol (HFIP) and acetic acid (AcOH) plays an important role in the modulation
Shiwen Liu   +6 more
doaj   +1 more source

EFFECT OF PROPELLER MIXER TURNS NUMBER ON THE SULFIDES OXIDATION RATE IN THE OIL PHASE IN A MIXING REACTOR

open access: yesИзвестия высших учебных заведений: Проблемы энергетики, 2019
The effect of the rotation number of the propeller mixer on the concentration of sulfoxide sulfur in the oil fraction of Arlan oil during the oxidation of this fraction sulfides with hydrogen peroxide along with an acid catalyst, a mixture of formic and ...
R. E. Lipantyev, V. P. Tutubalina
doaj   +1 more source

Membrane-free selective oxidation of thioethers with water over a nickel phosphide nanocube electrode

open access: yesCell Reports Physical Science, 2021
Summary: Developing a membrane-free oxidation reaction, especially using water as the oxygen source, to generate high-value chemicals with high selectivity for replacing low-value O2 over a cost-effective catalyst is significant.
Shuyan Han   +6 more
doaj   +1 more source

Desulfurization of Dibenzothiophene and Oxidized Dibenzothiophene Ring Systems

open access: yesMolecules, 2010
Lithium, used in conjunction with sodium metal, produces a high yield of biphenyl when reacted with dibenzothiophene, dibenzothiophene sulfoxide or dibenzothiophene sulfone.
Diego P. Morales   +2 more
doaj   +1 more source

Sulfur-Containing Monoterpenoids as Potential Antithrombotic Drugs: Research in the Molecular Mechanism of Coagulation Activity Using Pinanyl Sulfoxide as an Example

open access: yesFrontiers in Pharmacology, 2018
In this article we present the synthesis of enantiomerically pure sulfoxide and study the influence of this compound on hemostasis. Detailed NMR studies and molecular dynamics simulations using sodium dodecyl sulfate (SDS) membrane models indicated that ...
Liliya E. Nikitina   +13 more
doaj   +1 more source

Deep eutectic solvent mediated controlled and selective oxidation of organic sulfides and hydroxylation of arylboronic acids

open access: yesCurrent Research in Green and Sustainable Chemistry, 2021
A mild and efficient protocol has been developed for the controlled oxidation of wide variety of organic sulfides to corresponding sulfoxides using deep eutectic solvent (DES) as catalyst and hydrogen peroxide as oxidant under ambient condition.
Apurba Dutta   +4 more
doaj   +1 more source

Inhibition of methionine sulfoxide reduction by dimethyl sulfoxide

open access: yesBMB Reports, 2009
Dimethyl sulfoxide (DMSO) is widely used in chemistry and biology as a solvent and as a cryoprotectant. It is also used as a pharmaceutical agent for the treatment of interstitial cystitis and rheumatoid arthritis. Previous reports described DMSO as being reduced by methionine-S-sulfoxide reductase (MsrA).
Geun-Hee, Kwak   +3 more
openaire   +3 more sources

The applicability of sulfoxide Michael acceptor – 2­-(S)-­[(4­-methylphenyl)sulfinyl]-­2­-cyclopenten­-1­-one in constructing the carbon skeleton of 9,11­-secosterols [PDF]

open access: yesProceedings of the Estonian Academy of Sciences
A possibility of use of the Michael addition reaction of the A,B­-ring fragment enolate to sulfoxide 2­-(S)-­[(4­-methylphenyl)sulfinyl]-­2­-cyclopenten­-1­-one for constructing the main skeleton of 9,11­-secosterols was studied.
Kristi Rõuk   +3 more
doaj   +1 more source

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