Results 81 to 90 of about 27,751 (287)

Defect-engineered graphene functionalization via cycloaddition reaction – towards a versatile platform for nanoscale devices and 3D heterostructures [PDF]

open access: yes, 2022
In recent years it has been shown that the outstanding properties of graphene, a direct consequence of its unique 2D structure, could be further tailored by surface functionalization with suitable materials, towards a fine tuning of the system's physical
BASTA, Luca
core  

Catalysis in Chemical Modification of Proteins

open access: yesChemCatChem, Volume 17, Issue 11, June 6, 2025.
Catalytic principles of synthetic organic chemistry have been increasingly applied to chemical modification of proteins during the recent years. This review article describes how seven types of catalytic systems —electrocatalysis, photocatalysis, metal catalysis, acid catalysis, organocatalysis, supramolecular catalysis, and heterogeneous catalysis ...
Seiya Ishizawa   +4 more
wiley   +1 more source

Kinetic Resolution of Alkylidene Norcamphors via a Ligand-Controlled Umpolung-Type 1,3-Dipolar Cycloaddition

open access: yesiScience, 2019
Summary: Development of a general catalytic and highly efficient method utilizing readily available precursors for the regio- and stereoselective construction of bioactive natural-product-inspired spiro architectures remains a formidable challenge in ...
Chong Shen   +5 more
doaj  

Amino Acid Degradations Produced by Lipid Oxidation Products [PDF]

open access: yes, 2017
Differently to amino acid degradations produced by carbohydrate-derived reactive carbonyls, amino acid degradations produced by lipid oxidation products are lesser known in spite of being lipid oxidation a major source of reactive carbonyls in food. This
Hidalgo, Francisco J., Zamora, Rosario
core   +1 more source

Open‐Chain Tetrapyrroles Meet Metal Ions in the Functional Molecular Material Science

open access: yesChemPlusChem, Volume 90, Issue 6, June 2025.
Open‐chain tetrapyrroles, synthesized via oxidative cleavage and condensation, offer greater structural flexibility than cyclic counterparts like porphyrins. Their tunable electronic and geometric properties through metalation enable applications in bioimaging, therapies, ion sensing, chiroptical materials, and spintronic devices, making them valuable ...
Aninda Ghosh   +3 more
wiley   +1 more source

[3+2] Cycloaddition Reaction for the Stereoselective Synthesis of a New Spirooxindole Compound Grafted Imidazo[2,1-b]thiazole Scaffold: Crystal Structure and Computational Study

open access: yesCrystals, 2021
A new spirooxindole hybrid engrafted imidazo[2,1-b]thiazole core structure was designed and achieved via [3+2] cycloaddition reaction approach. One multi-component reaction between the ethylene derivative based imidazo[2,1-b]thiazole scaffold with 6-Cl ...
Mezna Saleh Altowyan   +5 more
doaj   +1 more source

Photocarboxylation of Arylated 2H‐Azirines Exploiting Continuous Flow Technology

open access: yesEuropean Journal of Organic Chemistry, Volume 28, Issue 18, May 23, 2025.
An efficient continuous process for the synthesis of trisubstituted oxazoles is reported which links the photochemical opening of azirines and the subsequent trapping of the azomethine ylides with CO2 gas. This highlights challenges and solutions when incorporating CO2 as a feedstock material for the photochemical synthesis of small heterocyclic ...
Arlene Bonner   +2 more
wiley   +1 more source

Recent Applications of Quinolinium Salts in the Synthesis of Annulated Heterocycles

open access: yesSynOpen, 2022
Quinoline derivatives are frequently found in natural products and biologically active compounds; however, construction of quinoline fused polyheterocycles is a challenging goal in synthetic organic chemistry.
Suven Das
doaj   +1 more source

Enantioselective Synthesis of exo-4-Nitroprolinates from Nitro­alkenes and Azomethine Ylides Catalyzed by Chiral Phosphor­amidite·Silver(I) or Copper(II) Complexes [PDF]

open access: yes, 2015
Chiral complexes formed by privileged phosphoramidites derived from chiral binol and optically pure Davies’ amines, and copper(II) triflate, silver(I) triflate or silver(I) benzoate are excellent catalysts for the general 1,3-dipolar cycloaddition ...
Castelló Moncayo, Luis Miguel   +5 more
core   +2 more sources

Computational Design, Synthesis, and Biological Assessment of Some Pyrrolo[3,4‐c]Pyrroles Targeting Mycobacterium Tuberculosis

open access: yesChemistrySelect, Volume 10, Issue 17, May 5, 2025.
A new set of spirooxindole‐ and spiroindenoquinoxaline‐derived pyrrolo[3,4‐c] pyrroles has been synthesized through atom‐economic one‐pot multicomponent reactions. Based on the results, compounds 4b and 5a demonstrated promising Glide scores and exhibited strong binding affinity with decaprenylphosphoryl‐β‐D‐ribofuranose oxidoreductase.
Mathiyazhagan Lavanya   +8 more
wiley   +1 more source

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