Results 151 to 160 of about 225,375 (330)
Isoleucine and Valine Metabolism in Escherichia coli
H. E. Umbarger, Barbara Brown
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Constitutional isomers of fluoro‐tryptophan alter the stability of the β‐hairpin peptide Trpzip2 by tuning key CH/π and NH/π interactions. Abstract The stability of pairwise tryptophan (Trp) edge‐to‐face aromatic interactions has been exploited in the design of small tryptophan zipper (Trpzip) peptides.
David Reiter+6 more
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The Ascent of Supramolecular Polymers and Gels in Asymmetric Catalysis
SPs and gels emerged as modular platforms for asymmetric catalysis. This review ranks literature reports according to the achiral or chiral nature of the monomers bearing the catalytic site. New paradigms showcased by this approach are particularly highlighted, such as catalysts operating with a low amount of chiral inducers, or with no chiral inducer,
Ran Chen+2 more
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Identification of a New Interesting BAG3 Modulator Able to Disrupt Cancer‐Related Pathways
Continuing our research aimed at discovering new BAG3 modulators as attractive anticancer drug candidates, we performed a screening campaign on an in‐house library, including compounds featuring a large variety of scaffolds. The obtained results induced us to focus on the triazole moiety and, following a stepwise structural refinement of the scaffold ...
Dafne Ruggiero+10 more
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Vibrational Partition Functions from Bond Order and Populations Relationships
A new computational model is presented that predicts vibrational partition functions using bond orders and populations relationships (QBOP). This model demonstrates that thermochemical energy contributions can be reasonably approximated based on well‐conditioned orbital populations without the need for a costly Hessian calculation.
Barbaro Zulueta, John A. Keith
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Bombyx Mori Silk Fibroin as a Sustainable Organocatalyst for Diastereoselective Michael Additions
Silk fibroin, natural biopolymer, has been successfully used as green catalyst for Michael addition reactions under mild conditions. Its pseudoenzymatic pocket enables enzyme‐like catalytic behavior, driving stereoselectivity, and highlighting a sustainable, nature‐inspired catalytic approach.
Carola Ricciardelli+8 more
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THE SPECIFICITY OF THE LEUCINE, ISOLEUCINE, AND VALINE REQUIREMENTS OF LACTOBACILLUS ARABINOSUS 17-5
D.M. Hegsted
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The role of valine in the biosynthesis of penicillin N and cephalosporin C by a Cephalosporium sp. [PDF]
S. C. Warren, GGF Newton, E. P. Abraham
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Utilizing the power of the absorbance‐activated droplet sorter, a key enzyme for a cell‐free multienzymatic cascade for sustainable isobutanol biosynthesis is optimized for improved thermostability and isobutanol tolerance required for efficient cascade performance.
Mariko Teshima+6 more
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Synthetic cannabinoid receptor agonists are being infused on paper and illicitly introduced into prisons through mail correspondence. An approach to quantify and map the synthetic cannabinoid 5F‐ADB on a seized paper sample from a UK prison was determined using ultraperformance liquid chromatography–quadrupole Dalton–mass spectrometry.
Giorgia Vaccaro+4 more
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