Covalent Organic Functionalization of Graphene Nanosheets and Reduced Graphene Oxide via 1,3-Dipolar Cycloaddition of Azomethine Ylide [PDF]
Nanoscale Advances, 3, 2021, 5841-5852, 2021 Organic functionalization of graphene is successfully performed via 1,3-dipolar cycloaddition of azomethine ylide in the liquid phase. The comparison between 1-methyl-2-pyrrolidinone and N,N-dimethylformamide as dispersant solvents, and between sonication and homogenization as dispersion techniques, proves N,N-dimethylformamide and homogenization as ...
arxiv +1 more source
The Azide-Allene Dipolar Cycloaddition: Is DFT Able to Predict Site- and Regio-Selectivity?
Molecules, 2021 The site- and regio-selectivity of thermal, uncatalysed 1,3-dipolar cycloadditions between arylazides and mono- or tetra-substituted allenes with different electronic features have been investigated by both conceptual (reactivity indices) and ...
Giorgio Molteni, Alessandro Ponti
doaj +1 more source
ChemInform Abstract: Iridium‐Catalyzed 1,3‐Dipolar Cycloadditions [PDF]
ChemInform, 2010 AbstractReview: 47 refs.
Carmona, Daniel, Oro, Luis A.
openaire +4 more sources
Nanoparticle‐Catalysed 1,3‐Dipolar Cycloadditions
European Journal of Organic Chemistry, 2020 The 1,3‐dipolar cycloadditions of azomethine‐ylides and ‐imines, nitrones, nitrilimines, and azides catalysed by inorganic nanoparticles are described. Emphasis is given to the nanometric catalysts involved, their structure, characterisation, and recyclability and, when remarkable, their preparation.
Ponti A., Molteni G.
openaire +4 more sources
Cycloadditions with 2-Chloro-1-Nitroethylene
CHIMIA, 1975 2-chloronitroethylene replaces successfully the still elusive unsubstituted nitroacetylene in both the 1,3-dipolar and Diels-Alder cycloadditions. These reactions generally afford interesting nitrated cyclic and heterocyclic compounds.
R. Verbruggen, H.G. Viehe
doaj +1 more source
1,3-Dipolar cycloadditions of 2-thio-3-chloroacrylamides with nitrile oxides and nitrones [PDF]
, 2010 1,3-Dipolar cycloadditions of 2-thio-3-chloroacrylamides with nitrile oxides and nitrones is described. A series of novel isoxazolines are isolated from the nitrile oxide cycloadditions, whilst the isoxazolines generated from the nitrone cycloadditions ...
Kissane, Marie +2 more
core +1 more source
Molecules, 2001 The ZnBr2 complex of the title compound has been studied by both structural and theoretical methods. Similar reactivities have been observed for the nitrone alone and the complex in 1,3-dipolar cycloadditions and nucleophilic additions.
Tomas Tejero +5 more
doaj +1 more source
Intramolecular Cycloaddition of Imines of Cysteine Derivatives
Molecules, 1998 Azomethine ylides were generated from Schiffs bases of S-allylcysteine methyl ester and their intramolecular 1,3-dipolar cycloadditions were studied. These reactions led to the synthesis of thieno[3,4-b]pyrrole derivatives in good yield.
Teresa M. V. D. Pinho e Melo +2 more
doaj +1 more source
Conformer-specific polar cycloaddition of dibromobutadiene with trapped propene ions [PDF]
, 2021 Diels-Alder cycloadditions are efficient routes for the synthesis of cyclic organic compounds. There has been a long-standing discussion whether these reactions proceed via stepwise or concerted mechanisms. Here, we adopt a new experimental approach to explore the mechanistic details of the model polar cycloaddition of 2,3-dibromo-1,3-butadiene with ...
arxiv +1 more source
Discovery of new mutually orthogonal bioorthogonal cycloaddition pairs through computational screening. [PDF]
, 2015 Density functional theory (DFT) calculations and experiments in tandem led to discoveries of new reactivities and selectivities involving bioorthogonal sydnone cycloadditions.
Houk, KN +3 more
core +1 more source