Iridium-Catalyzed Asymmetric Hydrogenation of Carbocation Precursors via Wagner-Meerwein Rearrangement. [PDF]
Mallick RK +3 more
europepmc +1 more source
Nitro Reduction‐Based RNA Control and Ultrafast Release
A chemical RNA caging–uncaging strategy based on nitro reduction is described. Nitroaryl groups introduced via acylation temporarily block the functions of diverse RNAs in vitro and in living cells. Treatment with a diboronic acid–bipyridine mixture rapidly reduces the nitro groups, releasing RNAs and restoring their activity.
Yiran Zhao +6 more
wiley +1 more source
Functional and Network PHAs via Stereoselective Polymerization and Tailored Post‐Transformation
Catalyst‐controlled stereoselective (co)polymerization of functionalized lactones produces vinyl‐, allyl‐, and propargyl‐functionalized PHAs with high syndiotacticity and a broad applicable temperature window, which can be further transformed into crosslinked PHA thermosets, elastic supramolecular networks, and functional grafts. ABSTRACT Incorporation
Ruirui Li +6 more
wiley +1 more source
Experimental and Computational Investigation of Sulfur Chemistry in the DART-MS Gas Stream: Implications for the Interpretation of the Mass Spectra of Organic Disulfides. [PDF]
Garosi B, Arathala P, Musah RA.
europepmc +1 more source
Unified Synthesis of Unconventional α‐Polyhalogenated Amines Through Hydroaminoalkylation
A unified, redox‐neutral method that transforms alkenes and alkynes into α‐polyhalomethyl amines using stable hemiaminal reagents is reported. This approach enables access to CF3, CF2H, CF2Cl, and CFClH motifs, expanding halogenated amine space with broad substrate scope, functional group tolerance, and applicability to late‐stage modification of drug ...
Angela K. Hofmeister +9 more
wiley +1 more source
Uncovering aroma profile and key odorants of Zisun tea: insights from grades and cultivars. [PDF]
Mei L +7 more
europepmc +1 more source
Bio-inspired asymmetric Zn-N<sub>2</sub>O<sub>2</sub> single-atom catalysts via natural skeleton for efficient N-alkylation of nitroarenes with alcohols. [PDF]
Huang Y +9 more
europepmc +1 more source
Semiochemicals and odorant receptors underlying potato cultivar susceptibility and resistance to potato tuber moth. [PDF]
Chen R +7 more
europepmc +1 more source
Deprotonative Single-Electron Oxidation as a General and Controllably Selective Platform for Benzylic C-H Functionalization. [PDF]
Coradi NJ, Bandar JS.
europepmc +1 more source
Evaluation of Novel Benzo-Annelated 1,4-Dihydropyridines as Potential Inhibitors of Antibacterial Efflux Pumps in <i>S. aureus</i> and MRSA Strains. [PDF]
Werner P +4 more
europepmc +1 more source

