Results 21 to 30 of about 123,983 (385)

Metal-Free Direct C–H Functionalization of Quinoxalin-2(1H)-Ones to Produce 3-Vinylated Quinoxalin-2(1H)-Ones in the Presence of Alkenes

open access: yesFrontiers in Chemistry, 2021
A novel and efficient C3-H vinylation reaction with quinoxalin-2(1H)-one as the substrate, in the presence of alkenes, under metal-free conditions, is reported herein.
Rongcai Ding   +6 more
doaj   +1 more source

Greener and sustainable method for alkene epoxidations by polymer-supported Mo(VI) catalysts [PDF]

open access: yes, 2009
A polybenzimidazole supported Mo(VI) (PBI.Mo) catalyst has been prepared and characterised. The catalytic activities of the PBI.Mo catalyst in epoxidation of alkenes with tert-butyl hydroperoxide (TBHP) as an oxidant have been studied under different ...
Ambroziak, K.   +3 more
core   +2 more sources

Highly selective electrochemical hydrogenation of alkynes: Rapid construction of mechanochromic materials [PDF]

open access: yes, 2019
Electrochemical hydrogenation has emerged as an environmentally benign and operationally simple alternative to traditional catalytic reduction of organic compounds.
Ge, Haibo, Li, Bijin
core   +1 more source

Allylic alcohols and amines by carbenoid eliminative cross-coupling using epoxides or aziridines

open access: yesBeilstein Journal of Organic Chemistry, 2021
α-Lithiated terminal epoxides and N-(tert-butylsulfonyl)aziridines undergo eliminative cross-coupling with α-lithio ethers, to give convergent access to allylic alcohols and allylic amines, respectively.
Matthew J. Fleming, David M. Hodgson
doaj   +1 more source

Hydrofluorination of Alkenes: A Review

open access: yesChemistry – An Asian Journal, 2021
AbstractIn this minireview, we explore the different approaches used to perform the hydrofluorination reaction of alkenes. Contrary to other hydrohalogenation reactions, the hydrofluorination requires specific conditions due to the lower reactivity of HF.
Xavier Bertrand   +2 more
openaire   +5 more sources

A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes [PDF]

open access: yes, 2013
Frustrated Lewis pairs are compounds containing both Lewis acidic and Lewis basic moieties, where the formation of an adduct is prevented by steric hindrance.
Chernichenko, K.   +2 more
core   +1 more source

Direct C–H trifluoromethylation of di- and trisubstituted alkenes by photoredox catalysis

open access: yesBeilstein Journal of Organic Chemistry, 2014
Background: Trifluoromethylated alkene scaffolds are known as useful structural motifs in pharmaceuticals and agrochemicals as well as functional organic materials.
Ren Tomita   +3 more
doaj   +1 more source

High quality anti-relaxation coating material for alkali atom vapor cells [PDF]

open access: yesOptics Express, Vol. 18, Issue 6, pp. 5825-5830 (2010), 2009
We present an experimental investigation of alkali atom vapor cells coated with a high quality anti-relaxation coating material based on alkenes. The prepared cells with single compound alkene based coating showed the longest spin relaxation times which have been measured up to now with room temperature vapor cells.
arxiv   +1 more source

ChemInform Abstract: Cyanamidoselenenylation of Alkenes.

open access: yesChemInform, 1987
AbstractReaction of the alkenes (I) and (VIII) with cyanamide (II) and N‐phenylselenophthalimide (III) produces the β‐phenylselenocyanamides (IV), (V), (IX), and (X).
Hernández, Rosendo   +3 more
openaire   +4 more sources

Relative reactivities of alkenes toward the diphenylmethyl cation [PDF]

open access: yes, 1983
The relative reactivities of alkyl and phenyl substituted alkenes toward diphenylmethyl chloride/ZnCl2/Et2O in dichloromethane at −78°C have been determined by competition experiments.
Allen   +21 more
core   +1 more source

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