Construction of spirocycles containing highly substituted pyrroli-dine and 1-indanone motifs with spiro quaternary stereogenic centers via 1,3-dipolar cycloaddition of 2-alkylidene-1-indanone and azomethine ylides promoted by simple imidazolium salts [PDF]
The 1,3-dipolar cycloaddition of 2-alkylidene-1-indanone with azomethine ylides has been developed successfully promoted by simple imidazolium salts to construct a variety of spirocycles containing highly substituted pyrrolidines efficiently, affording ...
Hu, Wei-Qiang +8 more
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For the first time, arylmethylidene cyclohexanones that are non-symmetrical due to the presence of peripheral substituents were studied in 1,3-dipolar cycloaddition reactions.
Alexander Anis’kov +3 more
doaj +1 more source
Synthesis of Different Heterocyclic Compounds of Pharmaceutical Relevance [PDF]
This thesis describes the synthesis of different cyclic imines and the exploration of their reactivity with cyclopropenones and 1,3-dipoles,as well as an investigation of the chemistry of the products.
Khan, Musharraf Naveed
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Estudo das reações do acido de meldrum a bases de Schiff aromaticas [PDF]
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciencias Fisicas e MatematicasOs compostos imínicos possuem reatividade semelhante a dos compostos carbonílicos, ambos apresentam ligações heteropolares insaturadas.
Rosa, Flavia Aparecida Fernandes da
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Controlling Asymmetric Remote and Cascade 1,3-Dipolar Cycloaddition Reactions by Organocatalysis [PDF]
The regio- and stereoselective control of cycloaddition reactions to polyconjugated systems has been demonstrated by applying asymmetric organocatalysis.
Stefania Vergura (2745067) +4 more
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An efficient synthesis of 1,3-diaryl-4-halo-1H-pyrazoles was achieved. The synthesis involves the [3 + 2] dipolar cycloaddition of 3-arylsydnones and 2-aryl-1,1-dihalo-1-alkenes. The process proceeds smoothly in moderate to excellent yields. 1,3-Diaryl-4-
Yiwen Yang +4 more
doaj +1 more source
Metal-catalyzed 1,3-dipolar cycloaddition reactions of nitrile oxides [PDF]
In the present review advances in the metal-catalyzed 1,3-dipolar cycloaddition reactions of nitrile oxides, mainly in the last decade, will be presented and discussed. An overview on the structure, preparation, dimerization and related reactions as well
Roscales García, Silvia +3 more
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The Reactivity of Addends in the 1,3-Dipolar Cycloaddition Reaction [PDF]
The influence of donor-acceptor interactions and localisation energies on the reactivity of addends in the 1,3-dipolar cycloaddition reaction is examined.
Samuilov Y., Konovalov A.
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Synthesis of oxetane/azetidine containing spirocycles via the 1,3-dipolar cycloaddition reaction [PDF]
Silver catalyzed 1,3-dipolar cycloaddition reactions between methyl 2-(oxetane/azetidine-3 ylidene) acetate as dipolarophiles and imines derived from –amino acid methyl esters, 2-aminomethyl pyridine and 2-aminomethyl pyrazine afforded oxetane/azetidine ...
Proud, M, Jones, B, Sridharan, V
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Some new N-substituted pyridazinones and triazolo[4,3-b]pyridazinones were synthesized, respectively, by simple alkylation and 1,3-dipolar cycloaddition of pyridazin-3-one with nitrile imines.
Souad Mojahidi +6 more
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