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Reactive & Efficient: Organic Azides as Cross-Linkers in Material Sciences
Molecules, 2020 The exceptional reactivity of the azide group makes organic azides a highly versatile family of compounds in chemistry and the material sciences. One of the most prominent reactions employing organic azides is the regioselective copper(I)-catalyzed ...
Marvin Schock, Stefan Bräse
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Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
Nature Communications, 2019 Vinyl azides generally act as 3-atom synthon through the fast release of molecular nitrogen, whereas keeping the azide group intact is more challenging. Here, the authors show a copper-catalyzed enantioselective cycloaddition of two types of vinyl azides
Nuligonda Thirupathi +3 more
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Iodine Azide, Bromine Azide and Mercuric Azide
Journal of Synthetic Organic Chemistry, Japan, 1970 Hiromichi OHTA, Masayuki YOSHIDA
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Azides in the Synthesis of Various Heterocycles
Molecules, 2022 In this review, we focus on some interesting and recent examples of various applications of organic azides such as their intermolecular or intramolecular, under thermal, catalyzed, or noncatalyzed reaction conditions.
AbdElAziz A. Nayl +8 more
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SulfoxFluor-enabled deoxyazidation of alcohols with NaN3
Nature Communications, 2022 Azides are common moieties in chemical synthesis. Here the authors present a methodology to synthesize alkyl azides in one step from simple alcohols under mild conditions.
Junkai Guo +4 more
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Ortho-Phosphinoarenesulfonamide-Mediated Staudinger Reduction of Aryl and Alkyl Azides
Molecules, 2022 Conventional Staudinger reductions of organic azides are sluggish with aryl or bulky aliphatic azides. In addition, Staudinger reduction usually requires a large excess of water to promote the decomposition of the aza-ylide intermediate into phosphine ...
Xingzhuo Li +5 more
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Nature Communications, 2022 Catalytic kinetic resolution of racemates is among the best ways to prepare enantiopure compounds, but this process is difficult with organic azides given the small size of the azido group.
Pengbo Ye +5 more
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Synthesis of 1,2,3-triazoles using Grignard reactions through the protection of azides
Frontiers in Chemistry, 2023 An efficient method to prepare organomagnesium intermediates having a protected azido group is reported. Protection of azido groups with di-(tert-butyl)(4-(dimethylamino)phenylphosphine (amphos) and following iodine–magnesium exchange realized the ...
Rina Namioka +3 more
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Beilstein Journal of Organic Chemistry, 2020 N-Sulfonyl amidines bearing 1,2,3-triazole, isoxazole, thiazole and pyridine substituents were successfully prepared for the first time by reactions of primary, secondary and tertiary heterocyclic thioamides with alkyl- and arylsulfonyl azides.
Vladimir Ilkin +7 more
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Overview of 1,5-Selective Click Reaction of Azides with Alkynes or Their Synthetic Equivalents
Molecules, 2023 Nowadays, the click reaction of azides with alkynes has evolved rapidly and become one of the most efficient methods to synthesize 1,2,3-triazoles, which are an important class of N-containing heterocycles.
Yaqi Zhao +3 more
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