Results 11 to 20 of about 1,863 (161)

Azetidine synthesis enabled by photo-induced copper catalysis via [3+1] radical cascade cyclization

open access: yesThe Innovation, 2022
Azetidines are an important type of saturated, highly strained, four-membered, nitrogen-containing heterocyclic compound. These compounds serve as important raw materials, intermediates, and catalysts in organic synthesis, as well as important active ...
Jianye Li   +8 more
doaj   +1 more source

The Polymerization of Azetidines and Azetidine Derivatives [PDF]

open access: yesPolymer Journal, 1980
The cationic ring-opening polymerization of azetidine, N-alkylazetidines and a number of azetidines carrying a second functional group is reviewed. Some of these monomers lead to “living” polymers. The rate constants for the polymerization of different azetidines are discussed and compared with the rate constants for the polymerization of other four ...
Goethals, E. J.   +4 more
openaire   +1 more source

Dynamic Phenomena and Complexation Effects in the α-Lithiation and Asymmetric Functionalization of Azetidines

open access: yesMolecules, 2022
In this work it is demonstrated that enantiomerically enriched N-alkyl 2-oxazolinylazetidines undergo exclusive α-lithiation, and that the resulting lithiated intermediate is chemically stable but configurationally labile under the given experimental ...
Pantaleo Musci   +6 more
doaj   +1 more source

Intermolecular 2+2 imine-olefin photocycloadditions enabled by Cu(I)-alkene MLCT

open access: yesNature Communications, 2022
An ideal method to construct azetidines would be through a [2 + 2] photocycloaddition that joins an olefin and an imine, shown only rarely in the literature, partially due to competitive photochemical processes of the imine.
Daniel M. Flores   +2 more
doaj   +1 more source

Reaction of Azetidines with Chloroformates. [PDF]

open access: yesChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Couty, François   +3 more
openaire   +3 more sources

Azetidine synthesis by La(OTf)3-catalyzed intramolecular regioselective aminolysis of cis-3,4-epoxy amines

open access: yesFrontiers in Chemistry, 2023
Azetidine is a prevalent structural motif found in various biologically active compounds. In this research paper, we report La(OTf)3-catalyzed intramolecular regioselective aminolysis of cis-3,4-epoxy amines to afford azetidines.
Yuse Kuriyama   +2 more
doaj   +1 more source

Synthesis of Azetidine-Based Beta-Amino Alcohols

open access: yesMedical Sciences Forum, 2022
Beta-amino alcohols are versatile chemicals used as scaffolds in medicinal chemistry and they are key factors for the efficacy of numerous pharmaceutical products.
Linda Supe
doaj   +1 more source

A general synthesis of azetidines by copper-catalysed photoinduced anti-Baldwin radical cyclization of ynamides

open access: yesNature Communications, 2022
The construction of four-membered rings via a 4-exo-dig cyclization was originally theorized to be unfavourable and only recently shown in sparse examples.
Clément Jacob   +15 more
doaj   +1 more source

A sustainable and chemoselective continuous flow hydrogenation of functionalized 2-azetines to azetidines

open access: yesTetrahedron Green Chem, 2023
The synthesis of functionalized azetidines from azetines is poorly explored. Here, we report the safe and sustainable continuous flow hydrogenation of 2-azetines using ethyl acetate and CPME as environmentally responsible solvents.
Elena Graziano   +6 more
doaj   +1 more source

Azetidines. II. Some Functional Derivatives of Azetidines [PDF]

open access: yesBulletin of the Chemical Society of Japan, 1967
Abstract The sodium methoxide-catalyzed cyclization of methyl α-tosylamino-γ-chlorobutyrate gave methyl 1-tosylazetidine-2-carboxylate, which was then converted to the corresponding carboxylic acid and carbinol. 1-Acetyl-2,2,4,4-tetramethylazetidine-3-carboxylic acid was prepared by the photolysis of 1-acetyl-4-diazo-2,2,5,5 ...
Teng-yueh Chen   +3 more
openaire   +1 more source

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