Addition and cycloaddition reactions of Phosphinyl- and Phosphonyl-2H-Azirines, Nitrosoalkenes and Azoalkenes [PDF]
, 2012 An overview of the use of 2H-azirines, conjugated nitrosoalkenes and conjugated azoalkenes bearing phosphorus substituents in addition and cycloaddition reactions is presented, focused on strategies for the synthesis of aminophosphonate and ...
Lemos, A.
core
I. The Synthesis, Absolute Configuration, and Stereochemistry of Thermal Decomposition of (+)-3R,5R- and (+)-3R,5S-3-Ethyl-5-Methyl-1-Pyrazoline. II. Mechanistic Investigations of the Thermal Decompositions of 2H-Azirines [PDF]
, 1976 I. (+)-3R,5R- and (+)-3R,5S-3-ethyl-5-methyl-1-pyrazolines (34T and 34C, respectively) have been prepared in optically active form. Their stereochemistries have been determined by correlation with (-)-R-3-hexanol and (-)-R-2-bromohexane.
Wendling, Larry Allan
core +1 more source
Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
European Journal of Organic Chemistry, EarlyView.Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley +1 more source
Chemistry of 1,3-Dioxepins. XVI.1 The Synthesis, Characterization and Crystallographic Analysis of Some Arylsulphanyl-, Arylsulphinyl-, Arylsulphonyl- and Benzoyl- N-Substituted Derivatives of 1a,2,6,6a-Tetrahydro-1H,4H-[1,3]dioxepino[5,6-b]azirines [PDF]
, 2006 Chemo-selective synthesis and characterization of N-[(4-nitrophenyl)sulphanyl]- 2 and N-[(4- nitrophenyl)sulphinyl]- 3 N-[(4-aminophenyl)sulphonyl]- 5 and N-(4-aminobenzoyl)- 7 derivatives of 1a,2,6,6a-tetrahydro-1H,4H-[1,3]dioxepino[5,6-b]azirines ...
Biserka Prugovečki +3 more
core +1 more source
European Journal of Organic Chemistry, EarlyView.1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer +6 more
wiley +1 more source
Pyridonderivate aus 3-Amino-2H-azirinen und Cyclopropenonen
CHIMIA, 1978 Reaction of the 3-dimethylamino-2H-azirines 1a and 1b with diphenylcyclopropenone (2a) in ether or acetonitrile leads to the 2-dimethylamino-5,6-diphenyl-4(3H)-pyridones 3a and 3b in 70 and 80% yield, respectively. The structure of these 1:1-adducts has
Stanislav Chaloupka, Heinz Heimgartner
doaj +1 more source
Síntese e reactividade de 2H - Azirinas [PDF]
, 2007 Tese de Doutoramento em Ciências (Área de Especialização em Química Orgânica)O trabalho teve como objectivo primeiro, sintetizar 2H-azirinas com o grupo sulfinilo na posição 3.
Sousa, João Henriques de
core
Journal of Physical Organic Chemistry, Volume 39, Issue 4, April 2026.New calculations have been applied to the pyrolysis of pyrrole under shock‐tube conditions and to the radical‐radical reaction between allyl and •CN at low temperature and pressure, using the same mechanistic scheme for both. ABSTRACT The pyrolysis of pyrrole has previously been studied in shock‐tube experiments and in jet‐stirred reactors. The results
Barry K. Carpenter
wiley +1 more source
Recent Contributions of Organic Synthesis to Forensic Science
ChemPlusChem, Volume 91, Issue 2, February 2026.Forensic science is a multidisciplinary field that plays a vital role in providing scientific evidence for criminal investigations. This review highlights advances and opportunities at the interface between organic synthesis and forensic science, with applications in drug identification, forensic toxicology, and latent fingerprint detection and ...
Gustavo dos Santos Martins +3 more
wiley +1 more source
Research Experience for Undergraduates Program, 2010 [PDF]
, 2010 Supported by the National Science ...
University of Arkansas, Fayetteville. Dept. of Chemistry and Biochemistry
core +3 more sources