The impressive colors of the bis-aminostyrylbenzopyrylium system. Evidence by stopped-flow for the B4 formation at pH>13 [PDF]
Funding Information: This work was supported by the Associate Laboratory for Green Chemistry - LAQV (UIDB/50006/2020) which is financed by national funds from FCT/MCTES and by the AgriFood XXI I&D&I project (NORTE-01-0145-FEDER-000041) co-financed by ...
Araújo, Paula +8 more
core +1 more source
DBS-Based Eutectogels: Organized Vessels to Perform the Michael Addition Reaction** [PDF]
Supramolecular eutectogels were obtained from the gelation of 1,3 : 2,4-dibenzylidene-D-sorbitol (DBS) in cholinium chloride-based deep eutectic solvents (DES), differing for the nature of the hydrogen bond donor.
Benaglia M. +3 more
core +1 more source
Királis koronaéterekkel katalizált enantioszelektív szintézisek és ''deracemizációs'' reakciók vizsgálata = Investigation of enantioselective synthesis and deracemization reactions by chiral crownethers [PDF]
A monoszacharidokból felépülő királis koronaéterek aszimmetrikus indukciót képesek kifejteni bizonyos reakciókban, ha királis fázistranszfer katalizátorként alkalmazzuk azokat.
Bakó, Péter +5 more
core
Binding of the five multistate species of the anthocyanin analog 7- β -D-glucopyranosyloxy-4′-hydroxyflavylium to the β -cyclodextrin derivative captisol [PDF]
The host-guest chemistry of the anthocyanin analog 7-β-D-glucopyranosyloxy-4'-hydroxyflavylium (GHF) was studied in the presence of the β-cyclodextrin derivative captisol by stopped flow, UVevisible spectroscopy, flash photolysis, circular dichroism and ...
Al Bittar, Sheiraz +5 more
core +2 more sources
Rapid Structural Analysis of Natural Products Using MicroED
The cryoEM method, MicroED used for rapid analysis and structure determination of natural products that remained unattainable by other structural biology methods ABSTRACT Structural analysis of natural products remains challenging due to their inherent complexity and limited availability.
Jieye Lin +3 more
wiley +1 more source
(E)-1-(2-Aminophenyl)-3-(thiophen-2-yl)prop-2-en-1-one
The molecule of the title heteroaryl chalcone derivative, C13H11NOS, exists in a trans-configuaration and is almost planar with a dihedral angle of 3.73 (8)° between the phenyl and thiophene rings. An intramolecular N—H...O hydrogen bond
Suchada Chantrapromma +3 more
doaj +1 more source
Revisiting the Juliá–Colonna enantioselective epoxidation : supramolecular catalysis in water [PDF]
We describe an efficient epoxidation process leading to chiral epoxyketones using the reusable homo-oligopeptide poly-L-leucine (PLL) in pure water, without any organic co-solvent. A range of substituted epoxyketones can be accessed with good conversions
Barbeau, Xavier +3 more
core +1 more source
Improved Longan Genome Assembly Reveals Insights Into Flowering Mechanisms
ABSTRACT Longan is an exotic tropical fruit crop and exhibits off‐season flowering induced by potassium chlorate (KClO3), though the molecular mechanisms remain unclear. We assembled a high‐quality, 441.5 Mb genome of variety ‘Shixia’, with a contig N50 at 28.1 Mb, 29, 325 protein‐coding genes, 26 telomeres and 15 centromeres.
Guochun Zhao +14 more
wiley +1 more source
CHALCONES: THE PROMISING COMPOUNDS TO PROVIDE NEW WAYS FOR CANCER TREATMENT [PDF]
Chalcones (1,3-diphenylpropen-1-ones), a biosynthetic product of the shikimate pathway, belonging to flavanoid family are precursors of open chain flavonoids and isoflavonoids, which are abundant in edible plants.
Retno, Arianingrum
core
Liquorice has a long history of use in traditional Chinese, Ayurvedic and herbal medicine. The liquorice plant contains numerous bioactive compounds, including triterpenes, flavonoids and secondary metabolites, with glycyrrhizin being the main active ...
Bell, Rae Frances +3 more
core +2 more sources

