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Tetraethynylbenzo[2,1,3]thiadiazole [PDF]
The synthesis and structural characterization of peralkynylated benzothiadiazole 2 is reported. The synthesis utilizes Vollhardt's access to hexaethynylbenzene by coupling different alkynes to tetrabromobenzo[2,1,3]thiodiazole via the Heck-Cassar-Sonogashira-Hagihara reaction.
Carlito G. Bangcuyo+2 more
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Synthesis of novel thiadiazoles and bis-thiadiazoles from carbonothioic dihydrazide
Tetrahedron Letters, 2010Efficient syntheses of 1,3,4-thiadiazoles and bis-thiadiazoles by the reaction of hydrazonoyl halides with carbonothioic dihydrazide are reported. In addition, 1,2,4-triazolo[3,4-b][1,3,4]thiadiazole is obtained via oxidative cyclization of bis-(substituted methylene)carbonothioic dihydrazone.
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1965
Publisher Summary 1,2, 4-thiadiazole derivatives have recently found important uses and have attained industrial and economic importance. The syntheses of 1,2,4-thiadiazoles are classified according to the nature of the fragments, from which the heterocyclic ring is built.
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Publisher Summary 1,2, 4-thiadiazole derivatives have recently found important uses and have attained industrial and economic importance. The syntheses of 1,2,4-thiadiazoles are classified according to the nature of the fragments, from which the heterocyclic ring is built.
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ChemInform Abstract: 1,2,4‐THIADIAZOLE 20. MITT. 3‐AMINO‐THIADIAZOLE
Chemischer Informationsdienst. Organische Chemie, 1970AbstractSchwefelung der Acylguanidine (I) und anschließende Behandlung mit Wasserstoffperoxid liefern durch dehydrierende Cyclisierung der zunächst gebildeten Thioacylguanidine (II) die Aminothiadiazole (III) mit sehr unterschiedlichen Ausbeuten ( 1‐76%).
Joachim Goerdeler, Peter R. Mertens
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2015
[288-92-6] C2H2N2S (MW 86.11) InChI = 1S/C2H2N2S/c1-3-2-5-4-1/h1-2H InChIKey = YGTAZGSLCXNBQL-UHFFFAOYSA-N (prepared from 5-bromo-1,2,4-thiadiazole) Alternate Name(s): 1-thia-2,4-diazacyclopentadiene; 2,4-diazathiophene. Physical Data: mp −33 to −35 °C, bp753 120.7–121.2 °C, d 1.3298 g mL−1 at 20 °C, 1.5316; λmax 229 nm ...
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[288-92-6] C2H2N2S (MW 86.11) InChI = 1S/C2H2N2S/c1-3-2-5-4-1/h1-2H InChIKey = YGTAZGSLCXNBQL-UHFFFAOYSA-N (prepared from 5-bromo-1,2,4-thiadiazole) Alternate Name(s): 1-thia-2,4-diazacyclopentadiene; 2,4-diazathiophene. Physical Data: mp −33 to −35 °C, bp753 120.7–121.2 °C, d 1.3298 g mL−1 at 20 °C, 1.5316; λmax 229 nm ...
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ChemInform Abstract: Multiple 1,2,3‐Thiadiazoles.
ChemInform, 1997AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Norbert Hanold+2 more
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Synthesis of 1,3,4-thiadiazole oligomers
Journal of the Chemical Society, Perkin Transactions 1, 2002AbstractFor Abstract see ChemInform Abstract in Full Text.
Charles W. Rees+2 more
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2015
[288-48-2 C2H2N2S (MW 86.12) InChI = 1S/C2H2N2S/c1-2-5-4-3-1/h1-2H InChIKey = UGUHFDPGDQDVGX-UHFFFAOYSA-N (heteroaromatic compound, precursor to thiirenes) Physical Data: bp 98 °C, mp −28 °C. Alternate Name: 2,3-diazathiophene. Handling: compound known to possess potent biological activities in humans.
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[288-48-2 C2H2N2S (MW 86.12) InChI = 1S/C2H2N2S/c1-2-5-4-3-1/h1-2H InChIKey = UGUHFDPGDQDVGX-UHFFFAOYSA-N (heteroaromatic compound, precursor to thiirenes) Physical Data: bp 98 °C, mp −28 °C. Alternate Name: 2,3-diazathiophene. Handling: compound known to possess potent biological activities in humans.
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2008
This chapter deals with new developments in the field of 1,2,3-thiadiazoles updating the second edition covering the period 1996 to 2006. Developments in structure determination, especially X-ray structures, have been reported along with new reactions of both the fully aromatic and reduced ring systems.
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This chapter deals with new developments in the field of 1,2,3-thiadiazoles updating the second edition covering the period 1996 to 2006. Developments in structure determination, especially X-ray structures, have been reported along with new reactions of both the fully aromatic and reduced ring systems.
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2008
This chapter deals with new developments in the field of 1,2,4-thiadiazoles, covering the period 1996–2006, updating CHEC-II(1996). Developments in structure determination, especially X-ray structures, have been reported along with new reactions of both the fully aromatic and reduced ring systems. New examples of established methods of preparation have
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This chapter deals with new developments in the field of 1,2,4-thiadiazoles, covering the period 1996–2006, updating CHEC-II(1996). Developments in structure determination, especially X-ray structures, have been reported along with new reactions of both the fully aromatic and reduced ring systems. New examples of established methods of preparation have
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