Results 31 to 40 of about 227,350 (349)

One-Pot Sequence of Staudinger/aza-Wittig/Castagnoli–Cushman Reactions Provides Facile Access to Novel Natural-like Polycyclic Ring Systems

open access: yesMolecules, 2022
Realization of the one-pot Staudinger/aza-Wittig/Castagnoli–Cushman reaction sequence for a series of azido aldehydes and homophthalic anhydrides is described. The reaction proceeded at room temperature and delivered novel polyheterocycles related to the
Rodion Lebedev   +4 more
doaj   +1 more source

Dynamic Light Scattering based microrheology of End-functionalised triblock copolymer solutions [PDF]

open access: yesarXiv, 2022
'Soft' patchy surfactant micelles have become an additional building tool in self-assembling systems. The triblock copolymer, Pluronic F108, forms spherical micelles in aqueous solutions upon heating leading to a simple phase diagram with a micellar crystalline solid at higher temperatures and concentrations.
arxiv  

A cell-permeable biscyclooctyne as a novel probe for the identification of protein sulfenic acids [PDF]

open access: yes, 2016
Reactive oxygen species act as important second messengers in cell signaling and homeostasis through the oxidation of protein thiols. However, the dynamic nature of protein oxidation and the lack of sensitivity of existing molecular probes have hindered ...
Hartley, Richard C.   +4 more
core   +2 more sources

Review of novel energetic polymers and binders – high energy propellant ingredients for the new space race

open access: yesDesigned Monomers and Polymers, 2019
Current solid rocket propellant formulations still employ traditional ingredients utilized since the 1960s, such as hydroxyl terminated polybutadiene (HTPB).
Tianze Cheng
doaj   +1 more source

N-(1-azido-2-(azidomethyl)butan-2-yl)-4-methylbenzenesulfonamide

open access: yesMolbank, 2022
A new bi-triazole precursor, N-(1-azido-2-(azidomethyl)butan-2-yl)-4-methylbenzenesulfonamide, was synthesized in two steps from 2-amino-2-ethyl-1,3-propanediol, with an overall yield of 80%.
Sara Hajib   +3 more
doaj   +1 more source

Structure, elastic and dynamical properties of KN$_3$ and RbN$_3$: A van der Waals density functional study [PDF]

open access: yesSolid state sciences, vol 23, pp, 17-25 (2013), 2013
We report a detailed first principles study on the structural, elastic, vibrational and thermodynamic properties of layered structure energetic alkali metal azides KN$_3$ and RbN$_3$. All the calculations were carried out by means of plane wave pseudopotential method with and without including van der Waals interactions.
arxiv   +1 more source

Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation

open access: yesNanomaterials, 2022
The current study aims to explain recent developments in the synthesis of Pb(II)-azido metal-organic coordination polymers. Coordination polymers are defined as hybrid materials encompassing metal-ion-based, organic linkers, vertices, and ligands ...
Jaber Dadashi   +4 more
doaj   +1 more source

Phase stability and lattice dynamics of ammonium azide under hydrostatic compression [PDF]

open access: yesPhysical Chemistry Chemical Physics, 17, 29210-29225, (2015), 2015
We have investigated the effect of hydrostatic pressure and temperature on phase stability of hydro-nitrogen solids using dispersion corrected Density Functional Theory calculations. From our total energy calculations, Ammonium Azide (AA) is found to be the thermodynamic ground state of N$_4$H$_4$ compounds in preference to Trans-Tetrazene (TTZ), Hydro-
arxiv   +1 more source

Site-Selective Dynamics of Azidolysozyme [PDF]

open access: yes, 2021
The spectroscopic response of and structural dynamics around all azido-modified alanine residues (AlaN$_3$) in Lysozyme is characterized. It is found that AlaN$_3$ is a positionally sensitive probe for the local dynamics, covering a frequency range of $\sim 15$ cm$^{-1}$ for the center frequency of the line shape.
arxiv   +1 more source

Bioconjugation of Green Fluorescent Protein via an Unexpectedly Stable Cyclic Sulfonium Intermediate [PDF]

open access: yes, 2012
Bioconjugation of superfolder GFP involving the formation of an unusually stable, and unprecedented, cyclic sulfonium species is described. This sulfonium can undergo smooth reaction with a range of nucleophiles to give sulfur-, selenium- and azide ...
Caddick, S   +4 more
core   +1 more source

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