Results 61 to 70 of about 37,655 (255)

Motif Editing for Reaction Pathway Switching From Formate to CO in Single‐Atom Indium Catalysts via Adjacent Carbon Site Manipulation

Advanced Functional Materials, EarlyView.
This work presents manipulation of adjacent carbon site in single‐atom indium catalysts via editing In‐N4 motif to In‐N2O2 for reaction pathway switching. Incorporation of O atoms leads to significant electron enrichment on the adjacent carbon sites surrounding the In‐N2O2 motif, which facilitates *COOH adsorption and CO formation with high selectivity.
Wenjing Zhao, Yichen Zhang, Xinwang Zhu, Lan Ran, Wenming Tong, Maoyu Wang, Hua Zhou, Shanyong Chen, Pau Farràs, Xiaoqing Qiu   +9 more
wiley   +1 more source

Synergistic Solar Interfacial Evaporation and Photocatalysis Enabled by a Hierarchical Porous Hydrogel Reactor

Advanced Functional Materials, EarlyView.
A tree‐inspired hydrogel interfacial reactor couples solar evaporation with photocatalysis for simultaneous desalination and waste water treatment. The bilayer design achieves 2.14 kg·m−2·h−1 evaporation rate with 79% dye degradation under one sun, demonstrating that photothermal heating and evaporation induced pollutant enrichment create a self ...
Yan Zhao, Xiaolong Ma, Zihong Wu, Muhammad Amjad, Dongsheng Wen   +4 more
wiley   +1 more source

Enhanced Tantalum Superconducting Resonator Performance via All‐Surface Organic Monolayer Passivation

Advanced Functional Materials, EarlyView.
The internal quality factor of tantalum superconducting resonators is significantly increased by ∼140% in the low photon regime by passivating their surfaces with a high‐quality alkene self‐assembled monolayer. Our methodology promises to enhance the performance of superconducting quantum circuits.
Harsh Gupta, Moritz Singer, Benedikt Schoof, Anna Cattani‐Scholz, Shreya Sharma, Luca Rommeis, Marc Tornow   +6 more
wiley   +1 more source

Abordagens em síntese assimétrica Approaches in asymmetric synthesis

Química Nova, 1998
The approaches in asymmetric synthesis as the chiron approach, chiral auxiliaries, chiral reagents and asymmetric catalysis are described in a simplified way.
Sergio Pinheiro, Vítor F. Ferreira
doaj   +1 more source

Targeting human MutT homolog 1 (MTH1) for cancer eradication: current progress and perspectives

Acta Pharmaceutica Sinica B, 2020
Since accelerated metabolism produces much higher levels of reactive oxygen species (ROS) in cancer cells compared to ROS levels found in normal cells, human MutT homolog 1 (MTH1), which sanitizes oxidized nucleotide pools, was recently demonstrated to ...
Yizhen Yin, Fener Chen
doaj   +1 more source

Biodegradable and Biocompatible Functional Polymers for Biomedical Applications

Advanced Functional Materials, EarlyView.
Biodegradable and biocompatible functional polymers integrate electrical, mechanical, and stimuli‐responsive functionalities while enabling programmed degradation under physiological conditions. This review introduces recent advances in conductive, shape‐memory, self‐healing, photocurable, and adhesive polymer systems, emphasizing material design ...
Won Bae Han, Shuvra Mondal, Sungkeun Han, Chan‐Hwi Eom, Venkata Ramesh Naganaboina, Suk‐Won Hwang   +5 more
wiley   +1 more source

Tuning Redox Dynamics in Cu‐Based Electrocatalysts: Effect of Secondary Metals

Advanced Functional Materials, EarlyView.
Advanced analysis of operando X‐ray absorption spectroscopy data reveals that secondary metals affect the redox processes in Cu‐based catalysts for electrocatalytic CO2 reduction. This influences the amount of oxides formed under pulsed reaction conditions and the distribution of reaction products.
Martina Rüscher, Andrea Martini, Eduardo Ortega, Lichen Bai, Eric Liberra, Daniel Escalera‐López, Hyo Sang Jeon, Antonia Herzog, Clara Rettenmaier, Dorottya Hursán, David Koshy, Mariana Cecilio de Oliveira Monteiro, Timon Wagner, Leon Jacobse, Felix Haase, Arno Bergmann, Janis Timoshenko, Beatriz Roldan Cuenya   +17 more
wiley   +1 more source

Advances in asymmetric organocatalysis over the last 10 years

Nature Communications, 2020
Organocatalysis has become a major pillar of (asymmetric) catalysis. Here, the authors discuss recent trends in organocatalytic activation modes for challenging stereoselective transformations and the emerging integration with other fields, such as ...
Shao-Hua Xiang, Bin Tan
doaj   +1 more source

Mechanistic Control of C─H Bond Activation and C─C Coupling in Light‐Driven Methane Conversion to C2+ Products over Multifunctional Photocatalysts

Advanced Functional Materials, EarlyView.
Methane photocatalytic activation under mild conditions remains a formidable challenge in the synthesis of solar fuels. In this review, we emphasize the growing importance of multifunctional materials and hybrid systems within a unified mechanistic framework that integrates selective C─H bond activation, formation and control of intermediates, C─C ...
Di Hu, Yuheng Jiang, Vitaly V. Ordomsky, Bastian Mei, Zhiyong Tang, Andrei Y. Khodakov   +5 more
wiley   +1 more source

Chemically Fueled Systems Chemistry Across Length Scales

Advanced Functional Materials, EarlyView.
Chemically fueled reaction cycles regulate processes through single and multiple catalytic sites on the molecular and assembly scale. This gives rise to unique kinetically controlled properties/functions like spatio‐temporal catalysis, oscillations, optical properties, and perform work.
Brigitte A. K. Kriebisch, Job Boekhoven
wiley   +1 more source