Results 11 to 20 of about 123,983 (385)
Chemistry Proceedings, 2021 The aim of the research is the development of a one-pot method for the synthesis of lignans, natural compounds that show a wide spectrum of biological activities.
Pavel V. Kovyazin +3 more
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Metal-free visible-light-enabled vicinal trifluoromethyl dithiolation of unactivated alkenes
Beilstein Journal of Organic Chemistry, 2021 The difunctionalization of alkenes involving a trifluoromethylthio group (SCF3) for the conversion of versatile and readily available olefins into structurally more complex molecules has been successfully studied.
Xiaojuan Li +5 more
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From‐Neutral‐to‐Neutral Reductive Radical Coupling of Non‐Activated Alcohols and Styrenes
ChemistryEurope, 2023 A reductive radical coupling reaction between non‐activated aliphatic alcohols and styrenes has been discovered through the use of low‐valent Ti‐mediated C−O bond homolysis.
Dr. Takuya Suga +2 more
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Frontiers in Chemistry, 2020 Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD4 is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones.
Wanmei Li +6 more
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Stereo-Electronic Factors Influencing the Stability of Hydroperoxyalkyl Radicals: Transferability of Chemical Trends across Hydrocarbons and ab initio Methods [PDF]
Phys. Chem. Chem. Phys., 2023, 2023 The hydroperoxyalkyl radicals (.QOOH) are known to play a significant role in combustion and tropospheric processes, yet their direct spectroscopic detection remains challenging. In this study, we investigate molecular stereo-electronic effects influencing the kinetic and thermodynamic stability of a .QOOH along its formation path from the precursor ...
arxiv +1 more source
Millimetre and submillimetre spectroscopy of isobutene and its detection in the molecular cloud G+0.693 [PDF]
A&A 680, A25 (2023), 2023 Isobutene ((CH$_3$)$_2$C=CH$_2$) is one of the four isomers of butene (C$_4$H$_8$). Given the detection of propene (CH$_3$CH=CH$_2$) toward TMC-1, and also in the warmer environment of the solar-type protostellar system IRAS 16293$-$2422, one of the next alkenes, isobutene, is a promising candidate to be searched for in space.
arxiv +1 more source
Molecules, 2020 A theoretical analysis of the reaction of oxidative sulfamidation of several alkenes was performed in order to explain the various experimental observations and different reactivity of triflamide and non-fluorinated sulfonamides.
Anton V. Kuzmin +2 more
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Microbial synthesis of long-chain α-alkenes from methanol by engineering Pichia pastoris
Bioresources and Bioprocessing, 2022 α-Alkenes (terminal alkenes) are important fuel and platform chemicals that are mainly produced from petroleum. Microbial synthesis might provide a sustainable approach for α-alkenes.
Peng Cai +6 more
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A Data-Driven Machine Learning Approach for Electron-Molecule Ionization Cross Sections [PDF]
J. Phys. B 57, 025201 (2024), 2023 Despite their importance in a wide variety of applications, the estimation of ionization cross sections for large molecules continues to present challenges for both experiment and theory. Machine learning algorithms have been shown to be an effective mechanism for estimating cross section data for atomic targets and a select number of molecular targets.
arxiv +1 more source
Enantioselective Hydrogenations with Chiral Titanocenes
Molecules, 2005 In this review article chiral titanocenes and their application for the enantioselective hydrogenations of different unsaturated compounds are discussed, with a special emphasis on the kinetics and the practicality of the developed systems. The nature of
J. Khinast, A. Panarello, O. Vassylyev
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