Results 21 to 30 of about 195,903 (365)
Factors affecting the extent of branching in fischertropsch synthesis products with iron-based catalysts [PDF]
, 1989 Branched products are mainly formed during secondary isomerization reactions, and not in the main synthesis reaction itself. The extent of branching is a function of the catalyst formulation. High acidity and a low hydrogenation strength of the catalyst (
Snel, R.
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Cobalt-catalyzed nucleophilic addition of the allylic C(sp3)–H bond of simple alkenes to ketones
Beilstein Journal of Organic Chemistry, 2018 We herein describe a cobalt/Xantphos-catalyzed regioselective addition of simple alkenes to acetophenone derivatives, affording branched homoallylic alcohols in high yields with perfect branch selectivities.
Tsuyoshi Mita +3 more
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Palladium-Catalyzed N-Alkenylation of N-Aryl Phosphoramidates with Alkenes
Molecules, 2023 Versatile and concise Pd-catalyzed oxidative N-alkenylation of N-aryl phosphoramidates with alkenes is described in this study, a reaction that is of great significance but surprisingly unexploited.
Yu-An Li, Ge Wu, Jia Li
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Chemistry Proceedings, 2022 The data obtained by the authors in the field of chemistry of substituted borolanes and 2,3-dihydro-1H-boroles are summarized. The authors developed a selective method for the synthesis of five-membered boracarbocycles via transmetalation of ...
Liliya I. Tulyabaeva +2 more
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Nickel/Photo-Cocatalyzed Asymmetric Acyl-Carbamoylation of Alkenes.
Journal of the American Chemical Society, 2020 An unprecedented asymmetric acyl-carbamoylation of pendant alkenes tethered on aryl carbamic chlorides with both aliphatic and aromatic aldehydes has been developed via the cooperative catalysis of a chiral nickel-PHOX complex and tetrabutylammonium deca-
Pei Fan +3 more
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Metal-free syn-dioxygenation of alkenes [PDF]
, 2013 Reactions employing inexpensive reagents from sustainable sources and with low toxicity are becoming increasingly desirable from an academic and industrial perspective.
Ashikari +60 more
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Journal of the American Chemical Society, 2020 Electrochemistry grants direct access to reactive intermediates (radicals and ions) in a controlled fashion toward selective organic transformations. This feature has been demonstrated in a variety of alkene functionalization reactions, most of which ...
W. Zhang, Song Lin
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Amine catalysis for the organocatalytic diboration of challenging alkenes [PDF]
, 2016 © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The generation of in situ sp 2 –sp 3 diboron adducts has revolutionised the synthesis of organoboranes.
Althaus +35 more
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Iron-Catalyzed, Highly Regioselective Synthesis of alpha-Aryl Carboxylic Acids from Styrene Derivatives and CO2 [PDF]
, 2012 The iron-catalyzed hydrocarboxylation of aryl alkenes has been developed using a highly active bench-stable iron(II) precatalyst to give alpha-aryl carboxylic acids in excellent yields and with near-perfect regioselectivity. Using just 1 mol % FeCl2, bis(
Greenhalgh, Mark D., Thomas, Stephen P.
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Combined experimental and computational investigations of rhodium-catalysed C-H functionalisation of pyrazoles with alkenes [PDF]
, 2014 Detailed experimental and computational studies have been carried out on the oxidative coupling of the alkenes C(2)H(3)Y (Y=CO(2)Me (a), Ph (b), C(O)Me (c)) with 3-aryl-5-R-pyrazoles (R=Me (1 a), Ph (1 b), CF(3) (1 c)) using a [Rh(MeCN)(3)Cp*][PF(6)](2 ...
Algarra, Andrés G. +6 more
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