Selectfluor-initiated cyanation of disulfides to thiocyanates
A Selectfluor-initiated cyanation of disulfides to thiocyanates has been developed. In this process, Selectfluor was employed as the oxidant and trimethylsilyl cyanide was used as the cyanation reagent.
Peng Zhou, Chuan-Fu Chen, Shubai Li
semanticscholar +1 more source
Polarity of domain boundaries in nonpolar materials derived from order parameter and layer group symmetry [PDF]
Domain boundaries and other twin boundaries in crystalline materials are receiving increasing interest. They can carry unique functional properties, which in many cases are absent in the surrounding bulk material. One such property of domain boundaries can be their electric polarity.
arxiv +1 more source
The Effect of Thiocyanate Concentration on Thiocyanate Distribution and Excretion
SummaryIt has been observed in rats that the measured volume of distribution of thiocyanate is decreased by high plasma concentrations of thiocyanate, and that large doses of thiocyanate have a faster rate of disappearance from the plasma than does endogenous thiocyanate at normal concentrations. These observations are interpreted as results of (i) the
Cullie F. Funderburk+1 more
openaire +3 more sources
Investigations on the Formation of 4-Aminobicyclo[2.2.2]-octanones
Benzylidene acetone reacts with thiocyanates derived from secondary amines in a one-pot reaction to give 4-aminobicyclo[2.2.2]octan-2-ones. The reaction mixture was investigated for the presence of possible intermediates using GC-MS.
Robert Weis+5 more
doaj +1 more source
Effect of Different Device Parameters on Tin Based Perovskite Solar Cell Coupled with In2S3 Electron Transport Layer and CuSCN and Spiro-OMeTAD Alternative Hole Transport Layers for High Efficiency Performance [PDF]
SCAPS 1-D was used for the simulation of lead-free environmentally benign methylammonium tin-iodide (CH3NH3SnI3) based solar cell. Indium sulphide (In2S3) was utilized as the electron transport layer (ETL) for its high carrier mobility and optimized band structure, unlike traditional titanium oxide (TiO2) ETL.
arxiv +1 more source
The Role of Specific Ion Effects in Ion Transport: The Case of Nitrate and Thiocyanate [PDF]
The selective transport of trivalent rare earth metals from aqueous to organic environments with the help of amphiphilic "extractants" is an industrially important process. When the amphiphilic extractant is positively charged or neutral, the coextracted background anions are not only necessary for charge balance but also have a large impact on ...
arxiv +1 more source
Synthesis and biological evaluation of novel urea and thiourea derivatives of valacyclovir [PDF]
A series of novel urea and thiourea derivatives of valacyclovir were efficiently synthesized in high yields and evaluated their antiviral activity.
Katla Ramana Venkata+4 more
doaj +1 more source
Aryl hydrocarbon receptor activation during in vitro and in vivo digestion of raw and cooked broccoli (brassica oleracea var. Italica) [PDF]
Broccoli is rich in glucosinolates, which can be converted upon chewing and processing into Aryl hydrocarbon Receptor (AhR) ligands. Activation of AhR plays an important role in overall gut homeostasis but the role of broccoli processing on the ...
Capuano, Edoardo+11 more
core +3 more sources
N-Bromosulphonamides, synthesized via direct bromination of sulphonamides, react with several types of arene substrates in the presence of KSCN to afford aryl thiocyanates. The method appears to be generally applicable to benzenoid substrates with a wide
Ardeshir Khazaei+2 more
doaj +1 more source