Results 251 to 260 of about 236,434 (328)

Gas-phase Curtius and Wolff rearrangement reactions investigated by tandem-MS, IR ion spectroscopy and theory.

open access: yesPhys Chem Chem Phys
Harnying W   +8 more
europepmc   +1 more source

Stimuli-Responsive Prodrug Linkers That Simultaneously Release Cargo and Neutralize In Situ Generated (Aza)Quinone Methides. [PDF]

open access: yesChemistry
Edupuganti VVSR   +7 more
europepmc   +1 more source

Is a Malleable Active Site Loop the Key to High Substrate Promiscuity? Hybrid, Biocatalytic Route to Structurally Diverse Taxoid Side Chains with Remarkable Dual Stereocontrol

open access: yesAngewandte Chemie, EarlyView.
A highly stereoselective, dynamic reductive kinetic resolution (DYRKR) entry into myriad Taxotere‐like side chains with Clostridium acetobutylicum alcohol dehydrogenase (CaADH) enzyme is reported. Follow‐on cross couplings expand the structural diversity of the library (36 total examples).
Gaurav P. Kudalkar   +15 more
wiley   +1 more source

Red‐Light‐Mediated Generation of Radicals: Applications in Organic Synthesis, Small‐Molecule Activation, Polymerization, and Bio‐Related Fields

open access: yesAngewandte Chemie International Edition, EarlyView.
Visible light‐driven photochemistry has advanced significantly, offering diverse methodologies in synthetic organic chemistry. Photocatalysis using red and near‐infrared (NIR) light is particularly notable due to its lower energy, reduced phototoxicity, minimized side reactions, and deeper penetration into reaction media.
Tong Zhang, Suman Pradhan, Shoubhik Das
wiley   +1 more source

Complex Donuts: Small Variations in DNA Sequence Dictate Pathway Complexity in DNA Nanotoroids

open access: yesAngewandte Chemie International Edition, Accepted Article.
The formation of higher‐order structures in natural biopolymers like polypeptides and nucleic acids is governed by sequence specificity and monomer chemistry. Nucleic acids can assemble into programmable nanostructures through base‐pairing interactions, but their chemical diversity is limited to four nucleobases.
Muhammad Ghufran Rafique   +8 more
wiley   +1 more source

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