Results 131 to 140 of about 1,143 (191)
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The “Benzothiazine” Chromophore of Pheomelanins: A Reassessment†

Photochemistry and Photobiology, 2007
AbstractThe characteristic absorption and photochemical properties of pheomelanins are generally attributed to “benzothiazine” structural units derived biogenetically from 5‐S‐cysteinyldopa. This notion, however, conveys little or no information about the structural chromophores responsible for the photoreactivity of pheomelanins.
NAPOLITANO, ALESSANDRA   +3 more
openaire   +4 more sources

A novel photoisomerzation of 1,2‐benzothiazine 1,1‐dioxides to 1,3‐benzothiazine 1,1‐dioxides

Journal of Heterocyclic Chemistry, 2007
AbstractA novel facile photoconversion of 4‐hydroxy‐1,2‐bezothiazine 1,1‐dioxides (3a‐e) into 4‐oxo‐1,3‐2H‐benzothiazine 1,1‐dioxides (4a‐e) and 4‐hydroxy‐2‐methyl‐N‐(pyridin‐2‐yl)‐2H‐1,2‐benzothiazine‐3‐carboxamide 1,1‐dioxide (PRX) into N‐methyl saccharin (2) upon 254 nm irradiation in methanol or acetonitrile is reported.
Ibrahim Elghamry   +2 more
openaire   +1 more source

1,4-Benzothiazines, Dihydro-1,4-benzothiazines, and Related Compounds.

1985
Publisher Summary The benzothiazines constitute a group of heterocyclic compounds; they have found a variety of industrial uses and show promise as herbicides. This chapter discusses the chemistry of 1,4-benzothiazines and dihydro-1,4-benzothiazines. The 1,4-benzothiazine ring is the basic unit for the phaeomelanins and trichochrome melanin pigments ...
C. Brown, R.M. Davidson
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Rearrangement of benzothiazine sulphoxides

Journal of the Chemical Society D: Chemical Communications, 1970
The reaction of substituted benzothiazine sulphoxides with Ac2O under reflux leads by an elimination reaction to a sulphenic acid derivative which undergoes subsequent addition to the generated double bond if the nitrogen is tertiary but is trapped as a cyclic sulphenamide by a secondary nitrogen.
Robert B. Morin, Douglas O. Spry
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Benzothiazines in Synthesis. Formal Synthesis of Erogorgiaene.

ChemInform, 2005
A benzothiazine, readily available in enantiomerically pure form via a completely selective, intramolecular addition of a sulfoximine-stabilized carbanion to an α,β-unsaturated ester, could be converted to a precursor to erogorgiaene in good overall yield.
Michael Harmata, Xuechuan Hong
openaire   +1 more source

1,4-Benzothiazines-A Biologically Attractive Scaffold

Mini-Reviews in Medicinal Chemistry, 2017
1,4-benzothiazine (1,4-B), a pharmacophore of anti-psychotic drug phenothiazines, is a vital class of heterocyclic compounds implicating versatile biological activities. The aim of this review article is to summarize various synthetic strategies, biological activities and structure activity relationship concerning the bioactive heterocycle, 1,4-B ...
Amit, Rai   +3 more
openaire   +2 more sources

A New, Chiral Bis-Benzothiazine Ligand

Organic Letters, 2001
[reaction: see text]. The synthesis and application of a new, chiral bis-benzothiazine ligand are described.
M, Harmata, S K, Ghosh
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Benzothiazines in Synthesis. Toward the Synthesis of Pseudopteroxazole

Organic Letters, 2004
[reaction: see text] The tricyclic benzothiazine 15 was prepared in a straightforward fashion via a completely stereoselective intramolecular Friedel-Crafts alkylation. This compound represents a potential precursor to the antitubercular agent, pseudopteroxazole.
Michael, Harmata   +2 more
openaire   +2 more sources

1,3-Benzothiazines (review)

Chemistry of Heterocyclic Compounds, 1979
Data on the methods for the synthesis of 1,3-benzothiazines and their derivatives and their chemical properties and physiological activity are correlated.
openaire   +1 more source

ChemInform Abstract: Benzothiazines in Organic Synthesis. Stereoselectivity in the Intermolecular Michael Addition Reactions of Benzothiazines.

ChemInform, 2008
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Michael Harmata   +2 more
openaire   +1 more source

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