Results 121 to 130 of about 29,566 (262)

Measuring Local Exothermic Effects During the Oxidative Coupling of Methane Using Operando Luminescence Thermometry

open access: yesAngewandte Chemie, EarlyView.
Operando luminescence thermometry shows that the local catalyst temperature can exceed the set oven temperature by almost 250°C during the exothermic oxidative coupling of methane process. We demonstrate how the reactor dimensions, catalyst grain size, and reactant feed mixture affect the local temperature.
Daniël W. Groefsema   +5 more
wiley   +2 more sources

SigmaFormer: Augmenting transformer encoders with COSMO sigma profiles for pure component property prediction

open access: yesAIChE Journal, EarlyView.
Abstract Transformer‐based molecular models pretrained on SMILES strings demonstrate strong performance in property prediction. However, these model often lack explicit integration of molecular surface charge distributions that govern intermolecular interactions such as hydrogen bonding and polarity.
Tae Hyun Kim   +2 more
wiley   +1 more source

Predicting Catalyst Performance From Pt/CeO2 Redispersion Kinetics

open access: yesAngewandte Chemie, EarlyView.
Unravelling kinetics of dynamic structural changes in catalysts is the key to predicting their catalytic properties. ETEM experiments reveal a continuous decrease in Pt particle size on cube‐shaped CeO2 under oxidizing conditions, changing from large nanoparticles to highly dispersed species.
Florian Maurer   +11 more
wiley   +2 more sources

Resolving passive heat transfer and phase‐change heat in cryogenic CO2 deposition (Desublimation) from CO2/N2 mixtures

open access: yesAIChE Journal, EarlyView.
Abstract In cryogenic CO2 desublimation systems where phase change dominates both heat transfer and separation, conventional lumped thermal‐resistance treatments embed interfacial latent heat into an overall heat‐transfer coefficient, obscuring how phase‐change heat is partitioned between the gas phase and the coolant and limiting diagnostic insight ...
Shengwen Xiao   +2 more
wiley   +1 more source

A Robust Deep Temporal Causal Discovery Platform for Single‐Cell Gene Regulatory Network Reconstruction

open access: yesAdvanced Intelligent Discovery, EarlyView.
scTIGER2.0 is a deep‐learning framework that infers gene regulatory networks from single‐cell RNA sequencing data. By integrating correlation, pseudotime ordering, deep learning and bootstrap‐based significance testing, it reduces false positives and reveals directional gene interactions.
Nishi Gupta   +3 more
wiley   +1 more source

The microbial nexus: linking arsenic biogeochemistry with greenhouse gas emissions. [PDF]

open access: yesFront Microbiol
Wu Z   +7 more
europepmc   +1 more source

IRF‐1 modulates hepatic ferroptosis and aggravates liver ischemia/reperfusion injury via DYRK1α

open access: yesAnimal Models and Experimental Medicine, EarlyView.
IRF‐1 modulates hepatic ferroptosis and aggravates liver ischemia/reperfusion injury via DYRK1α. Abstract Background The purpose is to define the contribution of the interferon regulatory factor‐1–dual‐specificity tyrosine phosphorylation‐regulated kinase 1α (IRF‐1–DYRK1α) axis to hepatocellular ferroptosis during liver ischemia/reperfusion injury ...
Jinping Zhang   +6 more
wiley   +1 more source

Trophic status strongly regulates nitrous oxide but not methane production in global freshwater lake sediments. [PDF]

open access: yesNat Commun
Yang Y   +14 more
europepmc   +1 more source

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