, 2023 We report the synthesis and characterization of novel alkyne-substituted deoxybenzoins that are setup for azide–alkyne cycloaddition chemistry to yield oligomeric and polymeric structures that exhibit useful thermal properties, both on their own and as ...
Chien-Han Chen (5117024) +2 more
core +6 more sources
Gamma Radiation Induced Contraction of Alkyne Modified Polymer Hydrogels [PDF]
, 2021 We describe the gamma radiation induced crosslinking of alkyne-modified dextran polymer gels. Crosslinking of the alkyne moieties leads to gel contraction and fusion with other gel objects, and can be used for controlled ...
Rienk, Eelkema +3 more
core +2 more sources
Experimental and Theoretical Elucidation of SPAAC Kinetics for Strained Alkyne-Containing Cycloparaphenylenes [PDF]
, 2022 Tuning strained alkyne reactivity via organic synthesis has evolved into a burgeoning field of study largely focused on cyclooctyne, wherein physical organic chemistry helps guide rational molecular design to produce molecules with intriguing properties.
Anna, Garrison +5 more
core +2 more sources
Untargeted identification of alkyne containing natural products using ruthenium catalyzed azide alkyne cycloaddition reactions coupled to LC-MS/MS. [PDF]
, 2021 Alkyne containing natural products have been identified from plants, insects, algae, fungi, and bacteria. This class of natural products have been characterized as having a variety of biological activities.
Daniel , Back +3 more
core +2 more sources
Alkynylzirconation of Alkynes and Application to One‐Pot Bisalkynylation of Alkynes. [PDF]
ChemInform, 2002 AbstractFor Abstract see ChemInform Abstract in Full Text.
Yuanhong, Liu +3 more
openaire +2 more sources
Alkyne-Tagged Raman Probes for Local Environmental Sensing by Hydrogen–Deuterium Exchange
, 2022 Alkyne-tagged Raman probes have shown high promise for noninvasive and sensitive visualization of small biomolecules to understand their functional roles in live cells.
Xiaotian Bi +5 more
core +1 more source
New catalytic strategies for DNA and RNA alkylation using rhodium (II) and copper (I) carbenes - a versatile tool for applications in chemical biology [PDF]
, 2015 A variety of nucleic acid substrates were catalytically alkylated with rhodium(II) and copper(I)-carbenoids generated from diazocarbonyl compounds. The alkylation took place via an N-H insertion reaction selectively targeting the nucleobases in single ...
Tishinov, Kiril
core +1 more source
Electrochemical Hydroboration of Alkynes [PDF]
Chemistry – A European Journal, 2021 AbstractHerein we reported the electrochemical hydroboration of alkynes by using B2Pin2 as the boron source. This unprecedented reaction manifold was applied to a broad range of alkynes, giving the hydroboration products in good to excellent yields without the need of a metal catalyst or a hydride source.
Maude Aelterman +3 more
openaire +2 more sources
Kinetic resolution of alkyne-substituted quaternary oxindoles via copper catalysed azide-alkyne cycloadditions [PDF]
, 2015 Kinetic resolution of alkyne-substituted quaternary oxindoles via copper catalysed azide-alkyne ...
William D.G. Brittain (7163375) +2 more
core +4 more sources
Mechanochemical Desymmetrization of Unbiased Bis- and Tris-alkynes to Access 3,5-Isoxazoles-Alkyne Adducts and Unsymmetrical Bis-3,5-isoxazoles [PDF]
, 2022 A mechanochemical desymmetrization of symmetrical bis- and tris-alkynes via a controlled 1,3-dipolar cycloaddition reaction with nitrile oxide dipoles has been developed.
Irini , Trakakis +5 more
core +2 more sources