Cycloaddition reactions of conjugated azoalkenes [PDF]
An overview of the use of 2H-azirines, conjugated nitrosoalkenes and conjugated azoalkenes bearing phosphorus substituents in addition and cycloaddition reactions is presented, focused on strategies for the synthesis of aminophosphonate and ...
Lemos, A.
core
Research Experience for Undergraduates Program, 2010 [PDF]
Supported by the National Science ...
University of Arkansas, Fayetteville. Dept. of Chemistry and Biochemistry
core +3 more sources
Multicomponent Synthesis of Fluorine‐Containing Bioactive Compounds and Drugs
Multicomponent reactions are robust synthetic tools to assamble complex polyheterocycles and other interesting molecular architectures with potential application in medicinal chemistry, including their fluorine‐containing analogues. Fluorine atoms placed strategically into bioactive molecules often enhance essential pharmacokinetic parameters like ...
Ivette Morales‐Salazar +7 more
wiley +1 more source
2-Thiabicyclo[3.2.0]hepta-3,6-Dienes. 3. Desulfuration and Sulfuration of 2-Thiabicyclo[3.2.0]hepta-3,6-Dienes and X-Ray Crystal Structure of 3a,6,7,8,9,9a-Hexahydro-3a,5-Dimethylthieno[3,2-B][2]benzothiophene-2,3-Dicarbonitrile [PDF]
The 2-3.2.0] hepta-3,6-Dienes 1–7 Extrude Sulfur in Solution at 285 °C to Give the 1,2-Benzenedicarbonitriles 8–12 in Yields of 42–56%. 5-(1,1-Dimethylethyl)-3,6-Dimethyl-2-3.2.0] hepta-3,6-Diene-1,7-Dicarbonitrile (6) Reacts at 140 °C to Give a Mixture ...
den Hertog, Herman J. +5 more
core +2 more sources
2H-Pyrrole und Pyrrole aus 3-Phenyl-2H-azirinen
Vinyl-phosphonium salts [2] and phenyl-vinyl-sulfone or divinylsulfone react with benzonitril-methylides a (which are photochemically generated from 3-phenyl-2H-azirines 1 and 2) to give, via the nonisolated intermediates of type b, 2H-pyrrole 4 and the
Ulrich Widmer +4 more
doaj +1 more source
Kupferkatalysierte, hochgradig enantioselektive Addition eines Siliciumnukleophils an 3‐substituierte 2H‐Azirine unter Verwendung eines Si‐B‐Reagenzes [PDF]
Zhiyuan Zhao +3 more
openalex +1 more source
Aromaticity and Photoreactivity of 4‐ and 3‐Nitrenopyridine 1‐Oxides and Phenylnitrene
NICS(1.7)zz, ACID, and spin density calculations reveal that triplet 4‐nitrenopyridine oxide, 3‐nitrenopyridine oxide, and phenylnitrene display Baird triplet aromaticity. These findings help clarify the relationships between structure and aromaticity in triplet arylnitrenes. ABSTRACT The pursuit of sustainable organic synthesis has renewed interest in
Fiona J. Wasson +7 more
wiley +1 more source
Polymerization‐Induced Direct Photolithography of Quantum Dots
We present a comprehensive overview of photochemical polymerization strategies for direct lithographic patterning of colloidal quantum dots (QDs). Reaction mechanisms are categorized by functional group type, and their application is discussed in terms of pattern fidelity, photostability, and environmental robustness, highlighting the potential of ...
Taehyung Kim +3 more
wiley +1 more source
Synthesis and reactions of aminopropenes, which contains functional groups [PDF]
В рамках данной работы осуществлен синтез енаминов, содержащих остатки первичных, вторичных, третичных аминов, а также амидную и тиоамидную группы. Проведено комплексное исследование структуры полученных соединений с помощью спектральных методов, включая
Lugovik, K. I., Луговик, К. И.
core
Synthesis of Siphonazole B Through Domino Cycloisomerization‐Oxazolonium Ion Rearrangements
The study by Strand and co‐workers describes a concise synthesis of siphonazole B. Both oxazole units are formed from a simple propargylamine using a novel domino cycloisomerization‐rearrangement approach. Additional synthetic features include a direct aldol‐type reaction for assembling the tricyclic siphonazole core and an oxidative amidation reaction
Filip Paulsen +5 more
wiley +1 more source

