Results 121 to 130 of about 77,454 (243)

An NHC‐Coordinated Silicon/Sulfur Analogue of an Acyl Carbene

Angewandte Chemie, EarlyView.
An NHC complex of an Si/S analogue of an acyl carbene is synthesized by the reaction of a disilyne with a cyclic thiourea. The observed Si2S three‐membered ring with unsymmetrical Si─S distances and a Si─Si single bond is consistent with intramolecular coordination of the silathioacyl sulfur to the silylene center.
Takuto Toyooka, Shintaro Ishida, Takeaki Iwamoto   +2 more
wiley   +1 more source

Efficient aerobic oxidation of benzyl alcohols using a magnetically recoverable Ni/nitrogen-containing carbon nanocomposite. [PDF]

RSC Adv
Arumugam DB, Santhakumar K.
europepmc   +1 more source

Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons

Angewandte Chemie, EarlyView.
1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu, Qian Wang, Matthew D. Wodrich, Jieping Zhu   +3 more
wiley   +1 more source

<i>Ordo ab Chao</i>: Crystallographic Disorder as a Window into Ionic Liquid Structure. [PDF]

Cryst Growth Des
Cooper J, Scheuren M, Teodoro LI, Butch CM, Jerdo RA, Allen KM, Toner ME, Zeller M, Mirjafari A, Hillesheim PC.   +9 more
europepmc   +1 more source

Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2

Angewandte Chemie, EarlyView.
By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin, Manting Mu, Max García‐Melchor, Eva Hevia   +3 more
wiley   +1 more source

Phytochemical Diversity in <i>Populus trichocarpa</i> Buds: Insights into Population Variation and Antifungal Properties. [PDF]

Plants (Basel)
Cothron SC, Leftwich L, Chen JG, Chen F.
europepmc   +1 more source

Report on Benzyl Compounds

Journal of AOAC INTERNATIONAL, 1933
openaire   +1 more source

Underexplored Catalysts as General Structures: Application of Machine Learning Techniques for Reaction‐Specific Datasets

Angewandte Chemie, EarlyView.
Bias‐aware machine learning identified an underexplored imidazolidinone catalyst with broad competitive performance in iminium‐based reactions. Experimental benchmarking shows how data‐driven prioritization can uncover overlooked catalyst scaffolds from sparse and historically biased literature data.
Jiajing Li, Isaiah O. Betinol, Junshan Lai, Soresu Juyo, Jolene P. Reid   +4 more
wiley   +1 more source

Comparative Profiling and In Silico Multitarget Analysis of Volatile Constituents from <i>Sambucus ebulus</i> L. Dried Fruits. [PDF]

Plants (Basel)
Stoyanov S, Dincheva I, Kolev I, Şenol H, Barbolov M, Radeva M, Olczyk P, Boshnakov P, Yaneva G, Ivanova D, Tasinov O.   +10 more
europepmc   +1 more source

Report on Benzyl Compounds

Journal of AOAC INTERNATIONAL, 1937
openaire   +1 more source