Results 201 to 210 of about 762 (252)

Flow Chemistry Meets Green Solvents: Telescoped Synthesis of Triazolyl Phosphoramidates and Phosphinamides in γ‐Valerolactone

ChemSusChem, Volume 19, Issue 9, 14 May 2026.
A telescoped three‐step continuous flow process enables the synthesis of organophosphorus 1,2,3‐triazoles in the biomass‐derived solvent γ‐valerolactone (GVL). The sequence integrates N‐phosphorylation, azidation, and Cu(I)‐catalyzed azide–alkyne cycloaddition (CuAAC), followed by in‐line copper removal, giving diverse triazoles in good to high overall
Viktória Gerő, Dániel Steinsits, Pál Tamás Szabó, Erika Bálint   +3 more
wiley   +1 more source

Desymmetrization of Pseudo‐para Diformyl[2.2]Paracyclophane via Brønsted Acid‐Catalyzed Reductive Amination

Advanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
A highly stereoselective desymmetrization of pseudo‐para diformyl[2.2]paracyclophanes is developed via chiral Brønsted acid‐catalyzed reductive amination. This protocol provides efficient access to enantiopure planar chiral paracyclophanes with broad substrate scope, excellent enantioselectivity, and versatile postsynthetic functionalization. Access to
Sandip Baban Shinde, Martin Kamlar, Vojtěch Dočekal, Ivana Císařová, Jan Veselý   +4 more
wiley   +1 more source

Intrabandgap States Engineering in Functionalized Nanodiamond to Generate Solvated Electrons for Photocatalysis Under Solar Illumination

Advanced Functional Materials, Volume 36, Issue 37, 7 May 2026.
The negative electron affinity of diamond allows to emit highly reductive electrons. By introducing intra‐bandgap states and an optimized electron transfer mechanism by surface functionalization with Ru(bpy)3, the formation of solvated electrons is achieved upon solar irradiation.
Benjamin Kiendl, Arsène Chemin, Adam H. Day, Rocio B. Rodriguez, Sneha Choudhury, Franziska Buchner, Kaan Atak, Christoph Merschjann, Emina Hadzifejzovic, Tim D. W. Claridge, Karin Larsson, Amélie Venerosy, Mailis M. Lounasvuori, Natalia Zabarska, Boyan Iliev, Thomas J. S. Schubert, Hugues A. Girard, Jean‐Charles Arnault, John S. Foord, Tristan Petit, Anke Krueger   +20 more
wiley   +1 more source

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A Review on Synthetic Approaches and Activities of 1, 2, 4-Triazoles

Research Journal of Pharmacy and Technology, 2022
1, 2, 4-Triazoles and their derivatives have a distinct place in the field of medicinal and pharmaceutical chemistry. These are used as lead compounds for the synthesis of numerous heterocyclic compounds which possess diverse biological activities and play pivotal roles. This review covers the latest literature and knowledge on the synthetic procedures
Mahavir Singh, H. Sawarkar, Birendra Shrivastav, Bakal Bakal   +3 more
openaire   +1 more source

Reaction of 3-amino-1:2:4-triazole with lactoperoxidase

Archives of Biochemistry and Biophysics, 1973
Bovine lactoperoxidase (LPO) gradually lost its enzymatic activity when dialyzed against a solution of 3-amino-1:2:4-triazole (AT) and hydrogen peroxide at pH 7.0. Amino acid analysis of the completely inactive enzyme revealed the formation of a new ninhydrin-positive chromatographic peak.
J Y, Chang, W A, Schroeder
openaire   +2 more sources

Synthesis of some nitro and amino derivatives of 1, 2, 4-triazole-5-thiones and 1, 2, 4-triazoles

Chemistry of Heterocyclic Compounds, 1967
Isomeric 3-(nitrophenyl)-1, 2, 4-triazole-5-thiones are synthesized by cyclizing 1-nitrobenzoylthiosemicarbazides. 1-(4-Nitrophenyl)-1, 2, 4-triazole-3-thione is prepared by condensing 4-(4-nitrophenyl) thiosemicarbazide with formic acid. Oxidation converts the triazolethiones to nitrophenyltriazoles, and the latter are reduced to aminophenyltriazoles.
G. I. Chipen, D. E. Duka, V. Ya. Grinshtein   +2 more
openaire   +1 more source

1 : 2 : 4-triazole as a corrosion inhibitor for copper

Corrosion Science, 1980
Abstract The solution chemistry of 1 : 2 : 4-triazole (TRZ) is investigated in the range of solution concentrations in which the compound acts as a corrosion inhibitor for copper. Parallel photo-electron spectroscopic studies show that although a surface layer of Cu(I) complex is formed at low TRZ concentrations, this is ineffective as an inhibitor ...
P.G. Fox, P.A. Bradley
openaire   +1 more source

Basicity and structure of 1, 2, 4-triazole derivatives

Chemistry of Heterocyclic Compounds, 1967
Basicity constants for a number of 1, 2, 4-triazole derivatives are determined. An assumed amine structure for 3-amino-1, 2, 4-triazoles in aqueous solution is demonstrated. It is assumed that protonization of 3- and 4-amino-1, 2, 4-triazoles occurs at the nitrogen in the heterocyclic ring, and not at the amino group.
L. I. Bagal, M. S. Pevzner, V. A. Lopyrev   +2 more
openaire   +1 more source

Inhibition of Cholinesterases by 1 : 2 : 4-Triazoles

Nature, 1955
IT has been repeatedly observed in my laboratory that workers, including non-smokers, manipulating 1 : 2 : 4-triazoles develop symptoms of light nicotine or physostigmine poisoning from time to time. Subsequent experiments have shown that some simple water-soluble 1 : 2 : 4-triazoles may act as inhibitors of cholinesterase activity.
openaire   +1 more source

1, 2, 4 - triazole-aldehydes

1962
Althouth many C-aldehydes of azoles and azines, including those of 1,2,3-triazoles, are known and readily obtainable, free aldehydes derived from 1,2,4-triazole do not appear to have been isolated previously. The main aim of the work submitted in this thesis was the synthesis of such 1,2,4-triazole-C-aldehydes.
openaire   +1 more source