Results 61 to 70 of about 824,863 (378)

Catalytic enantioselective synthesis of quaternary carbon stereocentres. [PDF]

open access: yes, 2014
Quaternary carbon stereocentres-carbon atoms to which four distinct carbon substituents are attached-are common features of molecules found in nature. However, before recent advances in chemical catalysis, there were few methods of constructing single ...
Overman, Larry E, Quasdorf, Kyle W
core  

Scalable Fabrication of Height‐Variable Microstructures with a Revised Wetting Model

open access: yesAdvanced Engineering Materials, EarlyView.
Height‐variable microstructures are fabricated using a scalable CO2 laser machining approach, enabling precise control of wettability through structural gradients. Classical wetting models fail to capture height‐induced effects, necessitating a revised theoretical framework.
Prabuddha De Saram   +2 more
wiley   +1 more source

Catalytic enantioselective intramolecular hydroamination of alkenes using chiral aprotic cyclic urea ligand on manganese (II)

open access: yesNature Communications
Asymmetric catalysis for enantioselective intramolecular hydroamination of alkenes is a critical method in the construction of enantioenriched nitrogen-containing rings, often prevalent in biologically active compounds and natural products.
Bin Cui   +6 more
doaj   +1 more source

Le limonène dans les huiles essentielles  : énantiomères et activités biologiques

open access: yesComptes Rendus. Chimie
Literature data are used to identify the enantiomeric diversity of limonene in 54 essential oils composed of between 0.3–99.7% of this molecule. Significant enantiomeric excesses are observed, either in (R)-(+)-, or in (S)-(–)-limonene, and more rarely ...
Aribi-Zouioueche, Louisa
doaj   +1 more source

Enantioselective Organocatalytic Singly Occupied Molecular Orbital Activation: The Enantioselective α-Enolation of Aldehydes [PDF]

open access: yes, 2007
The first enantioselective organocatalytic α-enolation of aldehydes has been accomplished using singly occupied molecular orbital (SOMO) catalysis.
Hong, Jun-Bae   +2 more
core   +1 more source

Key Trends and Insights in Smart Polymeric Skin Wearable Patches

open access: yesAdvanced Engineering Materials, EarlyView.
Intelligent polymers, which respond to various physical and biological stimuli, are explored for the development of skin wearable patches in biomedical applications. Smart polymers, also known as intelligent or stimuli‐responsive polymers, play a crucial role in the development of advanced wearable patches due to their versatility and softness.
Sergio J. Peñas‐Núñez   +2 more
wiley   +1 more source

Supramolecular asymmetric catalysis mediated by crown ethers and related recognition systems

open access: yesGreen Synthesis and Catalysis, 2021
In the past decades, the combination of supramolecular chemistry and catalysis has pushed forward the emergence of supramolecular catalysis as an intersectant and challenging research field.
Zibin Zhang   +5 more
doaj  

Heterogenisation of ketone catalysts within mesoporous supports for asymmetric epoxidation

open access: yes, 2013
The synthesis of the first mesoporous silica (150 Å) anchored carbohydrate-derived chiral ketone is described. This new heterogeneous catalyst has been shown to be effective in the asymmetric epoxidation of olefins by oxone.
Adam   +60 more
core   +1 more source

Non-catalytic bromination of benzene: a combined computational and experimental study [PDF]

open access: yes, 2015
The non-catalytic bromination of benzene is shown experimentally to require high 5-14M concentrations of bromine in order to proceed at ambient temperatures to form predominantly bromobenzene, along with detectable (The non-catalytic bromination of ...
Genaev, A   +4 more
core   +2 more sources

In Situ Constructed Magnetic Core‐Shell Hydrogen‐Bonded Organic Framework‐on‐Metal–Organic Framework Structure: an Efficient Catalyst for Peroxymonosulfate Activation

open access: yesAdvanced Functional Materials, EarlyView.
In this work, a magnetic core‐shell catalyst (HOF‐on‐Fe3O4/ZIF‐67) is successfully synthesized, consisting of a metal–organic framework (ZIF‐67) with magnetic Fe3O4 as the core and a porous hydrogen‐bonded organic framework (HOF) as the shell. The catalyst efficiently activated peroxymonosulfate, resulting in rapid and effective removal of water ...
Yingying Du   +4 more
wiley   +1 more source

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