Results 121 to 130 of about 43,569 (363)

Rapid and Scalable Halosulfonylation of Strain‐Release Reagents**

Angewandte Chemie, Volume 135, Issue 3, January 16, 2023., 2023
A one‐pot halosulfonylation of strained hydrocarbons is described that proceeds under practical, scalable and mild conditions. Sulfonyl halides featuring aryl, heteroaryl and alkyl substituents are generated in situ from sulfinate salts and convenient halogen atom sources. This chemistry enables the synthesis of an array of halogen/sulfonyl‐substituted
Helena D. Pickford, Vasyl Ripenko, Ryan E. McNamee, Serhii Holovchuk, Amber L. Thompson, Russell C. Smith, Pavel K. Mykhailiuk, Edward A. Anderson   +7 more
wiley   +2 more sources

Synthesis and Consecutive Reactions of α-Azido Ketones: A Review

Molecules, 2015
This review paper covers the major synthetic approaches attempted towards the synthesis of α-azido ketones, as well as the synthetic applications/consecutive reactions of α-azido ketones.
Sadia Faiz, Ameer Fawad Zahoor, Nasir Rasool, Muhammad Yousaf, Asim Mansha, Muhammad Zia-Ul-Haq, Hawa Z. E. Jaafar   +6 more
doaj   +1 more source

Adjusting Cell‐Surface Interactions Through a Covalent Immobilization of Biomolecules

Advanced Materials Interfaces, EarlyView.
This review presents an overview of current and emerging immobilization techniques coupled with an in‐depth investigation of the underlying mechanisms governing the activity and stability of covalently immobilized biomolecules. The aim of this study is to serve as a guide for the development of long‐lasting biomedical coatings with versatile biological
Sara Shakibania, Manus J. P. Biggs, Katarzyna Krukiewicz   +2 more
wiley   +1 more source

Controlling Frost Propagation on Polymeric Surfaces Using SI‐ATRP Chemical Micropatterning

Advanced Materials Interfaces, EarlyView.
Local wettability differences on the polymeric substrates grafted with hydrophilic stripes are linked to local variations in the presence and state of molecular water layer (MWL). The localized MWL results in fast‐propagating freezing events on the hydrophilic stripes followed by slower freezing propagation across the more hydrophobic substrate, thus ...
Miisa J. Tavaststjerna, Stephen J. Picken, Santiago J. Garcia   +2 more
wiley   +1 more source

EFFECTS OF MECHANICAL FAULT IN THE ENERGETICALLY ACTIVE WHISKERS

Вестник Кемеровского государственного университета, 2014
The paper considers the results on flexural deformation detected by the authors in whiskers of lead azides and potassium nitrate when exposed to light, electric field and temperature.
F. I. Ivanov, E. V. Isakova
doaj  

Continuous multistep synthesis of 2-(azidomethyl)oxazoles

Beilstein Journal of Organic Chemistry, 2018
An efficient three-step protocol was developed to produce 2-(azidomethyl)oxazoles from vinyl azides in a continuous-flow process. The general synthetic strategy involves a thermolysis of vinyl azides to generate azirines, which react with bromoacetyl ...
Thaís A. Rossa, Nícolas S. Suveges, Marcus M. Sá, David Cantillo, C. Oliver Kappe   +4 more
doaj   +1 more source

Mechanical deformation of monocytic THP-1 cells : occurrence of two seqential phases with differential sensitivity to metabolic inhibitors [PDF]

Experimental Biology Online - EBO 2 (1997) 5, 2007
Blood leukocytes can exhibit extensive morphological changes during their passage through small capillary vessels. The human monocytic THP-1 cell line was used to explore the metabolic dependence of these shape changes. Cells were aspirated into micropipettes for determination of the rate of protrusion formation.
arxiv  

Extracellular Vesicle Crosslinkers Constructing Hydrogels with Stress‐Relaxation and Bioactive Protein Modification

Advanced Materials Interfaces, EarlyView.
Extracellular vesicles (EVs) are functionalized and used as crosslinkers to construct hydrogels, compatible with common crosslinking chemistries in biomaterial scaffolds. EV crosslinkers provided stress relaxation properties, promoting cell growth. They also enabled efficient protein delivery while maintaining biological activity, as VEGF‐loaded EV ...
Lufeng Shi, Yanzhen Jing, Haowen Lu, Fanxuan Zhao, Mengying An, Shuiling Jin, Chang Gao, Yongdong Dai, Yinxin Zhu, Shuxu Yang, Songying Zhang, Xuesong Ye, Xiujun Cai, Yifan Wang, Shangjing Xin   +14 more
wiley   +1 more source

Synthesis of 6-Amino-5-cyano-1,4-disubstituted-2(1H)-Pyrimidinones via Copper-(I)-catalyzed Alkyne-azide ‘Click Chemistry’ and Their Reactivity

Molecules, 2010
In this paper we present the room temperature synthesis of a novel serie of 1,4-disubstituted-1,2,3-triazoles 4a-l by employing the (3 + 2) cycloaddition reaction of pyrimidinones containing alkyne functions with different model azides in the presence of
Fethi Zribi, Romain Duval, Fakher Chabchoub, Françoise Nepveu, Ennaji Najahi, Jan Sudor   +5 more
doaj   +1 more source

Compound oxidized styrylphosphine [PDF]

, 1979
A process is described for preparing flame resistant, nontoxic vinyl polymers which contain phosphazene groups and which do not emit any toxic or corrosive products when they are oxidatively degraded.
Paciorek, K. J. L.
core   +1 more source