Results 141 to 150 of about 86,355 (288)

A Cholesterol Analogue for Cell‐Surface Enzyme Display

open access: yesAngewandte Chemie, EarlyView.
We report a non‐genetic strategy for bacterial cell surface enzyme immobilisation using cholesterol‐based artificial lipids containing Ni2+‐NTA binding groups that can integrate into biological membranes. The engineered cells can capture His‐tagged enzymes directly from cell lysates while preserving intracellular and surface activity, allowing for ...
Vasco F. Batista   +3 more
wiley   +2 more sources

Reactions of benzyl compounds with synthesis gas in the presence of ruthenium carbonyl iodides

open access: yes, 1982
Benzyl compounds, PhCH2X (X = OH, OCH2Ph, OMe, OAc), react with CO/H2 mixtures at 9-10 MPa and 220 C in the presence of aqueous HI and [RU(CO)3I2]2 to afford toluene, HX and polymers of the type H(C7H6)nH(n = 2-6).
TW Turney, SG Hardin
core   +1 more source

Chemical Transformations of Benzyl Alcohol Caused by Atomic Chlorine

open access: yesMolecules
Atomic chlorine present in the polluted troposphere can form potentially carcinogenic compounds as a result of a reaction with a natural product. This paper examines the stability of benzyl alcohol—a natural product commonly found in cosmetics—in ...
Dariusz S. Sarzyński, Irena Majerz
doaj   +1 more source

Rediscovering Sodium Ionophores as Selective Agents for Lithium Recognition and Extraction

open access: yesAngewandte Chemie, EarlyView.
Long‐classified sodium ionophores unexpectedly prefer lithium and act as efficient extractants in solid–liquid extraction (SLE). Readily prepared from catechol and haloacetamides, these hosts recover hydrated LiCl from multicomponent salt mixtures via a hydration‐assisted O···Li+ binding mode, enabling scalable lithium separation with Li/Na, Li/K, and ...
Jakub Narodowiec   +6 more
wiley   +2 more sources

Reactions of Some Cyclomanganated Compounds with C-Nitroso Compounds, Allenes, and Ketenimines

open access: yes, 2008
eta2-(5-Methoxy-2-acetylphenyl)tetracarbonylmanganese (30) was reacted with 2-methyl-2-nitrosopropane (31) to form 2-acetyl-5-methoxy-N-(tert-butyl)aniline(43) in low yield.
Revell, John Bernard
core  

Nitrone Synthesis via Pair Electrochemical Coupling of Nitro-Compounds with Benzyl Alcohol Derivatives

open access: yes, 2019
Here we report a paired electrochemical coupling of readily accessible nitro-compounds with benzyl alcohols to yield nitrone derivatives. In this work, electrochemical behavior of nitrobenzene and benzyl alcohol derivatives was studied by cyclic ...
Hamid Salehzadeh (6883886)   +3 more
core   +1 more source

Enantioselective Synthesis of Axially Chiral Diaryl Ethers via Rhodium‐Catalyzed [2 + 2 + 2] Cycloaddition

open access: yesAngewandte Chemie, EarlyView.
An enantioselective rhodium‐catalyzed [2 + 2 + 2] cycloaddition enables the synthesis of axially chiral diaryl ethers. Carbonyl coordination ensures high reactivity and regioselectivity, affording products bearing up to four stereogenic axes with good enantio‐ and diastereoselectivity.
Yu Sato   +3 more
wiley   +2 more sources

Oxidative Debenzylation of N‑Benzyl Amides and O‑Benzyl Ethers Using Alkali Metal Bromide

open access: yes, 2016
The oxidative debenzylation of N-benzyl amides and O-benzyl ethers was promoted with high efficiency by a bromo radical formed through the oxidation of bromide from alkali metal bromide under mild conditions.
Yu Nakamura (419459)   +2 more
core   +1 more source

Anionic T‐Shaped Platinum(0) Pincer Complexes and Platinum(I) Intermediates in Radical Reactions With Alkyl Halides

open access: yesAngewandte Chemie, EarlyView.
Two anionic, T‐shaped, d10 platinum(0) complexes containing a PNP pincer ligand have been isolated and characterized. These complexes react with aliphatic C‐Br bonds under formation of a platinum(II) bromide and an alkyl complex, as well as the homocoupled hydrocarbons.
Vincenz J. Kohler   +6 more
wiley   +2 more sources

Home - About - Disclaimer - Privacy