Results 21 to 30 of about 9,711 (311)
A new one-pot synthesis of heterocyclic and carbocyclic vinyl sulfoxides has been developed which involves reaction of α-phosphorylvinyl sulfoxides with carbonyl compounds bearing oxygen, nitrogen, and carbon nucleophilic centers. Use of optically active
Marian Mikołajczyk (1520032) +4 more
core +3 more sources
An improved analytical method was developed for identifying sulfide compounds from aromatic fractions in Lungu atmospheric residue (LGAR). Sulfides in residue aromatics were selectively oxidized into sulfoxides using tetrabutyl ammonium periodate (TBAP ...
Wenlong Cui +3 more
doaj +1 more source
Inhibition of methionine sulfoxide reduction by dimethyl sulfoxide
Dimethyl sulfoxide (DMSO) is widely used in chemistry and biology as a solvent and as a cryoprotectant. It is also used as a pharmaceutical agent for the treatment of interstitial cystitis and rheumatoid arthritis. Previous reports described DMSO as being reduced by methionine-S-sulfoxide reductase (MsrA).
Geun-Hee, Kwak +3 more
openaire +3 more sources
The applicability of sulfoxide Michael acceptor – 2-(S)-[(4-methylphenyl)sulfinyl]-2-cyclopenten-1-one in constructing the carbon skeleton of 9,11-secosterols [PDF]
A possibility of use of the Michael addition reaction of the A,BÂ-ring fragment enolate to sulfoxide 2Â-(S)-Â[(4Â-methylphenyl)sulfinyl]-Â2Â-cyclopentenÂ-1Â-one for constructing the main skeleton of 9,11Â-secosterols was studied.
Kristi Rõuk +3 more
doaj +1 more source
NaSH·H2O and 37% aqueous solution of HCl were employed in reduction of sulfoxides to sulfides at room or elevated temperature in the absence of organic reducing agent and solvent-free reaction conditions. Operationally simple transformation took place in
Anže Zupanc, Marjan Jereb
doaj +1 more source
A Novel, Facile and Selective Synthesis of Sulfoxides Catalyzed by CuFe2O4/PEO-SO3H as a Reusable Heterogeneous Nanocatalyst [PDF]
In the present work, poly(ethylene oxide) (PEO) coated sulfonated copper ferrite nanoparticles were successfully used as an efficient, green, easy-to-use, magnetic, reusable, bimetallic, environment-friendly, and heterogeneous solid acid catalyst in the ...
Mojtaba Azizi +2 more
doaj +1 more source
Hydrogenative Kinetic Resolution of Vinyl Sulfoxides
Enantiopure sulfoxides are valuable precursors of organosulfur compounds with a broad application in organic and pharmaceutical chemistry. An unprecedented strategy for obtaining highly enantioenriched sulfoxides based on a hydrogenative kinetic ...
Fernández-Pérez, Hector +2 more
core +2 more sources
Highly Enantioselective Oxidations of Ketene Dithioacetals Leading to Trans Bis-sulfoxides
Ketene dithioacetals undergo a Sharpless-type asymmetric oxidation using (+)-DET, Ti(OiPr)4, and cumene hydroperoxide to give the trans bis-sulfoxides 4a−f with essentially complete control of enantioselectivity and diastereoselectivity.
Juliet K. Barrell (3046146) +4 more
core +1 more source
Flow electrosynthesis of sulfoxides, sulfones, and sulfoximines without supporting electrolytes [PDF]
An efficient electrochemical flow process for the selective oxidation of sulfides to sulfoxides and sulfones and of sulfoxides to N-cyanosulfoximines has been developed.
Wirth, Thomas, Amri, Nasser
core +1 more source
A click chemistry approach based on the reaction between alkynylflavins and mono(6-azido-6-deoxy)-β-cyclodextrin has proven to be a useful tool for the synthesis of flavin-cyclodextrin conjugates studied as monooxygenase mimics in enantioselective ...
Petra Tomanová +3 more
doaj +1 more source

