SPECIFIC “IONIC LIQUIDS” AS NEW ORGANOCATALYSTS OF BIGINELLI REACTION [PDF]
New ionic liquids bearing an imidazolium core with a carboxy group have been prepared in an attempt to design new organocatalysts of Biginelli reaction. Trends in the properties of these compounds are discussed.
Viorica Sargarovschi +2 more
doaj
Synthesis and antimicrobial evaluation of new 1,4-dihydro-4-pyrazolylpyridines and 4-pyrazolylpyridines [PDF]
Background Dialkyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylates (1,4-DHP) have now been recognized as vital drugs. Some of these derivatives such as amlodipine, felodipine, isradipine, etc. have been commercialized.
Om Prakash +5 more
core +1 more source
This study introduces an environmentally sustainable approach for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones (DHPMs), via the Biginelli reaction. A heterogeneous catalyst, Heteropolyacid-Clay (HPA-Clay), is developed by immobilizing H5PV2W10O40 on ...
Nuzhat Rehman +6 more
doaj +1 more source
Ferrocenil-származékok, heterovegyületek, poli-, illetve makrociklusos és glükozid-származékaik szintézise, szerkezete, sztereokémiai, molekuladinamikai és szisztematikus spektroszkópiai vizsgálata = Synthesis, structure, molecular dynamic, stereochemical and systematic spectroscopic study of ferrocenyl derivatives, heterocycles and their poly- and macrocyclic derivatives and glycosides. [PDF]
Több száz új, várhatóan biológiailag aktív ferrocén (Fc) származékot és heterociklusos vegyületet állítottunk elő. Szerkezetüket komplex nagyműszeres vizsgálatokkal (IR, 1H-, 13C-, 15N NMR, DNOE NMR, MS, X-ray) derítettük fel, a reakciómechanizmust ...
Csámpai, Antal +2 more
core
Using metrics and sustainability considerations to evaluate the use of bio-based and non-renewable Brønsted acidic ionic liquids to catalyse Fischer esterification reactions [PDF]
Background Ionic liquids have found uses in many applications, one of which is the joint solvation and catalysis of chemical transformations. Suitable Brønsted acidic ionic liquids can be formed by combining lactams with sulphonic acids. This work weighs
AC Cole +51 more
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An unexpected Ireland–Claisen rearrangement cascade during the synthesis of the tricyclic core of Curcusone C: Mechanistic elucidation by trial-and-error and automatic artificial force-induced reaction (AFIR) computations [PDF]
In the course of a total synthesis effort directed toward the natural product curcusone C, the Stoltz group discovered an unexpected thermal rearrangement of a divinylcyclopropane to the product of a formal Cope/1,3-sigmatropic shift sequence.
Houk, K. N. +6 more
core +5 more sources
Trifluoroacetic acid (TFA) is introduced as an effective catalyst for promotion of Biginelli reaction. 3,4-Dihydropyrimidin-2(1H)-one (-thione) derivatives (DHPMs) were simply and efficiently prepared using TFA catalyzed one-pot, three-component ...
Mohammad R. Mohammadizadeh, Neda Firoozi
doaj +1 more source
Design e síntese de nanopartículas magnéticas funcionalizadas com peptóides para a remoção de cromo de resíduos aquosos [PDF]
Dissertação (mestrado)–Universidade de Brasília, Faculdade UnB Planaltina, Mestrado em Ciência de Materiais, 2015.No presente trabalho realizou-se a síntese de nanopartículas magnéticas de óxido de ferro que foram funcionalizadas com peptóides.
Costa, Hingrid Lorrane Vieira da
core +1 more source
Biginelli Reaction Mediated Synthesis of Antimicrobial Pyrimidine Derivatives and Their Therapeutic Properties. [PDF]
Marinescu M.
europepmc +1 more source
Development of chiral phosphoric acids based on ferrocene-bridged paracyclophane frameworks [PDF]
International audienceThis work deals with the development of a new family of planar chiral phosphoric acids, based on a ferrocenophane/paracyclophane scaffold.
Betzer, Jean-François +7 more
core +6 more sources

