Results 41 to 50 of about 196,000 (337)

Modeling of Benzene with Ethylene Alkylation

open access: yesMATEC Web of Conferences, 2016
The paper considers the benzene alkylation with ethylene model development with the use of zeolite catalyst. A list of reactions occurring in the alkylation reactor was made and the thermodynamic possibility of determination of these reactions by the ...
Khlebnikova Elena   +3 more
doaj   +1 more source

Synthesis and structure of novel tripodal ligands based on tetrazol-5-thioles

open access: yesЖурнал Белорусского государственного университета: Химия, 2022
Novel tripodal ligands (R1N4CS)3CH, where R1 = Me, Ph, were synthesised by alkylation of 1-R-tetrazol-5-thioles with iodoform in alkaline media. These ligands were identified based on data of elemental analysis, nuclear magnetic resonance spectroscopy ...
Sergei V. Voitekhovich   +5 more
doaj   +1 more source

CDK11 inhibition induces cytoplasmic p21WAF1 splice variant by p53 stabilisation and SF3B1 inactivation

open access: yesMolecular Oncology, EarlyView.
CDK11 inhibition stabilises the tumour suppressor p53 and triggers the production of an alternative p21WAF1 splice variant p21L, through the inactivation of the spliceosomal protein SF3B1. Unlike the canonical p21WAF1 protein, p21L is localised in the cytoplasm and has reduced cell cycle‐blocking activity.
Radovan Krejcir   +12 more
wiley   +1 more source

Small molecule deoxynyboquinone triggers alkylation and ubiquitination of Keap1 at Cys489 on Kelch domain for Nrf2 activation and inflammatory therapy

open access: yesJournal of Pharmaceutical Analysis
Activation of nuclear factor erythroid 2-related factor 2 (Nrf2) by Kelch-like ECH-associated protein 1 (Keap1) alkylation plays a central role in anti-inflammatory therapy.
Ke-Gang Linghu   +12 more
doaj   +1 more source

Poly(1-vinyl-1,2,4-triazolium) poly(ionic liquid)s: synthesis and the unique behavior in loading metal ions

open access: yes, 2016
Herein we report the synthesis of a series of poly(4-alkyl-1-vinyl-1,2,4-triazolium) poly(ionic liquid)s either via straightforward free radical polymerization of their corresponding ionic liquid monomers, or via anion metathesis of the polymer ...
Yuan, Jiayin, Zhang, Weiyi
core   +1 more source

The preparation of ketene dithioacetals and thiophenes from chloropyridines containing an active methylene group [PDF]

open access: yes, 2010
The base catalysed reaction of carbon disulphide with the active methylene groups of chloropyridines 4 and 7, followed by alkylation with reagents which also contain active methylene groups, lead to ketene dithioacetals.
Bremner, David H.   +2 more
core   +3 more sources

Plecstatin inhibits hepatocellular carcinoma tumorigenesis and invasion through cytolinker plectin

open access: yesMolecular Oncology, EarlyView.
The ruthenium‐based metallodrug plecstatin exerts its anticancer effect in hepatocellular carcinoma (HCC) primarily through selective targeting of plectin. By disrupting plectin‐mediated cytoskeletal organization, plecstatin inhibits anchorage‐dependent growth, cell polarization, and tumor cell dissemination.
Zuzana Outla   +10 more
wiley   +1 more source

Experimental validation of computational fluid dynamic codes (CFD) for liquid-solid risers in clean alkylation processes [PDF]

open access: yesHemijska Industrija, 2002
This manuscript, based on the presentation given by one of the authors (M.P. Dudukovic) at the Technological and Engineering Forum in Pančevo, May 21 2002, summarizes the use of the computer automated radioactive particle tracking (CARPT) and gamma ...
Duduković Milorad P.   +3 more
doaj   +1 more source

Molecular Tuning of the Magnetic Response in Organic Semiconductors

open access: yes, 2017
The tunability of high-mobility organic semi-conductors (OSCs) holds great promise for molecular spintronics. In this study, we show this extreme variability - and therefore potential tunability - of the molecular gyromagnetic coupling ("g-") tensor with
Babak, Vladimir   +6 more
core   +2 more sources

Scalable synthesis of ionic liquids: comparison of performances of microstructured and stirred batch reactors [PDF]

open access: yes, 2012
A range of alkylpyridinium bromide ionic liquids have been synthesized in a stirred reactor at multigram scale and characterized by physical methods (viscosity, conductivity, melting point, electrochemical window, and water content).
Chaumat, Hélène   +5 more
core   +3 more sources

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