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A mild rhodium-catalyzed annulation of Boc-protected benzamides with diazo compounds via C−C/C−O bond formation has been explored. In the presence of [Cp*RhCl2]2, AgSbF6 and Cs2CO3, Boc-protected benzamides can be effectively annulated to ...
Guangyu Dong, Chunpu Li, Hong Liu
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N-(4-Ferrocenylphenyl)benzamide [PDF]
In the title compound, [Fe(C(5)H(5))(C(18)H(14)NO)], the unsubstituted cyclo-penta-dienyl ring is disordered over two sets of sites with occupancy ratio of 0.55 (1):0.45 (1). One conformation has the rings eclipsed and the other staggered. An intra-molecular C-H⋯O hydrogen bond forms an S(6) ring motif.
Naeema Khan+3 more
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Abstract Background Ionizing radiation (IR) is a standard modality for the management of solid tumors. Apart from its killing effects, IR can induce pro‐survival factors leading to radioresistance of cancer. Mechanistic understanding of radiation resistance is warranted to overcome the pro‐survival effects of IR.
Seema Gupta, Mansoor M. Ahmed
wiley +1 more source
The continuously increasing global impact of fungal infections is requiring the rapid development of novel antifungal agents. Due to their multiple pharmacological activities, thiourea derivatives represent privileged candidates for shaping new drugs. We
Carmen Limban+8 more
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CXCIV.—The condensation of salicylaldehyde and benzamide [PDF]
n ...
Titherley, Arthur Walsh+1 more
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N-(4-Chlorophenylsulfonyl)-4-iodobenzamide
In the title compound, C13H9ClINO3S, the benzene rings are inclined to one another by 81.6 (2)°. In the crystal, molecules are linked by pairs of N—H...O hydrogen bonds, forming inversion dimers with an R22(8) ring motif. The dimers are linked by C—H...O
S. Naveen+5 more
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The combination of solid phase polymer synthesis and enzymatic sialyation is used to yield multivalent stereoselective 3′‐sialyllactose‐presenting macromolecules. The one pot reaction using synthetase NmCSS and sialyltransferase PmST1 is suitable to transfer sialic acid to either glycan acceptors, such as lactose, but as shown now in this study also to
Patrick B. Konietzny+6 more
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N-(9,10-Dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide
In the present Short Note, we report a synthesis for the title compound, N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide by reacting 2-methylbenzoyl chloride (or 2-methylbenzoic acid) with 1-aminoanthraquinone. The synthesized target compound
Hamad H. Al Mamari, Ahmed Al Sheidi
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Transformation of Amides to Thioamides Using an Efficient and Novel Thiating Reagent
A convenient protocol was developed for the transformation of N-aryl-substituted benzamides to N-aryl-substituted benzothioamides using N-isopropyldithiocarbamate isopropyl ammonium salt as a novel thiating reagent.
Mohamed S. Gomaa+4 more
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Novel derivatives were prepared by reaction of aromatic amines with 2-(4-ethylphenoxymethyl)benzoyl isothiocyanate, affording the N-[2-(4-ethylphenoxymethyl) benzoyl]-Nꞌ-(substituted phenyl)thiourea.
Carmen Limban+14 more
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