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What evidence exists on the environmental occurrence and toxic effects of the tire additive 6PPD: a systematic map protocol [PDF]

open access: yesEnvironmental Evidence
Background The tire additive N-(1,3-dimethylbutyl)-Nʹ-phenyl-p-phenylenediamine (6PPD) is widely produced in large volumes as a rubber antidegradant. This chemical can be released into the environment throughout the lifecycle of rubber products. Recently,
Katryna J. Seabrook   +10 more
doaj   +2 more sources

Preparation of 2-((4-Methylpentan-2-Yl)amino)-5-(Phenylamino)cyclohexa-2,5-Diene-1,4-Dione (6PPD-Quinone), an Environmental Hazard for Salmon [PDF]

open access: yes, 2021
A recent report has identified 6PPD-quinone as an environmental compound responsible for drastic declines in coho salmon (Oncorhynchus kisutch) populations.
Alon, Agua   +2 more
core   +1 more source

Toxicological effects of 6PPD and 6PPD quinone in zebrafish larvae

open access: yesJournal of Hazardous Materials, 2022
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine (6PPD) is the most widely used antioxidant in automobile tyres and many rubber products. We investigated the impact of 6PPD and 6PPD quinone on acute toxicity, morphology, swimming behaviour, heart rate, and oxygen consumption in zebrafish larvae. Zebrafish embryos were exposed to 6PPD and 6PPD quinone
Shubham, Varshney   +4 more
openaire   +2 more sources

Reactive oxygen species and chromophoric dissolved organic matter drive the aquatic photochemical pathways and photoproducts of 6PPD-Quinone under simulated high-latitude conditions [PDF]

open access: yes, 2023
The photochemical degradation pathways of 6PPD-quinone (6PPDQ, 6PPD-Q), a toxic transformation product of the tire antiozonant 6PPD, were determined under simulated sunlight conditions typical of high-latitude surface waters.
Brian, DiMento   +4 more
core   +2 more sources

Presence of 6PPD-quinone in runoff water samples from Norway using a new LC–MS/MS method

open access: yesFrontiers in Environmental Chemistry, 2023
The chemical 6PPD-quinone is highly toxic to some fish species of the Oncorhynchus and Salvelinus genera and is the oxidation product of the common car tire additive 6PPD.
Fedor Kryuchkov   +4 more
doaj   +1 more source

Chiral perspective evaluations: Enantioselective hydrolysis of 6PPD and 6PPD-quinone in water and enantioselective toxicity to Gobiocypris rarus and Oncorhynchus mykiss

open access: yesEnvironment International, 2022
As a ubiquitous tire antidegradant, N-(1,3-dimethylbutyl)-N’-phenyl-p-phenylenediamine (6PPD) is persistently released into the environment. It is highly toxic to aquatic organisms, and its transformation product 6PPD-quinone (6PPD-Q), is “very highly ...
Shanshan Di   +8 more
doaj   +1 more source

Recycled silica as a renewable and sustainable alternative to carbon black in natural rubber foams

open access: yesPolymer International, Volume 72, Issue 12, Page 1104-1111, December 2023., 2023
Natural rubber foams were prepared by replacing petroleum‐based carbon black (CB) with recycled silica. The total filler concentration was fixed (40 phr), while the CB/silica ratio was changed. The results showed that recycled silica is a suitable alternative to CB producing superior mechanical and thermal properties compared to commercial silica ...
Ehsan Rostami‐Tapeh‐Esmaeil   +4 more
wiley   +1 more source

Computational studies of rubber ozonation explain the effectiveness of 6PPD as an antidegradant and the mechanism of its quinone formation [PDF]

open access: yes, 2022
The discovery that the commercial rubber antidegradant 6PPD reacts with ozone (\ce{O3}) to produce a highly toxic quinone (6PPDQ) spurred a significant research effort into non-toxic alternatives.
William, Hart-Cooper   +4 more
core   +2 more sources

A Horizon Scan to Support Chemical Pollution–Related Policymaking for Sustainable and Climate‐Resilient Economies

open access: yesEnvironmental Toxicology and Chemistry, Volume 42, Issue 6, Page 1212-1228, June 2023., 2023
A Delphi approach to horizon scan of emerging chemical pollution issues of concern shortlisted 15 priority topics spanning the broad themes of “green” chemicals, unregulated chemicals and emissions, susceptible populations, fibers and materials, and intersections with climate and artificial intelligence. AI = artificial intelligence.
Christopher Green   +32 more
wiley   +1 more source

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