Results 21 to 30 of about 116,499 (253)

Synthesis, crystal structure and Hirshfeld surface analysis of 2-azido-N-(2,6-dimethylphenyl)acetamide

open access: yesActa Crystallographica Section E: Crystallographic Communications
The asymmetric unit of the title compound, C10H12N4O, consists of two independent molecules differing in the rotational orientation of the 2-azidoacetamido group.
Abderrazzak El Moutaouakil Ala Allah   +7 more
doaj   +1 more source

2D frameworks self-assembled from a hydrazone ligand and azide salts: synthesis, structures, and luminescent property

open access: yesActa Chimica Slovenica, 2017
Three metal-organic coordination polymers {[Cu(L)(N3)]·(H2O)0.25}n (1), {[Zn(L)(N3)]·(H2O)0.5}n(2)and [Cd2(L)2(N3)2(H2O)]n(3)have been synthesized from hydrazone ligand N′-(1-(pyrazin-2-yl)ethylidene)isonicotinohydrazide (HL), NaN3 and corresponding ...
Peng Wang   +4 more
doaj   +1 more source

One-Pot Sequence of Staudinger/aza-Wittig/Castagnoli–Cushman Reactions Provides Facile Access to Novel Natural-like Polycyclic Ring Systems

open access: yesMolecules, 2022
Realization of the one-pot Staudinger/aza-Wittig/Castagnoli–Cushman reaction sequence for a series of azido aldehydes and homophthalic anhydrides is described. The reaction proceeded at room temperature and delivered novel polyheterocycles related to the
Rodion Lebedev   +4 more
doaj   +1 more source

[(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine

open access: yesMolbank
The formation of a N,1,1-triaryl imine derived from (2-chlorophenyl)-bis-(4-fluorophenyl)methanol is reported. The title compound is formed from a consecutive process which involves a nucleophilic substitution and subsequent Schmidt reaction.
Salvador Vilchis-Valdés   +4 more
doaj   +1 more source

Synthesis of alpha-tetrasubstituted triazoles by copper-catalyzed silyl deprotection/azide cycloaddition

open access: yesBeilstein Journal of Organic Chemistry, 2015
Propargylamines are popular substrates for triazole formation, but tetrasubstituted variants have required multistep syntheses involving stoichiometric amounts of metal.
Zachary L. Palchak   +2 more
doaj   +1 more source

Thiophene-2-carbonyl azide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2013
The title compound, C5H3N3OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018 Å) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding inter-actions between adjacent mol-ecules. Of particular note is the occurrence of RC-H⋯N(-)=N(+)=NR inter-actions between an aromatic C-H group and an azide ...
Michael Findlater   +3 more
openaire   +3 more sources

Salivary Hydrogen Sulfide Measured with a New Highly Sensitive Self-Immolative Coumarin-Based Fluorescent Probe

open access: yesMolecules, 2018
Ample evidence suggests that H2S is an important biological mediator, produced by endogenous enzymes and microbiota. So far, several techniques including colorimetric methods, electrochemical analysis and sulfide precipitation have been developed for H2S
Ewelina Zaorska   +4 more
doaj   +1 more source

2-Azido-N-(4-methylphenyl)acetamide

open access: yesIUCrData, 2022
The asymmetric unit of the title compound, C9H10N4O, comprises three independent molecules, two pairs of which differ significantly in the rotational orientation of the azido group and one pair having very similar conformations; the N—N—C—C torsion ...
Mohcine Missioui   +4 more
doaj   +1 more source

Bis{bis(azido-κN)bis[bis(pyridin-2-yl-κN)amine]cobalt(III)} sulfate dihydrate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2016
The search for new molecular materials with interesting magnetic properties, using the pseudohalide azide ion and di-2-pyridylamine (dpa, C10H9N3) as a chelating ligand, led to the synthesis and structure determination of the title compound, [Co(N3)2(dpa)
Fatima Setifi   +3 more
doaj   +1 more source

Five-Coordinated Geometries from Molecular Structures to Solutions in Copper(II) Complexes Generated from Polydentate-N-Donor Ligands and Pseudohalides

open access: yesMolecules, 2020
A novel series of mononuclear five-coordinated pseudohalido-Cu(II) complexes displaying distorted square bipyramidal: [Cu(L1)(NCS)2] (1), [Cu(L2)(NCS)2] (2) and [Cu(L3)(NCS)]ClO4 (5) as well as distorted trigonal bipyramidal: [Cu(isp3tren)(N3)]ClO4 (3), [
Franz A. Mautner   +6 more
doaj   +1 more source

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