Modern Methods for Conjugated Polymers Preparation: A Concept of Transition Metal‐Free Synthesis
European Journal of Organic Chemistry, Volume 28, Issue 2, January 10, 2025.Conjugated polymers (CPs) are promising organic materials currently at the center of the organic electronics revolution. Synthesis strategies play a crucial role in the rise of this field, and this review aims to shed light on transition metal‐free organic chemistry for the synthesis of conjugated polymers, which is currently experiencing a renaissance.
Tomaž Kotnik, Sebastijan Kovačič
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Application of 1,3-Dipolar Reactions between Azomethine Ylides and Alkenes to the Synthesis of Catalysts and Biologically Active Compounds [PDF]
, 2018 The (3+2) cycloaddition between azomethine ylides and alkenes is an efficient, convergent and stereocontrolled method for the synthesis of unnatural pyrrolidine and proline scaffolds.
Arrastia, Iosune +2 more
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Chemistry – A European Journal, Volume 30, Issue 72, December 23, 2024.A convenient synthesis of planar chiral [2.2]paracyclophane imidazoline N,O‐ligands has been developed. The application of these classes of ligands showed excellent performance in organozinc additions to aldehydes. An improved seven‐step synthesis of [2.2]paracyclophane‐imidazoline N,O‐ligands (UCD‐Imphanols) possessing both central and planar ...
Sundaravel Vivek Kumar, Patrick J Guiry
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New Chemistry of Imidazolinium ylides [PDF]
, 2001 Previous work in this group has shown 4,5-dihydroimidazolium ylides, formed by N- alkylation of 4,5-dihydroimidazoles, to undergo 1,3-dipolar cycloadditions with a range of dipolarophiles in a highly regio- and stereoselective fashion.
Lory, Pedro M. J.
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Total Synthesis of (−)-Daphenylline [PDF]
, 2016 Total synthesis of (−)-daphenylline, a hexacyclic Daphniphyllum alkaloid, was achieved. Construction of the tricyclic DEF ring system was initiated by asymmetric Negishi coupling followed by an intramolecular Friedel–Crafts reaction.
67333 +7 more
core +1 more source
One pot synthesis of pyrrolidines type 3,7-diazabicyclo [3.3.0] octane and biological activity [PDF]
, 2008 Pyrrolidines type 2,4-disubstituted (alkyl, aryl or heteroaryl)-6,8-dioxo-3,7-diazabicyclo [3.3.0] octanes (8a-d) were successfully synthesized by an efficient one pot 1,3-dipolar cycloaddition of azomethine ylides (in situ generated from the reaction of
Amornraksa, Kitti +2 more
core
Highly diastereoselective synthesis of substituted pyrrolidines using a sequence of azomethine ylide cycloaddition and nucleophilic cyclization [PDF]
, 2010 : Although cycloadditions of azomethine ylides usually give mixtures of endo/exo adducts, we successfully tuned the mechanistic path of a new reaction cascade to afford substituted pyrrolidines in high yields and diastereomeric purity.
Achiwa K. +30 more
core +1 more source
Strecker degradation of amino acids promoted by a camphor-derived sulfonamide [PDF]
, 2016 A camphor-derived sulfonimine with a conjugated carbonyl group, oxoimine 1 (O2SNC10H13O), reacts with amino acids (glycine, L-alanine, L-phenylalanine, L-leucine) to form a compound O2SNC10H13NC10H14NSO2 (2) which was characterized by spectroscopic means
Carvalho, M. Fernanda N. N. +6 more
core +4 more sources
Addition of azomethine ylides to carbon-encapsulated iron nanoparticles
Dalton Transactions, 2018 Carbon-encapsulated iron nanoparticles have been covalently functionalized using the Prato reaction.
Artur Kasprzak +6 more
openaire +4 more sources
[3+2] Dipolar Cycloaddition of a Stabilized Azomethine Ylide and an Electron-Deficient Dipolarophile: Revision of Regioselectivity. [PDF]
J Org Chem, 2023 Wu KJY, Benedetto AE, Myers AG.
europepmc +1 more source