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Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins [PDF]

open access: goldMolecules, 2019
A mild rhodium-catalyzed annulation of Boc-protected benzamides with diazo compounds via C−C/C−O bond formation has been explored. In the presence of [Cp*RhCl2]2, AgSbF6 and Cs2CO3, Boc-protected benzamides can be effectively annulated to ...
Guangyu Dong, Chunpu Li, Hong Liu
doaj   +2 more sources

N-(diisopropylphosphanyl)benzamide

open access: yesMolbank, 2023
N-(diisopropylphosphanyl)benzamide, PhC(O)NHPiPr2, has been synthesized in good yield following two alternative procedures that employ benzamide as the starting material. The first one is a two-step preparation, in which N-(trimetilsilyl)benzamide is reacted with PiPr2Cl, to give the title compound in good yield, whereas the second one is a ...
María M. Alcaide   +3 more
openaire   +5 more sources

N-(Cyanomethyl)benzamide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2010
In the structure of the title compound, C(9)H(8)N(2)O, the amide group is twisted by a dihedral angle of 21.86 (7)° with respect to the benzene ring, while the planes of the benzene ring and cyano-methyl group form a dihedral angle of 53.13 (11)°. In the crystal structure, mol-ecules are linked via N-H⋯O hydrogen bonds, forming a chain running parallel
Abdelrhani Elachqar   +4 more
openaire   +3 more sources

Synthesis and In Silico Evaluation of Potential Insecticide Activity of Benzamides

open access: yesChemistry Proceedings, 2021
In order to find alternative pesticides, a series of benzamide derivatives was synthesized. An in silico inverted virtual screening protocol considering the 13 common insecticide protein targets was used to evaluate the potential insecticide activity of ...
Miguel A. F. Ribeiro   +8 more
doaj   +1 more source

N-(4-Methylphenyl)benzamide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2007
The structure of the title compound, C(14)H(13)NO, resembles those of N-(2-chloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(3,4-dichloro-phen-yl)benzamide and 2-chloro-N-(2-chloro-phen-yl)benzamide with similar bond parameters.
B. Thimme Gowda   +3 more
openaire   +6 more sources

N-(4-Chlorophenyl)benzamide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2008
The structure of the title compound, C(13)H(10)ClNO, resembles those of N-phen-ylbenzamide, N-(2-chloro-phenyl)-benzamide and other benzanilides, with similar bond parameters. The amide group -NHCO- makes a dihedral angle of 29.95 (9)° with the benzoyl ring, while the benzoyl and aniline rings form a dihedral angle of 60.76 (3)°.
Hartmut Fuess   +4 more
openaire   +3 more sources

N-(3,5-Dichlorophenyl)benzamide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2008
The conformation of the H-N-C=O unit in the title compound, C(13)H(9)Cl(2)NO, is trans, similar to the conformation observed in N-(3-chloro-phen-yl)benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(2,4-dichloro-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benzamide and N-(3,4-dichloro-phen-yl)benz-amide.
B. Thimme Gowda   +3 more
openaire   +3 more sources

N-(2,6-Dichlorophenyl)benzamide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2008
The conformation of the N-H and C=O bonds in the structure of the title compound (N26DCPBA), C(13)H(9)Cl(2)NO, are anti to each other, similar to that observed in N-phenyl-benzamide (NPBA), N-(2-chloro-phen-yl)benzamide (N2CPBA), N-(2,3-dichloro-phen-yl)benzamide (N23DCPBA) and other benzanilides. The asymmetric unit of N26DCPBA contains two mol-ecules.
Hartmut Fuess   +4 more
openaire   +3 more sources

Polymorphism in Benzamide

open access: yesAngewandte Chemie, 2005
(Figure Presented) At long last, the crystal structure of the metastable form of benzamide, whose existence has been known of for over 170 years, has finally been solved by using a combination of in situ crystallization, high-speed synchrotron X-ray powder diffraction, and global-optimization methods of structure determination (see picture).
W. I. F. David   +5 more
openaire   +3 more sources

N-(2,6-Dimethylphenyl)benzamide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2008
The title compound, C(15)H(15)NO, crystallizes with two mol-ecules in the asymmetric unit. The H-N-C=O units are in a trans conformation, similar to that observed in N-(3,4-dimethyl-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benz-amide and other benzanilides.
B. Thimme Gowda   +4 more
openaire   +3 more sources

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