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Selective Chiral Diamine-bisoxazoline Iron(II) Catalysts for Pyrrolidine Formation via Intramolecular C(sp<sup>3</sup>)-H Amination of Aliphatic Azides. [PDF]
He Z +9 more
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Exploring the versatility of heterocyclic compounds containing nitrogen atoms (triazoles): a comprehensive review. [PDF]
Akram M, Tamminana R.
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Enantioselective C-H amination catalyzed by homoleptic iron salox complexes.
Stroek W +3 more
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Pyrolysis of aryl azides. II. Naphthyl azides
Kinetic studies of the pyrolyses of 1- and 2-naphthyl azides reveal neighbouring group participation by nitro and phenylazo substituents. The acceleration observed in 1-nitro-2-naphthyl azide, 1-phenylazo-2-naphthyl azide, and 2-nitro-1-naphthyl azide is 1730-, 211-, and 23.6-fold, respectively, in nitrobenzene solution at 120º.
G Boshev, LK Dyall, PR Sadler
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Alkyne Phosphonites for Sequential Azide–Azide Couplings
Angewandte Chemie - International Edition, 2013Modern research often demands the modular conjugation of molecular systems with functional modules including fluorophores, purification tags, solubility enhancers, isotopic labels, or biologically active ligands, which enable their functional analysis, tracking in complex environments, and aids in several medicinal and pharmaceutical applications. Such
Jens Dernedde, Christian Hackenberger
exaly +3 more sources
Acta Crystallographica Section C Crystal Structure Communications, 2001
Crystals of the title compound, nitrocarbamimidoyl azide, CH(2)N(6)O(2), consist of two symmetry-independent molecules and the structure is stabilized by intra- and intermolecular hydrogen bonds. The molecule possesses a nitrimine structure.
A D, Vasiliev +4 more
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Crystals of the title compound, nitrocarbamimidoyl azide, CH(2)N(6)O(2), consist of two symmetry-independent molecules and the structure is stabilized by intra- and intermolecular hydrogen bonds. The molecule possesses a nitrimine structure.
A D, Vasiliev +4 more
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Dual Roles of Azide: Dearomative Dimerization of Furfuryl Azides
The Journal of Organic Chemistry, 2022A dearomative dimerization of furfuryl azides for the construction of furfuryl triazoles is developed. As a rare leaving group, azide is capable of initiating the generation of a furfuryl cation under the Lewis acid-catalyzed conditions, followed by reacting with the other azide to realize an intermolecular [3 + 2] cycloaddition/furan ring-opening ...
Zhe Hao +6 more
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Kinetic Study of the Radical Azidation with Sulfonyl Azides*
Australian Journal of Chemistry, 2013Rate constants for the reaction between a secondary alkyl radical and two different sulfonyl azides were determined using bimolecular competing radical reactions. The rates of azidation were determined by competition with hydrogen atom transfer from tris(trimethylsilyl)silane ((TMS)3SiH) of the 4-phenylcyclohexyl radical.
Weidner Karin, Renaud Philippe
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Ab initio Study of Energetic Solids: Cupric Azide, Mercuric Azide, and Lead Azide
ChemInform, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Weihua, Zhu, Heming, Xiao
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