Results 21 to 30 of about 227,350 (349)

Crystal structure of (N^C) cyclometalated AuIII diazide at 100 K

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
The title compound, an (N^C)-cyclometalated gold(III) diazide, namely, diazido[5-ethoxycarbonyl-2-(5-ethoxycarbonylpyridin-2-yl)phenyl-κ2C1,N]gold(III), [Au(C17H16NO4)(N3)2] or Au(ppyEt)(N3)2, was synthesized by reacting Au(ppyEt)Cl2 with NaN3 in water ...
Volodymyr Levchenko   +3 more
doaj   +1 more source

Site-Selective Dynamics of Ligand-Free and Ligand-Bound Azidolysozyme [PDF]

open access: yes, 2021
Azido-modified alanine residues (AlaN$_3$) are environment-sensitive, minimally invasive infrared probes for the site-specific investigation of protein structure and dynamics. Here, the capability of the label is investigated to query whether or not a ligand is bound to the active site of Lysozyme and how the spectroscopy and dynamics change upon ...
arxiv   +1 more source

Lattice dynamics and electronic structure of energetic solids LiN3 and NaN3: A first principles study [PDF]

open access: yesChemical Physics Letters, Volume 586, Page no 44 (2013), 2013
We report density functional theory calculations on the crystal structure, elastic, lattice dynamics and electronic properties of iso-structural layered monoclinic alkali azides, LiN3 and NaN3. The effect of van der Waals interactions on the ground- state structural properties is studied by using various dispersion corrected density functionals.
arxiv   +1 more source

Oligonucleotide Tagging for Copper-Free Click Conjugation

open access: yesMolecules, 2013
Copper-free click chemistry between cyclooctynes and azide is a mild, fast and selective technology for conjugation of oligonucleotides. However, technology for site-specific introduction of the requisite probes by automated protocols is scarce, while ...
Alan Rowan   +7 more
doaj   +1 more source

Synthesis of alpha-tetrasubstituted triazoles by copper-catalyzed silyl deprotection/azide cycloaddition

open access: yesBeilstein Journal of Organic Chemistry, 2015
Propargylamines are popular substrates for triazole formation, but tetrasubstituted variants have required multistep syntheses involving stoichiometric amounts of metal.
Zachary L. Palchak   +2 more
doaj   +1 more source

2-(2-Azabicyclo[3.2.1]octa-3,6-dien-2-yl)-1,3-dimethoxyimidazolium hexafluoridophosphate

open access: yesIUCrData, 2016
The title salt, C12H16N3O2+·PF6−, was obtained by the dipolar cycloaddition of norbornadiene to 2-azido-1,3-dimethoxyimidazolium hexafluoridophosphate.
Simone Haslinger   +3 more
doaj   +1 more source

Promising Oxygen- and Nitrogen-Rich Azidonitramino Ether Plasticizers for Energetic Materials

open access: yesMolecules, 2022
A simple, mild and general method has been developed for the preparation of alkyl nitramines bearing a halogenoalkoxylic moiety. From these reactive halogen intermediates, a few azidoalkoxyl alkyl nitramines have been produced as energetic plasticizers ...
Dmitry B. Vinogradov   +10 more
doaj   +1 more source

2D frameworks self-assembled from a hydrazone ligand and azide salts: synthesis, structures, and luminescent property

open access: yesActa Chimica Slovenica, 2017
Three metal-organic coordination polymers {[Cu(L)(N3)]·(H2O)0.25}n (1), {[Zn(L)(N3)]·(H2O)0.5}n(2)and [Cd2(L)2(N3)2(H2O)]n(3)have been synthesized from hydrazone ligand N′-(1-(pyrazin-2-yl)ethylidene)isonicotinohydrazide (HL), NaN3 and corresponding ...
Peng Wang   +4 more
doaj   +1 more source

SnAr Reactions of 2,4-Diazidopyrido[3,2-d]pyrimidine and Azide-Tetrazole Equilibrium Studies of the Obtained 5-Substituted Tetrazolo[1,5-a]pyrido[2,3-e]pyrimidines

open access: yesMolecules, 2022
A straightforward method for the synthesis of 5-substituted tetrazolo[1,5-a]pyrido[2,3-e]pyrimidines from 2,4-diazidopyrido[3,2-d]pyrimidine in SnAr reactions with N-, O-, and S- nucleophiles has been developed.
Kristaps Leškovskis   +3 more
doaj   +1 more source

Dual function additives: A small molecule crosslinker for enhanced efficiency and stability in organic solar cells [PDF]

open access: yes, 2015
A bis‐azide‐based small molecule cross­linker is synthesized and evaluated as both a stabilizing and efficiency‐boosting additive in bulk heterojunction organic photovoltaic cells.
Ashraf, RS   +8 more
core   +2 more sources

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