Results 21 to 30 of about 10,152 (212)

Efficient NiOx Hole Transport Layers Enabled by Multifunctional MXenes for High‐Performance Tin‐Lead Perovskite Solar Cells

open access: yesAdvanced Functional Materials, EarlyView.
An efficient NiOx HTL is successfully prepared by introducing MXene as an additive without further surface modification to fabricate high‐performance FASn0.5Pb0.5I3 perovskite solar cells. The introduction of MXene contributes to improved conductivity of NiOx, better aligned at NiOx/perovskite interfaces, and enhanced quality of perovskite films ...
Lijun Chen   +12 more
wiley   +1 more source

Amyloidogenic Peptide Fragments Designed From Bacterial Collagen‐like Proteins Form Hydrogel

open access: yesAdvanced Functional Materials, EarlyView.
This study identified amyloidogenic sequence motifs in bacterial collagen‐like proteins and exploited these to design peptides that self‐assemble into β‐sheet fibers and form hydrogels. One hydrogel supported healthy fibroblast growth, showing promise for biocompatible materials. Our work demonstrates that bacterial sequences can be harnessed to create
Vamika Sagar   +5 more
wiley   +1 more source

Otto Billeter or How the Oldest [3,3]-Sigmatropic Rearrangement went to Neuchâtel, Part 2 Otto Billeter oder wie die älteste [3,3]-sigmatrope Umlagerung nach Neuenburg kam: Teil 2

open access: yesCHIMIA, 2000
The historical survey of the uncatalyzed, thermal rearrangement of thiocyanates into isothiocyanates is continued, starting with a review of Otto Billeter's scientific and social career in Neuchâtel. A specific look is taken at 1925 where Ludwig
Hans-Jürgen Hansen
doaj   +2 more sources

Ultrasound-promoted synthesis of novel fused heterocycles by criss-cross cycloaddition

open access: yesJournal of Saudi Chemical Society, 2016
This work reports a novel and highly efficient methodology for the synthesis of perhydrotriazolotriazoledithions from two successive 1,3-dipolar cycloaddition under ultrasound irradiation.
Javad Safari   +2 more
doaj   +1 more source

Performance Constraints of All‐Perovskite Tandem Solar Cells in Low‐Intensity, Low‐Temperature Environments

open access: yesAdvanced Materials, EarlyView.
All‐perovskite tandem solar cells are evaluated under low‐intensity and low‐temperature (LILT) conditions relevant to space environments. Distinct loss regimes emerge, where weaker entropic mixing causes halide segragation below ≈240 K going along with a strong current imbalance, while poor electron transport in C60 dominates.
Sercan Ozen   +10 more
wiley   +1 more source

Nonheme Fe Enzyme‐Catalyzed Enantiodivergent Nitrogen Migration: Directed Evolution and Computational Study of Isopenicillin N Synthases for Biocatalytic Synthesis of Arylglycines

open access: yesAngewandte Chemie, EarlyView.
Nonheme Fe enzyme isopenicillin N synthase was reprogrammed and evolved as an efficient nitrogen migratase IPNSNim, converting diverse azanyl esters to valuable l‐arylglycines with up to 16 000 TTN and 97:3 e.r. IPNSNim and ACCONim allowed enantiodivergent preparation of both l‐ and d‐arylglycines.
Ken Lin   +7 more
wiley   +2 more sources

Al-MCM-41: An Efficient and Recyclable Heterogeneous Catalyst for the Synthesis of β-Hydroxy Thiocyanates in Water

open access: yesJournal of Chemistry, 2013
An efficient and green procedure has been developed for the synthesis of β-hydroxy thiocyanate by the regioselective ring opening of epoxides with NH4SCN.
Soheil Sayyahi   +2 more
doaj   +1 more source

[3,3]-Sigmatropic Rearrangements of Fluorinated Allyl (Thio)cyanates – A Tool for the Synthesis of Fluorinated (Thio)ureas

open access: yesCHIMIA, 2014
The first (thio)cyanate to iso(thio)cyanate rearrangements based on 2-fluoroallylic alcohols are presented. Long-chain 2-fluoroallylic alcohols were converted to corresponding N-unsubstituted carbamates by treatment with trichloroacetyl ...
Daniel C. Ramb, Lisa Kost, Günter Haufe
doaj   +1 more source

Ionic Liquid‐Enhanced 3D Printed Flexible Resin for Pressure‐Sensing Applications

open access: yesAdvanced Materials Technologies, EarlyView.
A 3D‐printed resin–ionic liquid (IL) composite forms gyroid ionotronic architectures showing dynamic ionic migration under compression. Impedance analysis reveals distinct frequency responses across three topologies at high IL concentrations.
Nelson Pereira   +4 more
wiley   +1 more source

Predictive, Data‐Driven Design of Red‐Light Photoredox Catalysts for C─Heteroatom Bond Formation

open access: yesAngewandte Chemie, EarlyView.
From redox numbers to red light: Donor oxidation and core reduction potentials predict E0‐0 in cyanoarene dyes, guiding selection of an efficient red‐light catalyst, 4MeODPATPN (PC13). Under 620 nm light, PC13 facilitates Ni‐catalyzed C─heteroatom cross‐couplings (C─N, C─O, C─S) with high functional‐group tolerance and reduced hydrodehalogenation ...
Amir Gizatullin   +6 more
wiley   +2 more sources

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