Results 121 to 130 of about 153,292 (304)
Advanced Science, EarlyView.We report a general strategy for meta‐selective C–H arylation using aryl iodides and a Pd(II)/Pd(IV) catalytic system guided by a removable directing group. DFT and experimental studies reveal that counter anion tuning (acetate to trifluoroacetate) significantly enhances selectivity.
Jagrit Grover +6 more
wiley +1 more source
Electronic Structures of Benzyl Cation and Related Compounds [PDF]
Bulletin of the Chemical Society of Japan, 1962 Abstract The electronic structure of the benzyl cation has been calculated on the basis of an approximation of the composite systems in order to explain the electronic spectrum of the benzyl cation from the point of view of electron-transfer interaction between the fragments.
openaire +1 more source
Cell‐Free DNA‐Based Theranostics for Inflammatory Disorders
Advanced Science, EarlyView.Summary on the dual potential of cfDNA as biomarkers and therapeutic targets for inflammatory disorders. Figure was created with BioRender.com. ABSTRACT Inflammatory disorders are characterized by immune‐mediated inflammatory cascades that can affect multiple organs.
Jiatong Li +7 more
wiley +1 more source
New studies in aromatic chloromethylation [PDF]
, 1992 Chloromethylation reactions of anisole, cumene and trifluoromethylbenzene have been examined using the reagents formaldehyde and hydrogen chloride, in the presence of an extensive range of catalysts.
Eglington, Michael
core
Beyond Traditional RAFT Polymerization: Emerging Strategies and Future Perspectives; A Third Update
Advanced Science, EarlyView.This review explores recent advances in the past five years for non‐traditional RAFT polymerization, focusing on new activation strategies, sustainable depolymerization, and integration with automated and AI‐driven synthesis. Together, these innovations advance polymer chemistry and reveal how the pieces of the non‐traditional RAFT puzzle are steadily ...
Vianna F. Jafari +10 more
wiley +1 more source
Chemical Transformations of Benzyl Alcohol Caused by Atomic Chlorine
MoleculesAtomic chlorine present in the polluted troposphere can form potentially carcinogenic compounds as a result of a reaction with a natural product. This paper examines the stability of benzyl alcohol—a natural product commonly found in cosmetics—in ...
Dariusz S. Sarzyński, Irena Majerz
doaj +1 more source
Advanced Science, EarlyView.Fe‐based magnetic nanocubes conjugated with TRPV1 antibodies (FeNCs‐TRPV1) are developed for the specific targeting of TRPV1 channels. Intraspinally injected FeNCs‐TRPV1 induces TRPV1 desensitization in rats exposed to repetitive and transient ACMF.
Xueying Cheng +15 more
wiley +1 more source
Journal of Hazardous MaterialsBenzalkonium chlorides (BACs) are quaternary ammonium compounds (QUATs) that are used as biocides. The degradation of these compounds in wastewater treatment plants is essential to reduce their spread into the environment and thus prevent the development of QUAT-resistant genes.
Yrsa Larsson +3 more
openaire +3 more sources
Reactions of p-Nitrophenyloxirane with Amines Containing Fragments with Bicyclic Skeleton [PDF]
, 2002 Reactions of p-nitrophenyloxirane with amines containing fragments with bicyclic skeleton of norbornene, norbornane, epoxynorbornane (stereoisomeric exo- and endo-5-aminomethylbicyclo[2.2.1]hept-2-enes, N-benzyl-endo-5-aminomethylbicyclo[2.2.1]hept-2-ene,
Golodaeva, E. A. +3 more
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Nickel‐Catalyzed Twofold Conjunctive Coupling via Philicity‐Alternating Radical Relay
Advanced Science, EarlyView.Herein, we disclose a nickel‐catalyzed twofold conjunctive coupling that enables a four‐component assembly involving an activated alkene, a 1,3‐enyne, and both alkyl and aryl halides. Multiple C–C bonds are selectively constructed through a philicity‐alternating radical relay and the selective radical capture by the nickel catalyst.
Ji Hwan Jeon +7 more
wiley +1 more source