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Recent Advances in π-Stacking Interaction-Controlled Asymmetric Synthesis [PDF]

Molecules
The π-stacking interaction is one of the most important intramolecular and intermolecular noncovalent interactions in organic chemistry. It plays an important role in stabilizing some structures and transition states in certain reactions via both ...
Jiaxi Xu
doaj   +2 more sources

Preparation and DFT studies of chiral Cu (I)-complexes of biphenyl bisoxazolines and their application in enantioselective Kharasch–Sosnovsky reaction

Scientific Reports, 2022
Effect of a range of t-butyl perbenzoates bearing electron-withdrawing and electron-donating substitutions on the phenyl ring and HZSM-5 as a porous additive at 0 °C in enantioselective allylic C–H bond oxidation of cyclic and acyclic olefins in the ...
Saadi Samadi, Hamid Arvinnezhad, Sirwan Mansoori, Hadi Parsa   +3 more
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Synthesis of novel phthalimido oxime pseudoesters and evaluation of their cytotoxicity [PDF]

Journal of the Serbian Chemical Society, 2020
A series of novel optically pure oxime pseudoesters derivatives were synthesized by the reaction of substitute keto oximes with various N-substituted α-amino acids chlorides in the presence of triethylamine and dichloromethane at 0°C, and their ...
Mehrez Asma, Chakroun Ibtissem, Mtat Dalila, Ben Mansour Hédi, Touati Ridha   +4 more
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Asymmetric Synthesis of Noradamantane Scaffolds via Diphenylprolinol Silyl Ether-Mediated Domino Michael/Epimerization/Michael (or Aldol)/1,2-Addition Reactions. [PDF]

Angew Chem Int Ed Engl
Daskalakis K, Umekubo N, Indu S, Kawauchi G, Taniguchi T, Monde K, Hayashi Y.   +6 more
europepmc   +3 more sources

Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions

Comptes Rendus. Chimie, 2020
Diarylamines were synthesized using p-toluene sulfonamides with benzhydrol derivatives in the presence of a copper/bisphosphine complex by Borrowing Hydrogen (BH) mechanism, yielding ${
Ashouri, Akram, Samadi, Saadi, Ahmadian, Masoud, Nasiri, Behzad   +3 more
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Recent Advances in DMSO-Based Direct Synthesis of Heterocycles

Molecules, 2022
Besides serving as a low-toxicity, inexpensive and easily accessible solvent, dimethyl sulfoxide (DMSO) has also been extensively used as a versatile reagent for the synthesis of functionalized molecules.
Hai-Lei Cui
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Nickel-catalyzed direct stereoselective α-allylation of ketones with non-conjugated dienes

Nature Communications, 2023
The development of efficient and sustainable methods for the construction of carbon-carbon bonds with the simultaneous stereoselective generation of vicinal stereogenic centers is a longstanding goal in organic chemistry.
Yi-Xuan Cao, Matthew D. Wodrich, Nicolai Cramer   +2 more
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Synergistic Pd/Cu catalysis for stereoselective allylation of vinylethylene carbonates with glycine iminoesters: Enantioselective access to diverse trisubstituted allylic amino acid derivatives

Green Synthesis and Catalysis, 2021
We reported a synergistic Pd/Cu catalyzed enantioselective decarboxylative allylation of vinylethylene carbonates with glycine iminoesters, which provides facile access to non-proteinogenic diverse trisubstituted allylic amino acid derivatives in high ...
Miaolin Ke, Zhigang Liu, Ke Zhang, Sheng Zuo, Fener Chen   +4 more
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Novel functional [4]helicenes through a photooxidation pathway. Investigation of the absorption and fluorescence in solution

Comptes Rendus. Chimie, 2021
Novel functional [4]helicenes have been designed and synthesized, in 54%–72% overall yields, through an operational and simple two-step photochemical approach starting from various p-substituted phenylacetonitriles, and were characterized by NMR ($^{1}$H,
Hafedh, Nesrine, Asghar, Basim H., Aloui, Faouzi   +2 more
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Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines

Beilstein Journal of Organic Chemistry, 2021
A facile synthesis of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridine derivatives is reported which is based on POCl3-mediated cyclodehydration followed by double Suzuki–Miyaura cross-coupling.
Najeh Tka, Mohamed Adnene Hadj Ayed, Mourad Ben Braiek, Mahjoub Jabli, Peter Langer   +4 more
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