A Platinum molecular complex immobilised on the surface of graphene as active catalyst in alkyne hydrosilylation [PDF]
A platinum complex bearing a N‐heterocyclic carbene (NHC) ligand functionalised with a pyrene‐tag is immobilised onto the surface of reduced graphene oxide (rGO).
Borja, Pilar +4 more
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The title compound, C17H14N2O, is built up from the planar benzodiazole unit linked to the benzyl and propynyl substituents. The substituents are rotated significantly out of the benzodiazole plane, where the benzyl group is inclined by 68.91 (7)° to the
Asmaa Saber +5 more
doaj +1 more source
Highly active iridium(I) complexes for the selective hydrogenation of carbon-carbon multiple bonds [PDF]
New iridium(I) complexes, bearing a bulky NHC/phosphine ligand combination, have been established as extremely efficient hydrogenation catalysts that can be used at low catalyst loadings, and are compatible with functional groups which are often ...
Andersson, Shalini +5 more
core +1 more source
Palladium-catalyzed cross coupling reactions of 4-bromo-6H-1,2-oxazines
A number of 4-aryl- and 4-alkynyl-substituted 6H-1,2-oxazines 8 and 9 have been prepared in good yields via cross coupling reactions of halogenated precursors 2, which in turn are easily accessible by bromination of 6H-1,2-oxazines 1. Lewis-acid promoted
Reinhold Zimmer +5 more
doaj +1 more source
One-pot multicomponent synthesis of 2,3-dihydropyrans: new access to furanose–pyranose 1,3-C–C-linked-disaccharides [PDF]
An efficient synthesis of 2,3-dihydropyrans starting from different terminal alkynes was developed. The 2,3-dihydropyrans were obtained in a few minutes through a microwave-assisted multicomponent enyne cross-metathesis/hetero-Diels–Alder reaction ...
Armstrong +28 more
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Recent developments in gold-catalyzed cycloaddition reactions
In the last years there have been extraordinary advances in the development of gold-catalyzed cycloaddition processes. In this review we will summarize some of the most remarkable examples, and present the mechanistic rational underlying the ...
Fernando López, José L. Mascareñas
doaj +1 more source
There is considerable attention directed at chemically modifying nucleic acids with robust functional groups in order to alter their properties. Since the breakthrough of copper-assisted azide-alkyne cycloadditions (CuAAC), there have been several ...
Wei Gong +2 more
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Facile and green synthesis of 3,5-disubstituted isoxazoles using doped nano-sized copper(I) oxide (Cu2O) on melamineâformaldehyde resin as an efficient nano-catalyst under ultrasonic irradiation [PDF]
In the present research, doped nano-sized copper(I) oxide (Cu2O) on melamine–formaldehyde resin as a heterogeneous and efficient nano-catalyst has been employed for green and mild synthesis of 3,5-disubstituted isoxazoles under ultrasonic irradiation. In
Somayeh Behrouz
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Noncanonical Amino Acids in the Interrogation of Cellular Protein Synthesis [PDF]
Proteins in living cells can be made receptive to bioorthogonal chemistries through metabolic labeling with appropriately designed noncanonical amino acids (ncAAs).
Ngo, John T., Tirrell, David A.
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(7R)-6-Methyl-7,9-bis(prop-2-yn-1-yl)-7H,8H,9H-1,2,4-triazolo[4,3-b][1,2,4]triazepin-8-one
In the title molecule, C12H11N5O, the seven-membered ring derived from triazepine adopts a boat conformation. Intermolecular C—H...N hydrogen bonds and C—H...π-ring interactions form columns of molecules parallel to the a axis, which are further ...
Youness El Bakri +5 more
doaj +1 more source

